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Study of essential oils adsorption on three phosphate fertilizers

N. Benali, H. Ben Daoud, M. Farhati, Chedly Tizaoui Orcid Logo, M. Romdhane

Chemical Industry & Chemical Engineering Quarterly, Volume: 24, Issue: 1

Swansea University Author: Chedly Tizaoui Orcid Logo

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DOI (Published version): 10.2298/ciceq170207037b

Abstract

In this paper, we report the study of essential oils adsorption on three phosphate fertilizers: mono-ammonium phosphate, di-ammonium phosphate and triple super phosphate with the aim to prepare a bi-function product which can be used as a fertilizer and bio-pesticides. Essential oils were isolated b...

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Published in: Chemical Industry & Chemical Engineering Quarterly
ISSN: 1451-9372
Published: 2018
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URI: https://cronfa.swan.ac.uk/Record/cronfa39591
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last_indexed 2019-04-03T09:59:23Z
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fullrecord <?xml version="1.0"?><rfc1807><datestamp>2019-04-02T14:28:28.8886130</datestamp><bib-version>v2</bib-version><id>39591</id><entry>2018-04-26</entry><title>Study of essential oils adsorption on three phosphate fertilizers</title><swanseaauthors><author><sid>4b34a0286d3c0b0b081518fa6987031d</sid><ORCID>0000-0003-2159-7881</ORCID><firstname>Chedly</firstname><surname>Tizaoui</surname><name>Chedly Tizaoui</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2018-04-26</date><deptcode>CHEG</deptcode><abstract>In this paper, we report the study of essential oils adsorption on three phosphate fertilizers: mono-ammonium phosphate, di-ammonium phosphate and triple super phosphate with the aim to prepare a bi-function product which can be used as a fertilizer and bio-pesticides. Essential oils were isolated by steam distillation from Eucalyptus salubris and Artemisia herba.alba and analysed by GC-MS and GC-FID. About 12 and 22 constituents were identified and quantified in these oils, respectively. The kinetic adsorption study of essential oils showed that DAP and TSP exhibited high adsorption capacities compared with MAP (DAP (0.143 g/g) and TSP (0.139 g/g) for Eucalyptus salubris essential oil and (DAP (0.135 g/g) and TSP (0.134 g/g) for Artemisia herba-alba essential oil). The adsorption isotherms of all identified components in the Eucalyptus salubris essential oil were determined and the Langmuir and Freundlich models were used to describe the experimental data. Langmuir model fitted well the isotherms of the majority of the essential oil components (1,8-cineole, &#x3B1;-pinene, &#x3B2;-Pinene, isopinocarveol, &#x3B2;-eudesmol, &#x3B1;-phellandrene, Pinocarvone, P-cymene and Spathulenol) and only Terpineol and Globulol isotherm data followed the Freundlich model. The selectivity was affected by the abundance of each component in the crude essential oil and the polarity of terpenic components.</abstract><type>Journal Article</type><journal>Chemical Industry &amp; Chemical Engineering Quarterly</journal><volume>24</volume><journalNumber>1</journalNumber><publisher/><issnPrint>1451-9372</issnPrint><keywords>Adsorption; di-ammonium phosphate; Essential oil; isotherms; mono-ammonium phosphate; triple super phosphate fertilizers.</keywords><publishedDay>31</publishedDay><publishedMonth>12</publishedMonth><publishedYear>2018</publishedYear><publishedDate>2018-12-31</publishedDate><doi>10.2298/ciceq170207037b</doi><url/><notes/><college>COLLEGE NANME</college><department>Chemical Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>CHEG</DepartmentCode><institution>Swansea University</institution><apcterm/><lastEdited>2019-04-02T14:28:28.8886130</lastEdited><Created>2018-04-26T22:45:52.6133047</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Chemical Engineering</level></path><authors><author><firstname>N.</firstname><surname>Benali</surname><order>1</order></author><author><firstname>H.</firstname><surname>Ben Daoud</surname><order>2</order></author><author><firstname>M.</firstname><surname>Farhati</surname><order>3</order></author><author><firstname>Chedly</firstname><surname>Tizaoui</surname><orcid>0000-0003-2159-7881</orcid><order>4</order></author><author><firstname>M.</firstname><surname>Romdhane</surname><order>5</order></author></authors><documents><document><filename>0039591-28022019084105.pdf</filename><originalFilename>benali2018v2.pdf</originalFilename><uploaded>2019-02-28T08:41:05.4800000</uploaded><type>Output</type><contentLength>6479425</contentLength><contentType>application/pdf</contentType><version>Version of Record</version><cronfaStatus>true</cronfaStatus><embargoDate>2019-02-28T00:00:00.0000000</embargoDate><copyrightCorrect>true</copyrightCorrect><language>eng</language></document></documents><OutputDurs/></rfc1807>
spelling 2019-04-02T14:28:28.8886130 v2 39591 2018-04-26 Study of essential oils adsorption on three phosphate fertilizers 4b34a0286d3c0b0b081518fa6987031d 0000-0003-2159-7881 Chedly Tizaoui Chedly Tizaoui true false 2018-04-26 CHEG In this paper, we report the study of essential oils adsorption on three phosphate fertilizers: mono-ammonium phosphate, di-ammonium phosphate and triple super phosphate with the aim to prepare a bi-function product which can be used as a fertilizer and bio-pesticides. Essential oils were isolated by steam distillation from Eucalyptus salubris and Artemisia herba.alba and analysed by GC-MS and GC-FID. About 12 and 22 constituents were identified and quantified in these oils, respectively. The kinetic adsorption study of essential oils showed that DAP and TSP exhibited high adsorption capacities compared with MAP (DAP (0.143 g/g) and TSP (0.139 g/g) for Eucalyptus salubris essential oil and (DAP (0.135 g/g) and TSP (0.134 g/g) for Artemisia herba-alba essential oil). The adsorption isotherms of all identified components in the Eucalyptus salubris essential oil were determined and the Langmuir and Freundlich models were used to describe the experimental data. Langmuir model fitted well the isotherms of the majority of the essential oil components (1,8-cineole, α-pinene, β-Pinene, isopinocarveol, β-eudesmol, α-phellandrene, Pinocarvone, P-cymene and Spathulenol) and only Terpineol and Globulol isotherm data followed the Freundlich model. The selectivity was affected by the abundance of each component in the crude essential oil and the polarity of terpenic components. Journal Article Chemical Industry & Chemical Engineering Quarterly 24 1 1451-9372 Adsorption; di-ammonium phosphate; Essential oil; isotherms; mono-ammonium phosphate; triple super phosphate fertilizers. 31 12 2018 2018-12-31 10.2298/ciceq170207037b COLLEGE NANME Chemical Engineering COLLEGE CODE CHEG Swansea University 2019-04-02T14:28:28.8886130 2018-04-26T22:45:52.6133047 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering N. Benali 1 H. Ben Daoud 2 M. Farhati 3 Chedly Tizaoui 0000-0003-2159-7881 4 M. Romdhane 5 0039591-28022019084105.pdf benali2018v2.pdf 2019-02-28T08:41:05.4800000 Output 6479425 application/pdf Version of Record true 2019-02-28T00:00:00.0000000 true eng
title Study of essential oils adsorption on three phosphate fertilizers
spellingShingle Study of essential oils adsorption on three phosphate fertilizers
Chedly Tizaoui
title_short Study of essential oils adsorption on three phosphate fertilizers
title_full Study of essential oils adsorption on three phosphate fertilizers
title_fullStr Study of essential oils adsorption on three phosphate fertilizers
title_full_unstemmed Study of essential oils adsorption on three phosphate fertilizers
title_sort Study of essential oils adsorption on three phosphate fertilizers
author_id_str_mv 4b34a0286d3c0b0b081518fa6987031d
author_id_fullname_str_mv 4b34a0286d3c0b0b081518fa6987031d_***_Chedly Tizaoui
author Chedly Tizaoui
author2 N. Benali
H. Ben Daoud
M. Farhati
Chedly Tizaoui
M. Romdhane
format Journal article
container_title Chemical Industry & Chemical Engineering Quarterly
container_volume 24
container_issue 1
publishDate 2018
institution Swansea University
issn 1451-9372
doi_str_mv 10.2298/ciceq170207037b
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
document_store_str 1
active_str 0
description In this paper, we report the study of essential oils adsorption on three phosphate fertilizers: mono-ammonium phosphate, di-ammonium phosphate and triple super phosphate with the aim to prepare a bi-function product which can be used as a fertilizer and bio-pesticides. Essential oils were isolated by steam distillation from Eucalyptus salubris and Artemisia herba.alba and analysed by GC-MS and GC-FID. About 12 and 22 constituents were identified and quantified in these oils, respectively. The kinetic adsorption study of essential oils showed that DAP and TSP exhibited high adsorption capacities compared with MAP (DAP (0.143 g/g) and TSP (0.139 g/g) for Eucalyptus salubris essential oil and (DAP (0.135 g/g) and TSP (0.134 g/g) for Artemisia herba-alba essential oil). The adsorption isotherms of all identified components in the Eucalyptus salubris essential oil were determined and the Langmuir and Freundlich models were used to describe the experimental data. Langmuir model fitted well the isotherms of the majority of the essential oil components (1,8-cineole, α-pinene, β-Pinene, isopinocarveol, β-eudesmol, α-phellandrene, Pinocarvone, P-cymene and Spathulenol) and only Terpineol and Globulol isotherm data followed the Freundlich model. The selectivity was affected by the abundance of each component in the crude essential oil and the polarity of terpenic components.
published_date 2018-12-31T03:50:18Z
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score 11.035655

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