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Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction

Zhiyong Liu, Tingwei He, Huihui Wang, Sagar Jain, Kaikai Liu, Jien Yang, Na Zhang, Hairui Liu, Mingjian Yuan

Journal of Power Sources, Volume: 401, Pages: 303 - 311

Swansea University Author: Sagar Jain

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DOI (Published version): 10.1016/j.jpowsour.2018.09.007

Abstract

Zinc oxide (ZnO) as an electron transport material has been used in regular planar perovskite solar cells (PSCs). Herein, ZnO nanoparticles serve as an additive directly in perovskite active layer in order to fabricate a bulkheterojunction inverted planar PSC. The CH3NH3PbI3-xClx:ZnO bulk heterojunc...

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Published in: Journal of Power Sources
ISSN: 0378-7753
Published: Elsevier 2018
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URI: https://cronfa.swan.ac.uk/Record/cronfa43751
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spelling 2018-11-05T13:28:52.6709662 v2 43751 2018-09-10 Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction 7073e179bb5b82db3e3efd3a8cd07139 Sagar Jain Sagar Jain true false 2018-09-10 EEN Zinc oxide (ZnO) as an electron transport material has been used in regular planar perovskite solar cells (PSCs). Herein, ZnO nanoparticles serve as an additive directly in perovskite active layer in order to fabricate a bulkheterojunction inverted planar PSC. The CH3NH3PbI3-xClx:ZnO bulk heterojunction is prepared by mixing ZnO nanoparticles into CH3NH3PbI3-xClx precursor solution. ZnOnanoparticles act as catalytic centers and induce the growth of perovskite grains leading to the formation of large-size perovskite crystals. Remarkably, hysterysisfree power conversion efficiency of 17.26% is achieved when precisely control the concentration of ZnO nanoparticles in CH3NH3PbIxCl3-x:ZnO bulk heterojunction active layer. The presence of ZnO nanoparticles in the perovskite films enhances the conductivity and electron mobility. Efficient charge injection of CH3NH3PbIxCl3x:ZnO film can improve charge extraction in the PSCs. Moreover, the PSCs with CH3NH3PbIxCl3-x:ZnO bulk heterojunction exhibit high fill factor of 77.3% and short current density of 22.71mAcm−2, which is attributed to improved perovskite quality. The bulk heterojunction structure is fabricated by combining perovskite and metal oxides, which is of great importance to the development and commercialization of PSCs in the future. Journal Article Journal of Power Sources 401 303 311 Elsevier 0378-7753 Perovskite solar cell, Zinc oxide, Bulk heterojunction Absorption, Electron mobility 15 10 2018 2018-10-15 10.1016/j.jpowsour.2018.09.007 https://www.sciencedirect.com/science/article/pii/S0378775318309789?via%3Dihub COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2018-11-05T13:28:52.6709662 2018-09-10T22:09:47.7806478 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Zhiyong Liu 1 Tingwei He 2 Huihui Wang 3 Sagar Jain 4 Kaikai Liu 5 Jien Yang 6 Na Zhang 7 Hairui Liu 8 Mingjian Yuan 9 0043751-10092018221127.pdf Invertedplanarperovskitesolarcells.pdf 2018-09-10T22:11:27.1870000 Output 3437097 application/pdf Accepted Manuscript true 2019-09-06T00:00:00.0000000 true eng
title Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
spellingShingle Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
Sagar Jain
title_short Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
title_full Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
title_fullStr Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
title_full_unstemmed Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
title_sort Improvement in the performance of inverted planar perovskite solar cells via the CH3NH3PbI3-xClx:ZnO bulk heterojunction
author_id_str_mv 7073e179bb5b82db3e3efd3a8cd07139
author_id_fullname_str_mv 7073e179bb5b82db3e3efd3a8cd07139_***_Sagar Jain
author Sagar Jain
author2 Zhiyong Liu
Tingwei He
Huihui Wang
Sagar Jain
Kaikai Liu
Jien Yang
Na Zhang
Hairui Liu
Mingjian Yuan
format Journal article
container_title Journal of Power Sources
container_volume 401
container_start_page 303
publishDate 2018
institution Swansea University
issn 0378-7753
doi_str_mv 10.1016/j.jpowsour.2018.09.007
publisher Elsevier
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
url https://www.sciencedirect.com/science/article/pii/S0378775318309789?via%3Dihub
document_store_str 1
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description Zinc oxide (ZnO) as an electron transport material has been used in regular planar perovskite solar cells (PSCs). Herein, ZnO nanoparticles serve as an additive directly in perovskite active layer in order to fabricate a bulkheterojunction inverted planar PSC. The CH3NH3PbI3-xClx:ZnO bulk heterojunction is prepared by mixing ZnO nanoparticles into CH3NH3PbI3-xClx precursor solution. ZnOnanoparticles act as catalytic centers and induce the growth of perovskite grains leading to the formation of large-size perovskite crystals. Remarkably, hysterysisfree power conversion efficiency of 17.26% is achieved when precisely control the concentration of ZnO nanoparticles in CH3NH3PbIxCl3-x:ZnO bulk heterojunction active layer. The presence of ZnO nanoparticles in the perovskite films enhances the conductivity and electron mobility. Efficient charge injection of CH3NH3PbIxCl3x:ZnO film can improve charge extraction in the PSCs. Moreover, the PSCs with CH3NH3PbIxCl3-x:ZnO bulk heterojunction exhibit high fill factor of 77.3% and short current density of 22.71mAcm−2, which is attributed to improved perovskite quality. The bulk heterojunction structure is fabricated by combining perovskite and metal oxides, which is of great importance to the development and commercialization of PSCs in the future.
published_date 2018-10-15T03:55:05Z
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