Journal article 974 views
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes
ACS Applied Materials & Interfaces, Volume: 2, Issue: 7, Pages: 1851 - 1856
Swansea University Author: Alvin Orbaek White
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DOI (Published version): 10.1021/am100128m
Abstract
A procedure for vertically aligned carbon nanotube (VA-CNT) production has been developed through liquid-phase deposition of alumoxanes (aluminum oxide hydroxides, boehmite) as a catalyst support. Through a simple spin-coating of alumoxane nanoparticles, uniform centimer-square thin film surfaces we...
Published in: | ACS Applied Materials & Interfaces |
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ISSN: | 1944-8244 1944-8252 |
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2010
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URI: | https://cronfa.swan.ac.uk/Record/cronfa32811 |
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<?xml version="1.0"?><rfc1807><datestamp>2017-03-30T16:11:30.0825745</datestamp><bib-version>v2</bib-version><id>32811</id><entry>2017-03-29</entry><title>Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes</title><swanseaauthors><author><sid>8414a23650d4403fdfe1a735dbd2e24e</sid><ORCID>0000-0001-6338-5970</ORCID><firstname>Alvin</firstname><surname>Orbaek White</surname><name>Alvin Orbaek White</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2017-03-29</date><deptcode>CHEG</deptcode><abstract>A procedure for vertically aligned carbon nanotube (VA-CNT) production has been developed through liquid-phase deposition of alumoxanes (aluminum oxide hydroxides, boehmite) as a catalyst support. Through a simple spin-coating of alumoxane nanoparticles, uniform centimer-square thin film surfaces were coated and used as supports for subsequent deposition of metal catalyst. Uniform VA-CNTs are observed to grow from this film following deposition of both conventional evaporated Fe catalyst, as well as premade Fe nanoparticles drop-dried from the liquid phase. The quality and uniformity of the VA-CNTs are comparable to growth from conventional evaporated layers of Al2O3. The combined use of alumoxane and Fe nanoparticles to coat surfaces represents an inexpensive and scalable approach to large-scale VA-CNT production that makes chemical vapor deposition significantly more competitive when compared to other CNT production techniques.</abstract><type>Journal Article</type><journal>ACS Applied Materials &amp; Interfaces</journal><volume>2</volume><journalNumber>7</journalNumber><paginationStart>1851</paginationStart><paginationEnd>1856</paginationEnd><publisher/><issnPrint>1944-8244</issnPrint><issnElectronic>1944-8252</issnElectronic><keywords>alumoxane; catalyst support; chemical vapor deposition; vertically aligned carbon nanotubes</keywords><publishedDay>31</publishedDay><publishedMonth>12</publishedMonth><publishedYear>2010</publishedYear><publishedDate>2010-12-31</publishedDate><doi>10.1021/am100128m</doi><url>http://www.scopus.com/inward/record.url?eid=2-s2.0-77956641504&amp;partnerID=MN8TOARS</url><notes/><college>COLLEGE NANME</college><department>Chemical Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>CHEG</DepartmentCode><institution>Swansea University</institution><apcterm/><lastEdited>2017-03-30T16:11:30.0825745</lastEdited><Created>2017-03-29T14:46:48.7250642</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Chemical Engineering</level></path><authors><author><firstname>N.T.</firstname><surname>Alvarez</surname><order>1</order></author><author><firstname>C.E.</firstname><surname>Hamilton</surname><order>2</order></author><author><firstname>C.L.</firstname><surname>Pint</surname><order>3</order></author><author><firstname>A.</firstname><surname>Orbaek</surname><order>4</order></author><author><firstname>J.</firstname><surname>Yao</surname><order>5</order></author><author><firstname>A.L.</firstname><surname>Frosinini</surname><order>6</order></author><author><firstname>A.R.</firstname><surname>Barron</surname><order>7</order></author><author><firstname>J.M.</firstname><surname>Tour</surname><order>8</order></author><author><firstname>R.H.</firstname><surname>Hauge</surname><order>9</order></author><author><firstname>Alvin</firstname><surname>Orbaek White</surname><orcid>0000-0001-6338-5970</orcid><order>10</order></author></authors><documents/><OutputDurs/></rfc1807> |
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2017-03-30T16:11:30.0825745 v2 32811 2017-03-29 Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes 8414a23650d4403fdfe1a735dbd2e24e 0000-0001-6338-5970 Alvin Orbaek White Alvin Orbaek White true false 2017-03-29 CHEG A procedure for vertically aligned carbon nanotube (VA-CNT) production has been developed through liquid-phase deposition of alumoxanes (aluminum oxide hydroxides, boehmite) as a catalyst support. Through a simple spin-coating of alumoxane nanoparticles, uniform centimer-square thin film surfaces were coated and used as supports for subsequent deposition of metal catalyst. Uniform VA-CNTs are observed to grow from this film following deposition of both conventional evaporated Fe catalyst, as well as premade Fe nanoparticles drop-dried from the liquid phase. The quality and uniformity of the VA-CNTs are comparable to growth from conventional evaporated layers of Al2O3. The combined use of alumoxane and Fe nanoparticles to coat surfaces represents an inexpensive and scalable approach to large-scale VA-CNT production that makes chemical vapor deposition significantly more competitive when compared to other CNT production techniques. Journal Article ACS Applied Materials & Interfaces 2 7 1851 1856 1944-8244 1944-8252 alumoxane; catalyst support; chemical vapor deposition; vertically aligned carbon nanotubes 31 12 2010 2010-12-31 10.1021/am100128m http://www.scopus.com/inward/record.url?eid=2-s2.0-77956641504&partnerID=MN8TOARS COLLEGE NANME Chemical Engineering COLLEGE CODE CHEG Swansea University 2017-03-30T16:11:30.0825745 2017-03-29T14:46:48.7250642 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering N.T. Alvarez 1 C.E. Hamilton 2 C.L. Pint 3 A. Orbaek 4 J. Yao 5 A.L. Frosinini 6 A.R. Barron 7 J.M. Tour 8 R.H. Hauge 9 Alvin Orbaek White 0000-0001-6338-5970 10 |
title |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes |
spellingShingle |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes Alvin Orbaek White |
title_short |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes |
title_full |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes |
title_fullStr |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes |
title_full_unstemmed |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes |
title_sort |
Wet Catalyst-Support Films for Production of Vertically Aligned Carbon Nanotubes |
author_id_str_mv |
8414a23650d4403fdfe1a735dbd2e24e |
author_id_fullname_str_mv |
8414a23650d4403fdfe1a735dbd2e24e_***_Alvin Orbaek White |
author |
Alvin Orbaek White |
author2 |
N.T. Alvarez C.E. Hamilton C.L. Pint A. Orbaek J. Yao A.L. Frosinini A.R. Barron J.M. Tour R.H. Hauge Alvin Orbaek White |
format |
Journal article |
container_title |
ACS Applied Materials & Interfaces |
container_volume |
2 |
container_issue |
7 |
container_start_page |
1851 |
publishDate |
2010 |
institution |
Swansea University |
issn |
1944-8244 1944-8252 |
doi_str_mv |
10.1021/am100128m |
college_str |
Faculty of Science and Engineering |
hierarchytype |
|
hierarchy_top_id |
facultyofscienceandengineering |
hierarchy_top_title |
Faculty of Science and Engineering |
hierarchy_parent_id |
facultyofscienceandengineering |
hierarchy_parent_title |
Faculty of Science and Engineering |
department_str |
School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering |
url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-77956641504&partnerID=MN8TOARS |
document_store_str |
0 |
active_str |
0 |
description |
A procedure for vertically aligned carbon nanotube (VA-CNT) production has been developed through liquid-phase deposition of alumoxanes (aluminum oxide hydroxides, boehmite) as a catalyst support. Through a simple spin-coating of alumoxane nanoparticles, uniform centimer-square thin film surfaces were coated and used as supports for subsequent deposition of metal catalyst. Uniform VA-CNTs are observed to grow from this film following deposition of both conventional evaporated Fe catalyst, as well as premade Fe nanoparticles drop-dried from the liquid phase. The quality and uniformity of the VA-CNTs are comparable to growth from conventional evaporated layers of Al2O3. The combined use of alumoxane and Fe nanoparticles to coat surfaces represents an inexpensive and scalable approach to large-scale VA-CNT production that makes chemical vapor deposition significantly more competitive when compared to other CNT production techniques. |
published_date |
2010-12-31T03:40:20Z |
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1763751829222457344 |
score |
11.035874 |