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A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion

Francesco Galiano, Alberto Figoli, Shamim Ahmed Deowan, Daniel Johnson Orcid Logo, Sacide Alsoy Altinkaya, Lucia Veltri, Giorgio De Luca, Raffaella Mancuso, Nidal Hilal, Bartolo Gabriele, Jan Hoinkis

Journal of Membrane Science, Volume: 482, Pages: 103 - 114

Swansea University Authors: Daniel Johnson Orcid Logo, Nidal Hilal

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DOI (Published version): 10.1016/j.memsci.2015.02.019

Abstract

An innovative hydrophilic and anti-fouling coating material for application in membrane technology for wastewater treatment has been developed by polymerization of a polymerizable bicontinuous microemulsion (PBM) and used for surface modification of a commercial flat polyethersulfone (PES) membrane....

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Published in: Journal of Membrane Science
Published: 2015
URI: https://cronfa.swan.ac.uk/Record/cronfa20304
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first_indexed 2015-03-17T03:03:19Z
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spelling 2018-05-13T05:02:53.6357567 v2 20304 2015-03-12 A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion 4bdcc306062428d2715b0dd308cc092f 0000-0001-6921-0389 Daniel Johnson Daniel Johnson true false 3acba771241d878c8e35ff464aec0342 Nidal Hilal Nidal Hilal true false 2015-03-12 An innovative hydrophilic and anti-fouling coating material for application in membrane technology for wastewater treatment has been developed by polymerization of a polymerizable bicontinuous microemulsion (PBM) and used for surface modification of a commercial flat polyethersulfone (PES) membrane. The novel nanostructured coating has been produced using acryloyloxyundecyltriethylammonium bromide (AUTEAB) as a co-polymerizable surfactant, obtained through a synthetic method characterized by a lower cost and a higher reproducibility compared to other known polymerizable surfactants. The novel composite membranes have been characterized and compared with the uncoated PES membranes. Coated membranes resulted in a smoother surface and a higher hydrophilicity with respect to the uncoated ones, and showed a particular nano-size channel-like morphology making them highly resistant to the fouling phenomenon. The covalent anchorage of the surfactant on the membrane surface ensured the embedment of the molecule in the polymeric matrix avoiding its leaching and also leading the coated membranes to have significant antimicrobial activity, which is very important for reducing the biofouling phenomenon.All these aspects make the tailored coating material an ideal and efficient coating for modifications of commercial membrane surfaces, to be used in membrane processes in wastewater treatment. Journal Article Journal of Membrane Science 482 103 114 15 5 2015 2015-05-15 10.1016/j.memsci.2015.02.019 COLLEGE NANME COLLEGE CODE Swansea University 2018-05-13T05:02:53.6357567 2015-03-12T10:14:52.7873489 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Francesco Galiano 1 Alberto Figoli 2 Shamim Ahmed Deowan 3 Daniel Johnson 0000-0001-6921-0389 4 Sacide Alsoy Altinkaya 5 Lucia Veltri 6 Giorgio De Luca 7 Raffaella Mancuso 8 Nidal Hilal 9 Bartolo Gabriele 10 Jan Hoinkis 11
title A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
spellingShingle A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
Daniel Johnson
Nidal Hilal
title_short A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
title_full A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
title_fullStr A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
title_full_unstemmed A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
title_sort A step forward to a more efficient wastewater treatment by membrane surface modification via polymerizable bicontinuous microemulsion
author_id_str_mv 4bdcc306062428d2715b0dd308cc092f
3acba771241d878c8e35ff464aec0342
author_id_fullname_str_mv 4bdcc306062428d2715b0dd308cc092f_***_Daniel Johnson
3acba771241d878c8e35ff464aec0342_***_Nidal Hilal
author Daniel Johnson
Nidal Hilal
author2 Francesco Galiano
Alberto Figoli
Shamim Ahmed Deowan
Daniel Johnson
Sacide Alsoy Altinkaya
Lucia Veltri
Giorgio De Luca
Raffaella Mancuso
Nidal Hilal
Bartolo Gabriele
Jan Hoinkis
format Journal article
container_title Journal of Membrane Science
container_volume 482
container_start_page 103
publishDate 2015
institution Swansea University
doi_str_mv 10.1016/j.memsci.2015.02.019
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description An innovative hydrophilic and anti-fouling coating material for application in membrane technology for wastewater treatment has been developed by polymerization of a polymerizable bicontinuous microemulsion (PBM) and used for surface modification of a commercial flat polyethersulfone (PES) membrane. The novel nanostructured coating has been produced using acryloyloxyundecyltriethylammonium bromide (AUTEAB) as a co-polymerizable surfactant, obtained through a synthetic method characterized by a lower cost and a higher reproducibility compared to other known polymerizable surfactants. The novel composite membranes have been characterized and compared with the uncoated PES membranes. Coated membranes resulted in a smoother surface and a higher hydrophilicity with respect to the uncoated ones, and showed a particular nano-size channel-like morphology making them highly resistant to the fouling phenomenon. The covalent anchorage of the surfactant on the membrane surface ensured the embedment of the molecule in the polymeric matrix avoiding its leaching and also leading the coated membranes to have significant antimicrobial activity, which is very important for reducing the biofouling phenomenon.All these aspects make the tailored coating material an ideal and efficient coating for modifications of commercial membrane surfaces, to be used in membrane processes in wastewater treatment.
published_date 2015-05-15T03:23:56Z
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