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Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures

Anna Lukowiak, Lidia Zur, Thi Tran, Marcello Meneghetti, Simone Berneschi, Gualtiero Nunzi Conti, Stefano Pelli, Cosimo Trono, B.N. Bhaktha, Daniele Zonta, Stefano Taccheo Orcid Logo, Giancarlo Righini, Maurizio Ferrari

Crystals, Volume: 7, Issue: 2, Start page: 61

Swansea University Author: Stefano Taccheo Orcid Logo

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DOI (Published version): 10.3390/cryst7020061

Abstract

Glass photonics are widespread, from everyday objects around us to high-tech specialized devices. Among different technologies, sol–gel synthesis allows for nanoscale materials engineering by exploiting its unique structures, such as transparent glass-ceramics, to tailor optical and electromagnetic...

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Published in: Crystals
ISSN: 2073-4352
Published: 2017
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa32358
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Abstract: Glass photonics are widespread, from everyday objects around us to high-tech specialized devices. Among different technologies, sol–gel synthesis allows for nanoscale materials engineering by exploiting its unique structures, such as transparent glass-ceramics, to tailor optical and electromagnetic properties and to boost photon-management yield. Here, we briefly discuss the state of the technology and show that the choice of the sol–gel as a synthesis method brings the advantage of process versatility regarding materials composition and ease of implementation. In this context, we present tin-dioxide–silica (SnO2–SiO2) glass-ceramic waveguides activated by europium ions (Eu3+). The focus is on the photorefractive properties of this system because its photoluminescence properties have already been discussed in the papers presented in the bibliography. The main findings include the high photosensitivity of sol–gel 25SnO2:75SiO2 glass-ceramic waveguides; the ultraviolet (UV)-induced refractive index change (Δn ~ −1.6 × 10−3), the easy fabrication process, and the low propagation losses (0.5 ± 0.2 dB/cm), that make this glass-ceramic an interesting photonic material for smart optical applications.
Keywords: sol–gel; SnO2–SiO2; transparent glass-ceramics; photorefractivity; planar waveguides; attenuation coefficient; Lorentz–Lorenz formula
College: Faculty of Science and Engineering
Issue: 2
Start Page: 61