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Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles

Matt Carnie Orcid Logo, Cecile Charbonneau Orcid Logo, Matthew Davies Orcid Logo, Brian O' Regan, David Worsley Orcid Logo, Trystan Watson Orcid Logo

J. Mater. Chem. A, Volume: 2, Issue: 40, Pages: 17077 - 17084

Swansea University Authors: Matt Carnie Orcid Logo, Cecile Charbonneau Orcid Logo, Matthew Davies Orcid Logo, David Worsley Orcid Logo, Trystan Watson Orcid Logo

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DOI (Published version): 10.1039/C4TA03387F

Abstract

High efficiency, solution processed organic–inorganic trihalide perovskite solar cells are now a reality, meaning that perovskite photovoltaics have the potential to challenge more established photovoltaic technologies. To date, some of the most efficient solution processed perovskite solar cells fe...

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Published in: J. Mater. Chem. A
ISSN: 2050-7488 2050-7496
Published: 2014
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URI: https://cronfa.swan.ac.uk/Record/cronfa18690
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spelling 2020-09-17T10:53:45.7946636 v2 18690 2014-10-10 Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles 73b367694366a646b90bb15db32bb8c0 0000-0002-4232-1967 Matt Carnie Matt Carnie true false 4dc059714847cb22ed922ab058950560 0000-0001-9887-2007 Cecile Charbonneau Cecile Charbonneau true false 4ad478e342120ca3434657eb13527636 0000-0003-2595-5121 Matthew Davies Matthew Davies true false c426b1c1b0123d7057c1b969083cea69 0000-0002-9956-6228 David Worsley David Worsley true false a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false 2014-10-10 MTLS High efficiency, solution processed organic–inorganic trihalide perovskite solar cells are now a reality, meaning that perovskite photovoltaics have the potential to challenge more established photovoltaic technologies. To date, some of the most efficient solution processed perovskite solar cells feature a pre-deposited Al2O3 scaffold and we have shown in a previous communication, that it is possible to make efficient devices by co-depositing the Al2O3 nanoparticles with the perovskite precursor solution. In this work, we have substituted the alumina nanoparticles with 3-aminopropyl (3-oxobutanoic acid) functionalized silica nanoparticles (f-SiO2). We observe performance enhancements in planar heterojunction (PHJ) devices made with up to 0.75 wt% f-SiO2 nanoparticles present in the precursor solution, yielding power conversion efficiencies (PCE) of up to 12.4%, compared to the maximum PCE of 10.5% in the equivalent PHJ devices made without f-SiO2 nanoparticles. The performance enhancement arises in part from an average increase to VOC by up to 50 mV when the nanoparticles are present in the precursor solution and is attributed to substrate passivation within pinholes formed in the perovskite film during processing. Journal Article J. Mater. Chem. A 2 40 17077 17084 2050-7488 2050-7496 28 10 2014 2014-10-28 10.1039/C4TA03387F COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2020-09-17T10:53:45.7946636 2014-10-10T22:24:37.1935047 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Matt Carnie 0000-0002-4232-1967 1 Cecile Charbonneau 0000-0001-9887-2007 2 Matthew Davies 0000-0003-2595-5121 3 Brian O' Regan 4 David Worsley 0000-0002-9956-6228 5 Trystan Watson 0000-0002-8015-1436 6
title Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
spellingShingle Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
Matt Carnie
Cecile Charbonneau
Matthew Davies
David Worsley
Trystan Watson
title_short Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
title_full Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
title_fullStr Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
title_full_unstemmed Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
title_sort Performance enhancement of solution processed perovskite solar cells incorporating functionalized silica nanoparticles
author_id_str_mv 73b367694366a646b90bb15db32bb8c0
4dc059714847cb22ed922ab058950560
4ad478e342120ca3434657eb13527636
c426b1c1b0123d7057c1b969083cea69
a210327b52472cfe8df9b8108d661457
author_id_fullname_str_mv 73b367694366a646b90bb15db32bb8c0_***_Matt Carnie
4dc059714847cb22ed922ab058950560_***_Cecile Charbonneau
4ad478e342120ca3434657eb13527636_***_Matthew Davies
c426b1c1b0123d7057c1b969083cea69_***_David Worsley
a210327b52472cfe8df9b8108d661457_***_Trystan Watson
author Matt Carnie
Cecile Charbonneau
Matthew Davies
David Worsley
Trystan Watson
author2 Matt Carnie
Cecile Charbonneau
Matthew Davies
Brian O' Regan
David Worsley
Trystan Watson
format Journal article
container_title J. Mater. Chem. A
container_volume 2
container_issue 40
container_start_page 17077
publishDate 2014
institution Swansea University
issn 2050-7488
2050-7496
doi_str_mv 10.1039/C4TA03387F
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
active_str 0
description High efficiency, solution processed organic–inorganic trihalide perovskite solar cells are now a reality, meaning that perovskite photovoltaics have the potential to challenge more established photovoltaic technologies. To date, some of the most efficient solution processed perovskite solar cells feature a pre-deposited Al2O3 scaffold and we have shown in a previous communication, that it is possible to make efficient devices by co-depositing the Al2O3 nanoparticles with the perovskite precursor solution. In this work, we have substituted the alumina nanoparticles with 3-aminopropyl (3-oxobutanoic acid) functionalized silica nanoparticles (f-SiO2). We observe performance enhancements in planar heterojunction (PHJ) devices made with up to 0.75 wt% f-SiO2 nanoparticles present in the precursor solution, yielding power conversion efficiencies (PCE) of up to 12.4%, compared to the maximum PCE of 10.5% in the equivalent PHJ devices made without f-SiO2 nanoparticles. The performance enhancement arises in part from an average increase to VOC by up to 50 mV when the nanoparticles are present in the precursor solution and is attributed to substrate passivation within pinholes formed in the perovskite film during processing.
published_date 2014-10-28T03:21:56Z
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score 11.016235

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