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Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
ChemCatChem, Volume: 7, Issue: 24, Pages: 4039 - 4041
Swansea University Author: Russell Wakeham
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DOI (Published version): 10.1002/cctc.201500886
Abstract
cis-1,4-Butenediol is shown to be a highly active hydrogen source for asymmetric transfer hydrogenation in the reduction of ketones. With the use of a ruthenium catalyst, cis-1,4-butenediol is isomerised and subsequently oxidised to a lactone as an irreversible step, which provides the driving force...
Published in: | ChemCatChem |
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ISSN: | 1867-3880 |
Published: |
Wiley-Blackwell
2015
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Online Access: |
Check full text
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URI: | https://cronfa.swan.ac.uk/Record/cronfa32707 |
Abstract: |
cis-1,4-Butenediol is shown to be a highly active hydrogen source for asymmetric transfer hydrogenation in the reduction of ketones. With the use of a ruthenium catalyst, cis-1,4-butenediol is isomerised and subsequently oxidised to a lactone as an irreversible step, which provides the driving force for the asymmetric reduction of ketones. |
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College: |
Faculty of Science and Engineering |
Issue: |
24 |
Start Page: |
4039 |
End Page: |
4041 |