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Understanding the effect of carbon nanotube functionalization on copper electrodeposition

Ewa Kazimierska, Enrico Andreoli Orcid Logo, Andrew Barron

Journal of Applied Electrochemistry

Swansea University Authors: Ewa Kazimierska, Enrico Andreoli Orcid Logo, Andrew Barron

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DOI (Published version): 10.1007/s10800-019-01318-x

Abstract

The dynamics of electrochemical deposition and dissolution of copper in the presence of functionalized multiwalled carbon nanotubes in solution has been studied in detail using an electrochemical quartz crystal microbalance. Results demonstrate the central role of carbon nanotube functionalization o...

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Published in: Journal of Applied Electrochemistry
ISSN: 0021-891X 1572-8838
Published: 2019
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URI: https://cronfa.swan.ac.uk/Record/cronfa50517
first_indexed 2019-06-05T11:07:42Z
last_indexed 2019-07-18T21:35:42Z
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spelling 2019-07-18T15:53:04.8232215 v2 50517 2019-05-24 Understanding the effect of carbon nanotube functionalization on copper electrodeposition acd104d55246ee2d03420795510359e9 Ewa Kazimierska Ewa Kazimierska true false cbd843daab780bb55698a3daccd74df8 0000-0002-1207-2314 Enrico Andreoli Enrico Andreoli true false 92e452f20936d688d36f91c78574241d Andrew Barron Andrew Barron true false 2019-05-24 The dynamics of electrochemical deposition and dissolution of copper in the presence of functionalized multiwalled carbon nanotubes in solution has been studied in detail using an electrochemical quartz crystal microbalance. Results demonstrate the central role of carbon nanotube functionalization on the values of mass and current densities of copper deposition. Amine functionalization increases competitive hydrogen evolution without significantly affecting the total amount of deposited copper, whereas carboxylic functionalization clearly enhances the deposition of larger amounts of smoother copper deposits. Molar mass analysis of deposited species reveals interactions of carbon nanotubes with the electrode surface dependent on the type of functionalization. The effect of carbon nanotube functionalization should be closely considered in the development of electrochemical strategies for the integration of carbon nanotubes in metallic copper. Journal Article Journal of Applied Electrochemistry 0021-891X 1572-8838 31 12 2019 2019-12-31 10.1007/s10800-019-01318-x COLLEGE NANME COLLEGE CODE Swansea University 2019-07-18T15:53:04.8232215 2019-05-24T10:25:31.9193464 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Ewa Kazimierska 1 Enrico Andreoli 0000-0002-1207-2314 2 Andrew Barron 3 0050517-24052019103408.pdf kazimierska2019v2.pdf 2019-05-24T10:34:08.9300000 Output 5753321 application/pdf Version of Record true 2019-05-24T00:00:00.0000000 Distributed under the terms of a Creative Commons Attribution (CC-BY-4.0) true eng
title Understanding the effect of carbon nanotube functionalization on copper electrodeposition
spellingShingle Understanding the effect of carbon nanotube functionalization on copper electrodeposition
Ewa Kazimierska
Enrico Andreoli
Andrew Barron
title_short Understanding the effect of carbon nanotube functionalization on copper electrodeposition
title_full Understanding the effect of carbon nanotube functionalization on copper electrodeposition
title_fullStr Understanding the effect of carbon nanotube functionalization on copper electrodeposition
title_full_unstemmed Understanding the effect of carbon nanotube functionalization on copper electrodeposition
title_sort Understanding the effect of carbon nanotube functionalization on copper electrodeposition
author_id_str_mv acd104d55246ee2d03420795510359e9
cbd843daab780bb55698a3daccd74df8
92e452f20936d688d36f91c78574241d
author_id_fullname_str_mv acd104d55246ee2d03420795510359e9_***_Ewa Kazimierska
cbd843daab780bb55698a3daccd74df8_***_Enrico Andreoli
92e452f20936d688d36f91c78574241d_***_Andrew Barron
author Ewa Kazimierska
Enrico Andreoli
Andrew Barron
author2 Ewa Kazimierska
Enrico Andreoli
Andrew Barron
format Journal article
container_title Journal of Applied Electrochemistry
publishDate 2019
institution Swansea University
issn 0021-891X
1572-8838
doi_str_mv 10.1007/s10800-019-01318-x
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
document_store_str 1
active_str 0
description The dynamics of electrochemical deposition and dissolution of copper in the presence of functionalized multiwalled carbon nanotubes in solution has been studied in detail using an electrochemical quartz crystal microbalance. Results demonstrate the central role of carbon nanotube functionalization on the values of mass and current densities of copper deposition. Amine functionalization increases competitive hydrogen evolution without significantly affecting the total amount of deposited copper, whereas carboxylic functionalization clearly enhances the deposition of larger amounts of smoother copper deposits. Molar mass analysis of deposited species reveals interactions of carbon nanotubes with the electrode surface dependent on the type of functionalization. The effect of carbon nanotube functionalization should be closely considered in the development of electrochemical strategies for the integration of carbon nanotubes in metallic copper.
published_date 2019-12-31T07:48:44Z
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score 11.048085

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