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Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping

Anahid Sabetghadam, Xinlei Liu, Angelica F. Orsi, Magdalena M. Lozinska, Timothy Johnson, Kaspar M. B. Jansen, Paul A. Wright, Mariolino Carta Orcid Logo, Neil B. McKeown, Freek Kapteijn, Jorge Gascon

Chemistry - A European Journal

Swansea University Author: Mariolino Carta Orcid Logo

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DOI (Published version): 10.1002/chem.201803006

Abstract

Membrane separation for gas purification is an energy‐efficient and environment‐friendly technology. However, the development of high performance membranes is still a great challenge. In principle, mixed matrix membranes (MMMs) have the potential to overcome current materials limitations, but in pra...

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Published in: Chemistry - A European Journal
ISSN: 09476539
Published: 2018
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URI: https://cronfa.swan.ac.uk/Record/cronfa41083
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first_indexed 2018-07-21T04:47:26Z
last_indexed 2018-08-23T04:55:18Z
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spelling 2018-08-21T10:47:05.6343364 v2 41083 2018-07-20 Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping 56aebf2bba457f395149bbecbfa6d3eb 0000-0003-0718-6971 Mariolino Carta Mariolino Carta true false 2018-07-20 CHEM Membrane separation for gas purification is an energy‐efficient and environment‐friendly technology. However, the development of high performance membranes is still a great challenge. In principle, mixed matrix membranes (MMMs) have the potential to overcome current materials limitations, but in practice there is no straightforward method to match the properties of fillers and polymers (the main components of MMMs) in such a way that the final membrane performance reflects the high performance of the microporous filler and the processability of the continuous polymer phase. This issue is especially important when high flux polymers are utilized. In this work, we demonstrate that the use of small amounts of a glassy polymer in combination with high performance PIM‐1 allow for the preparation of MOF based MMMs with superior separation properties and low aging rates under humid conditions, meeting the commercial target for post‐combustion CO2 capture. Journal Article Chemistry - A European Journal 09476539 31 12 2018 2018-12-31 10.1002/chem.201803006 https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803006 COLLEGE NANME Chemistry COLLEGE CODE CHEM Swansea University 2018-08-21T10:47:05.6343364 2018-07-20T19:40:31.4827706 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry Anahid Sabetghadam 1 Xinlei Liu 2 Angelica F. Orsi 3 Magdalena M. Lozinska 4 Timothy Johnson 5 Kaspar M. B. Jansen 6 Paul A. Wright 7 Mariolino Carta 0000-0003-0718-6971 8 Neil B. McKeown 9 Freek Kapteijn 10 Jorge Gascon 11 0041083-21082018104512.pdf TowardsHighPerformanceMOF.pdf 2018-08-21T10:45:12.3170000 Output 759305 application/pdf Accepted Manuscript true 2019-06-26T00:00:00.0000000 true eng
title Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
spellingShingle Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
Mariolino Carta
title_short Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
title_full Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
title_fullStr Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
title_full_unstemmed Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
title_sort Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping
author_id_str_mv 56aebf2bba457f395149bbecbfa6d3eb
author_id_fullname_str_mv 56aebf2bba457f395149bbecbfa6d3eb_***_Mariolino Carta
author Mariolino Carta
author2 Anahid Sabetghadam
Xinlei Liu
Angelica F. Orsi
Magdalena M. Lozinska
Timothy Johnson
Kaspar M. B. Jansen
Paul A. Wright
Mariolino Carta
Neil B. McKeown
Freek Kapteijn
Jorge Gascon
format Journal article
container_title Chemistry - A European Journal
publishDate 2018
institution Swansea University
issn 09476539
doi_str_mv 10.1002/chem.201803006
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry
url https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803006
document_store_str 1
active_str 0
description Membrane separation for gas purification is an energy‐efficient and environment‐friendly technology. However, the development of high performance membranes is still a great challenge. In principle, mixed matrix membranes (MMMs) have the potential to overcome current materials limitations, but in practice there is no straightforward method to match the properties of fillers and polymers (the main components of MMMs) in such a way that the final membrane performance reflects the high performance of the microporous filler and the processability of the continuous polymer phase. This issue is especially important when high flux polymers are utilized. In this work, we demonstrate that the use of small amounts of a glassy polymer in combination with high performance PIM‐1 allow for the preparation of MOF based MMMs with superior separation properties and low aging rates under humid conditions, meeting the commercial target for post‐combustion CO2 capture.
published_date 2018-12-31T03:52:22Z
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score 11.035655

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