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Metallic and organic coating development for high performance pre-finished steels. / Christopher James Taylor

Swansea University Author: Christopher James Taylor

Abstract

Organic coated steels are extremely popular in the construction industry due to their flexibility, cost, ease of construction and aesthetic nature. However the fact that they can be produced in many colours and finishes in large volumes slightly belies the complexity of the system itself. Many of th...

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Published: 2009
Institution: Swansea University
Degree level: Doctoral
Degree name: EngD
URI: https://cronfa.swan.ac.uk/Record/cronfa42304
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Many of the components have a degree of environmental sensitivity and therefore with the introduction and implementation of strict environmental legislation constant improvement is needed to keep in line or ahead of such directives. Improvement of the coating system from the substrate up is presented in this thesis. Initial work was undertaken to understand the species that would be released from an organic coating. To this end PVC based model coatings were produced and subjected to natural weathering for one year, the coatings were designed to degrade by addition of a U grade TiO2 to ensure that results were obtained during the period. The leachate species were monitored on a monthly basis and identified using inductively coupled plasma mass spectrometry (ICPMS). From this work it was found that pigmentation has an effect on the degradation of coatings. It was shown that monitoring of metallic run off is important as it provides details on species type, while some species can be identified as markers to photo-degradation of the coating. The comparison of stabilisers historic, present and novel using the same natural weathering method and testing period. Hydrotalcite was identified as a potential novel stabiliser for PVC based coatings. When compared to organotin based stabilisers as used in the past or Barium/Zinc based stabilisers that are currently used Hydrotalcite performed favourably both from a chemical and physical point of view. With regard to improving the coating system as a whole the next phase of work involved the identification of an optimum galvanised coating weight. Samples of Zn/Al galvanised steels with increasing coating weight were subjected to natural weathering for one year and the amount of zinc monitored monthly. Conventional hot dipped galvanised steel and Zalutite coatings were included in the sample field to provide further comparison points. A coating weight of 255 gm-2 was found to be the optimum with respect to the natural weathering, while Zalutite which contains a high aluminium addition performed best overall. This gave rise to the next section of work that involved used of the Scanning Vibrating Electrode Technique (SVET) to characterise the corrosion performance of galvanised coatings with aluminium additions greater than 4.8%. It was found that increasing the aluminium content improved both surface and cut edge corrosion. Under the parameters under which the samples were produced a wholly eutectic structure was achieved at a target addition of 6.1%. The final phase of work was a study on reducing the coating thickness of the high aluminium coatings to see if the improvement in corrosion performance attributed to increased aluminium addition carried across to thinner coatings. The samples were again tested using the SVET. 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spelling 2018-08-02T16:24:28.7605873 v2 42304 2018-08-02 Metallic and organic coating development for high performance pre-finished steels. 2746aa59ec0a45ffe4fc63bf21bb1967 NULL Christopher James Taylor Christopher James Taylor true true 2018-08-02 Organic coated steels are extremely popular in the construction industry due to their flexibility, cost, ease of construction and aesthetic nature. However the fact that they can be produced in many colours and finishes in large volumes slightly belies the complexity of the system itself. Many of the components have a degree of environmental sensitivity and therefore with the introduction and implementation of strict environmental legislation constant improvement is needed to keep in line or ahead of such directives. Improvement of the coating system from the substrate up is presented in this thesis. Initial work was undertaken to understand the species that would be released from an organic coating. To this end PVC based model coatings were produced and subjected to natural weathering for one year, the coatings were designed to degrade by addition of a U grade TiO2 to ensure that results were obtained during the period. The leachate species were monitored on a monthly basis and identified using inductively coupled plasma mass spectrometry (ICPMS). From this work it was found that pigmentation has an effect on the degradation of coatings. It was shown that monitoring of metallic run off is important as it provides details on species type, while some species can be identified as markers to photo-degradation of the coating. The comparison of stabilisers historic, present and novel using the same natural weathering method and testing period. Hydrotalcite was identified as a potential novel stabiliser for PVC based coatings. When compared to organotin based stabilisers as used in the past or Barium/Zinc based stabilisers that are currently used Hydrotalcite performed favourably both from a chemical and physical point of view. With regard to improving the coating system as a whole the next phase of work involved the identification of an optimum galvanised coating weight. Samples of Zn/Al galvanised steels with increasing coating weight were subjected to natural weathering for one year and the amount of zinc monitored monthly. Conventional hot dipped galvanised steel and Zalutite coatings were included in the sample field to provide further comparison points. A coating weight of 255 gm-2 was found to be the optimum with respect to the natural weathering, while Zalutite which contains a high aluminium addition performed best overall. This gave rise to the next section of work that involved used of the Scanning Vibrating Electrode Technique (SVET) to characterise the corrosion performance of galvanised coatings with aluminium additions greater than 4.8%. It was found that increasing the aluminium content improved both surface and cut edge corrosion. Under the parameters under which the samples were produced a wholly eutectic structure was achieved at a target addition of 6.1%. The final phase of work was a study on reducing the coating thickness of the high aluminium coatings to see if the improvement in corrosion performance attributed to increased aluminium addition carried across to thinner coatings. The samples were again tested using the SVET. The results suggest that there is some scope for reducing the coating thickness at certain aluminium levels. E-Thesis Materials science. 31 12 2009 2009-12-31 COLLEGE NANME Engineering COLLEGE CODE Swansea University Doctoral EngD 2018-08-02T16:24:28.7605873 2018-08-02T16:24:28.7605873 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Christopher James Taylor NULL 1 0042304-02082018162443.pdf 10798012.pdf 2018-08-02T16:24:43.9570000 Output 24248444 application/pdf E-Thesis true 2018-08-02T16:24:43.9570000 false
title Metallic and organic coating development for high performance pre-finished steels.
spellingShingle Metallic and organic coating development for high performance pre-finished steels.
Christopher James Taylor
title_short Metallic and organic coating development for high performance pre-finished steels.
title_full Metallic and organic coating development for high performance pre-finished steels.
title_fullStr Metallic and organic coating development for high performance pre-finished steels.
title_full_unstemmed Metallic and organic coating development for high performance pre-finished steels.
title_sort Metallic and organic coating development for high performance pre-finished steels.
author_id_str_mv 2746aa59ec0a45ffe4fc63bf21bb1967
author_id_fullname_str_mv 2746aa59ec0a45ffe4fc63bf21bb1967_***_Christopher James Taylor
author Christopher James Taylor
author2 Christopher James Taylor
format E-Thesis
publishDate 2009
institution Swansea University
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
active_str 0
description Organic coated steels are extremely popular in the construction industry due to their flexibility, cost, ease of construction and aesthetic nature. However the fact that they can be produced in many colours and finishes in large volumes slightly belies the complexity of the system itself. Many of the components have a degree of environmental sensitivity and therefore with the introduction and implementation of strict environmental legislation constant improvement is needed to keep in line or ahead of such directives. Improvement of the coating system from the substrate up is presented in this thesis. Initial work was undertaken to understand the species that would be released from an organic coating. To this end PVC based model coatings were produced and subjected to natural weathering for one year, the coatings were designed to degrade by addition of a U grade TiO2 to ensure that results were obtained during the period. The leachate species were monitored on a monthly basis and identified using inductively coupled plasma mass spectrometry (ICPMS). From this work it was found that pigmentation has an effect on the degradation of coatings. It was shown that monitoring of metallic run off is important as it provides details on species type, while some species can be identified as markers to photo-degradation of the coating. The comparison of stabilisers historic, present and novel using the same natural weathering method and testing period. Hydrotalcite was identified as a potential novel stabiliser for PVC based coatings. When compared to organotin based stabilisers as used in the past or Barium/Zinc based stabilisers that are currently used Hydrotalcite performed favourably both from a chemical and physical point of view. With regard to improving the coating system as a whole the next phase of work involved the identification of an optimum galvanised coating weight. Samples of Zn/Al galvanised steels with increasing coating weight were subjected to natural weathering for one year and the amount of zinc monitored monthly. Conventional hot dipped galvanised steel and Zalutite coatings were included in the sample field to provide further comparison points. A coating weight of 255 gm-2 was found to be the optimum with respect to the natural weathering, while Zalutite which contains a high aluminium addition performed best overall. This gave rise to the next section of work that involved used of the Scanning Vibrating Electrode Technique (SVET) to characterise the corrosion performance of galvanised coatings with aluminium additions greater than 4.8%. It was found that increasing the aluminium content improved both surface and cut edge corrosion. Under the parameters under which the samples were produced a wholly eutectic structure was achieved at a target addition of 6.1%. The final phase of work was a study on reducing the coating thickness of the high aluminium coatings to see if the improvement in corrosion performance attributed to increased aluminium addition carried across to thinner coatings. The samples were again tested using the SVET. The results suggest that there is some scope for reducing the coating thickness at certain aluminium levels.
published_date 2009-12-31T03:52:42Z
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score 11.036334

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