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Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors

Shirin Alexander Orcid Logo, Charles W. Dunnill, Andrew Barron Orcid Logo, Charlie Dunnill Orcid Logo

Journal of Colloid and Interface Science, Volume: 466, Pages: 275 - 283

Swansea University Authors: Shirin Alexander Orcid Logo, Andrew Barron Orcid Logo, Charlie Dunnill Orcid Logo

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DOI (Published version): 10.1016/j.jcis.2015.12.038

Abstract

HypothesisThe assembly of temperature/pH sensitive complex microparticle structures through chemisorption and physisorption provides a responsive system that offers application as routes to immobilization of proppants in-situ.ExperimentsThermogravimetric analysis (TGA) and scanning electron microsco...

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Published in: Journal of Colloid and Interface Science
Published: 2016
Online Access: https://www.sciencedirect.com/science/article/pii/S0021979715304227
URI: https://cronfa.swan.ac.uk/Record/cronfa28029
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first_indexed 2016-05-19T01:22:45Z
last_indexed 2023-01-11T14:00:34Z
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spelling 2022-12-06T16:46:26.5138928 v2 28029 2016-05-18 Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors 0773cc55f7caf77817be08806b8b7497 0000-0002-4404-0026 Shirin Alexander Shirin Alexander true false 92e452f20936d688d36f91c78574241d 0000-0002-2018-8288 Andrew Barron Andrew Barron true false 0c4af8958eda0d2e914a5edc3210cd9e 0000-0003-4052-6931 Charlie Dunnill Charlie Dunnill true false 2016-05-18 CHEG HypothesisThe assembly of temperature/pH sensitive complex microparticle structures through chemisorption and physisorption provides a responsive system that offers application as routes to immobilization of proppants in-situ.ExperimentsThermogravimetric analysis (TGA) and scanning electron microscopy (SEM) along with energy dispersive X-ray analysis (EDX) have been used to characterize a series of bi-functionalized monolayers and/or multilayers grown on alumina microparticles and investigate the reactive nature of both temperature sensitive cross-linker (epoxy resin) with the layers and pH-responsive bridging layer (polyetheramine).FindingsThe bifunctional acids, behaving as molecular anchors, allow for a controlled reaction with a cross-linker (resin or polymer) with the formation of networks, which is either irreversible or reversible based on the nature of the cross-linker. The networks results in formation of porous hierarchical particles that offer a potential route to the creation of immobile proppant pack. Journal Article Journal of Colloid and Interface Science 466 275 283 15 3 2016 2016-03-15 10.1016/j.jcis.2015.12.038 https://www.sciencedirect.com/science/article/pii/S0021979715304227 COLLEGE NANME Chemical Engineering COLLEGE CODE CHEG Swansea University 2022-12-06T16:46:26.5138928 2016-05-18T14:08:49.9063253 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Shirin Alexander 0000-0002-4404-0026 1 Charles W. Dunnill 2 Andrew Barron 0000-0002-2018-8288 3 Charlie Dunnill 0000-0003-4052-6931 4
title Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
spellingShingle Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
Shirin Alexander
Andrew Barron
Charlie Dunnill
title_short Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
title_full Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
title_fullStr Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
title_full_unstemmed Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
title_sort Assembly of porous hierarchical copolymers/resin proppants: New approaches to smart proppant immobilization via molecular anchors
author_id_str_mv 0773cc55f7caf77817be08806b8b7497
92e452f20936d688d36f91c78574241d
0c4af8958eda0d2e914a5edc3210cd9e
author_id_fullname_str_mv 0773cc55f7caf77817be08806b8b7497_***_Shirin Alexander
92e452f20936d688d36f91c78574241d_***_Andrew Barron
0c4af8958eda0d2e914a5edc3210cd9e_***_Charlie Dunnill
author Shirin Alexander
Andrew Barron
Charlie Dunnill
author2 Shirin Alexander
Charles W. Dunnill
Andrew Barron
Charlie Dunnill
format Journal article
container_title Journal of Colloid and Interface Science
container_volume 466
container_start_page 275
publishDate 2016
institution Swansea University
doi_str_mv 10.1016/j.jcis.2015.12.038
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
url https://www.sciencedirect.com/science/article/pii/S0021979715304227
document_store_str 0
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description HypothesisThe assembly of temperature/pH sensitive complex microparticle structures through chemisorption and physisorption provides a responsive system that offers application as routes to immobilization of proppants in-situ.ExperimentsThermogravimetric analysis (TGA) and scanning electron microscopy (SEM) along with energy dispersive X-ray analysis (EDX) have been used to characterize a series of bi-functionalized monolayers and/or multilayers grown on alumina microparticles and investigate the reactive nature of both temperature sensitive cross-linker (epoxy resin) with the layers and pH-responsive bridging layer (polyetheramine).FindingsThe bifunctional acids, behaving as molecular anchors, allow for a controlled reaction with a cross-linker (resin or polymer) with the formation of networks, which is either irreversible or reversible based on the nature of the cross-linker. The networks results in formation of porous hierarchical particles that offer a potential route to the creation of immobile proppant pack.
published_date 2016-03-15T03:34:05Z
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