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The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks

M. Taddei, F. Costantino, F. Marmottini, A. Comotti, P. Sozzani, R. Vivani, Marco Taddei Orcid Logo

Chem. Commun., Volume: 50, Issue: 94, Pages: 14831 - 14834

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1039/c4cc06223j

Abstract

The first crystalline microporous zirconium phosphonate metal–organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remar...

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Published in: Chem. Commun.
ISSN: 1359-7345 1364-548X
Published: Royal Society of Chemistry (RSC) 2014
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URI: https://cronfa.swan.ac.uk/Record/cronfa32748
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Abstract: The first crystalline microporous zirconium phosphonate metal–organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.
College: Faculty of Science and Engineering
Issue: 94
Start Page: 14831
End Page: 14834