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Hydrolytic stability in hemilabile metal–organic frameworks

Lauren N. McHugh, Matthew McPherson Orcid Logo, Laura J. McCormick, Samuel A. Morris, Paul S. Wheatley, Simon J. Teat, David McKay, Daniel M. Dawson, Charlotte E. F. Sansome, Sharon E. Ashbrook, Corinne A. Stone, Martin W. Smith, Russell E. Morris

Nature Chemistry, Volume: 10, Issue: 11, Pages: 1096 - 1102

Swansea University Author: Matthew McPherson Orcid Logo

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DOI (Published version): 10.1038/s41557-018-0104-x

Abstract

Highly porous metal–organic frameworks (MOFs), which have undergone exciting developments over the past few decades, show promise for a wide range of applications. However, many studies indicate that they suffer from significant stability issues, especially with respect to their interactions with wa...

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Published in: Nature Chemistry
ISSN: 1755-4330 1755-4349
Published: 2018
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URI: https://cronfa.swan.ac.uk/Record/cronfa49833
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last_indexed 2019-07-18T21:33:38Z
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spelling 2019-07-18T14:40:14.1313772 v2 49833 2019-04-01 Hydrolytic stability in hemilabile metal–organic frameworks 69886ed1df27345672e1a52ddee565fe 0000-0002-7529-5355 Matthew McPherson Matthew McPherson true false 2019-04-01 EEN Highly porous metal–organic frameworks (MOFs), which have undergone exciting developments over the past few decades, show promise for a wide range of applications. However, many studies indicate that they suffer from significant stability issues, especially with respect to their interactions with water, which severely limits their practical potential. Here we demonstrate how the presence of ‘sacrificial’ bonds in the coordination environment of its metal centres (referred to as hemilability) endows a dehydrated copper-based MOF with good hydrolytic stability. On exposure to water, in contrast to the indiscriminate breaking of coordination bonds that typically results in structure degradation, it is non-structural weak interactions between the MOF’s copper paddlewheel clusters that are broken and the framework recovers its as-synthesized, hydrated structure. This MOF retained its structural integrity even after contact with water for one year, whereas HKUST-1, a compositionally similar material that lacks these sacrificial bonds, loses its crystallinity in less than a day under the same conditions. Journal Article Nature Chemistry 10 11 1096 1102 1755-4330 1755-4349 13 11 2018 2018-11-13 10.1038/s41557-018-0104-x https://research-repository.st-andrews.ac.uk/handle/10023/17048 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2019-07-18T14:40:14.1313772 2019-04-01T11:05:40.5989151 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Lauren N. McHugh 1 Matthew McPherson 0000-0002-7529-5355 2 Laura J. McCormick 3 Samuel A. Morris 4 Paul S. Wheatley 5 Simon J. Teat 6 David McKay 7 Daniel M. Dawson 8 Charlotte E. F. Sansome 9 Sharon E. Ashbrook 10 Corinne A. Stone 11 Martin W. Smith 12 Russell E. Morris 13 0049833-10052019154156.pdf mchugh2018.pdf 2019-05-10T15:41:56.7930000 Output 10977280 application/pdf Accepted Manuscript true 2019-05-10T00:00:00.0000000 true eng
title Hydrolytic stability in hemilabile metal–organic frameworks
spellingShingle Hydrolytic stability in hemilabile metal–organic frameworks
Matthew McPherson
title_short Hydrolytic stability in hemilabile metal–organic frameworks
title_full Hydrolytic stability in hemilabile metal–organic frameworks
title_fullStr Hydrolytic stability in hemilabile metal–organic frameworks
title_full_unstemmed Hydrolytic stability in hemilabile metal–organic frameworks
title_sort Hydrolytic stability in hemilabile metal–organic frameworks
author_id_str_mv 69886ed1df27345672e1a52ddee565fe
author_id_fullname_str_mv 69886ed1df27345672e1a52ddee565fe_***_Matthew McPherson
author Matthew McPherson
author2 Lauren N. McHugh
Matthew McPherson
Laura J. McCormick
Samuel A. Morris
Paul S. Wheatley
Simon J. Teat
David McKay
Daniel M. Dawson
Charlotte E. F. Sansome
Sharon E. Ashbrook
Corinne A. Stone
Martin W. Smith
Russell E. Morris
format Journal article
container_title Nature Chemistry
container_volume 10
container_issue 11
container_start_page 1096
publishDate 2018
institution Swansea University
issn 1755-4330
1755-4349
doi_str_mv 10.1038/s41557-018-0104-x
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
url https://research-repository.st-andrews.ac.uk/handle/10023/17048
document_store_str 1
active_str 0
description Highly porous metal–organic frameworks (MOFs), which have undergone exciting developments over the past few decades, show promise for a wide range of applications. However, many studies indicate that they suffer from significant stability issues, especially with respect to their interactions with water, which severely limits their practical potential. Here we demonstrate how the presence of ‘sacrificial’ bonds in the coordination environment of its metal centres (referred to as hemilability) endows a dehydrated copper-based MOF with good hydrolytic stability. On exposure to water, in contrast to the indiscriminate breaking of coordination bonds that typically results in structure degradation, it is non-structural weak interactions between the MOF’s copper paddlewheel clusters that are broken and the framework recovers its as-synthesized, hydrated structure. This MOF retained its structural integrity even after contact with water for one year, whereas HKUST-1, a compositionally similar material that lacks these sacrificial bonds, loses its crystallinity in less than a day under the same conditions.
published_date 2018-11-13T04:01:03Z
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score 11.012678

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