Journal article 1141 views 267 downloads
The role of fullerenes in the environmental stability of polymer:fullerene solar cells
,
Beth Rice,
Jiaying Wu,
Alexandre de Castro Maciel,
Sachetan M. Tuladhar,
Emily Speller,
James McGettrick ,
Justin Searle ,
Sebastian Pont ,
Trystan Watson ,
Thomas Kirchartz ,
James Durrant ,
Wing Chung Tsoi ,
Jenny Nelson ,
Zhe Li
Energy & Environmental Science, Volume: 11, Issue: 2, Pages: 417 - 428
Swansea University Authors:
Harrison Lee, Mark Wyatt , Emily Speller, James McGettrick , Justin Searle , Trystan Watson , James Durrant , Wing Chung Tsoi , Jenny Nelson , Zhe Li
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DOI (Published version): 10.1039/c7ee02983g
Abstract
Environmental stability is a common challenge for the commercialisation of low cost, encapsulation-free organic opto-electronic devices. Understanding the role of materials degradation is the key to address this challenge, but most such studies have been limited to conjugated polymers. Here we quant...
| Published in: | Energy & Environmental Science |
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| ISSN: | 1754-5692 1754-5706 |
| Published: |
Royal Society of Chemistry (RSC)
2018
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| Online Access: |
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa38000 |
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| Abstract: |
Environmental stability is a common challenge for the commercialisation of low cost, encapsulation-free organic opto-electronic devices. Understanding the role of materials degradation is the key to address this challenge, but most such studies have been limited to conjugated polymers. Here we quantitatively study the role of the common fullerene derivative PCBM in limiting the stability of benchmark organic solar cells, showing that a minor fraction (<1%) of photo-oxidised PCBM, induced by short exposure to either solar or ambient laboratory lighting conditions in air, consistent with typical processing and operating conditions, is sufficient to compromise device performance severely. We identify the effects of photo-oxidation of PCBM on its chemical structure, and connect this to specific changes in its electronic structure, which significantly alter the electron transport and recombination kinetics. The effect of photo-oxidation on device current–voltage characteristics, electron mobility and density of states could all be explained with the same model of photoinduced defects acting as trap states. Our results demonstrate that the photochemical instability of PCBM and chemically similar fullerenes remains a barrier for the commercialisation of organic opto-electronic devices. |
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| College: |
Faculty of Science and Engineering |
| Issue: |
2 |
| Start Page: |
417 |
| End Page: |
428 |