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Low temperature sintering of aqueous TiO2 colloids for flexible, co-sensitized dye-sensitized solar cells

Peter Holliman Orcid Logo, Arthur Connell, Matthew Davies Orcid Logo, Matt Carnie Orcid Logo, Daniel Bryant, Eurig Wyn Jones

Materials Letters, Volume: 236, Pages: 289 - 291

Swansea University Authors: Peter Holliman Orcid Logo, Matthew Davies Orcid Logo, Matt Carnie Orcid Logo

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Abstract

Colloidal TiO2 films have been prepared using a binder-free aqueous paste with Degussa P25 and hexafluorotitanic acid (H2TiF6), which was optimised for different substrates. Dye-sensitized solar cells (DSSC) fabricated using this paste were sintered at (ca. 393 K) and efficiencies (η) of 3.0, 4.2 an...

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Published in: Materials Letters
ISSN: 0167-577X
Published: 2019
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa45210
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Abstract: Colloidal TiO2 films have been prepared using a binder-free aqueous paste with Degussa P25 and hexafluorotitanic acid (H2TiF6), which was optimised for different substrates. Dye-sensitized solar cells (DSSC) fabricated using this paste were sintered at (ca. 393 K) and efficiencies (η) of 3.0, 4.2 and 6.1% were measured for devices using titanium foil (ca. 1 mm thickness), indium-doped tin oxide on polyethylene terephthalate (ITO-PET), and for co-sensitized devices on fluorine-doped tin oxide (FTO) glass substrates, respectively. Electrochemical impedance measurements show that the charge transport resistance is less consistent for devices fabricated at low sintering temperature (ca. 393 K) by comparison to devices sintered at 773 K. These measurements correlate with the increased variation in device efficiency (η) for low temperature sintered DSSC devices.
Keywords: Solar energy, Manufacturing, Flexible substrates, Chemical sintering
College: Faculty of Science and Engineering
Start Page: 289
End Page: 291