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Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries

Ping Gao, Xiu-Mei Lin, Anji Munnangi Orcid Logo, Le Zhang, Thomas Diemant, R. Jürgen Behm, Maximilian Fichtner

Journal of The Electrochemical Society, Volume: 163, Issue: 10, Pages: A2326 - A2332

Swansea University Author: Anji Munnangi Orcid Logo

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DOI (Published version): 10.1149/2.0851610jes

Abstract

Here, we report on the electrochemical behavior of layered VOCl material as potential electrode material in rechargeable lithium-ion batteries. Orthorhombic VOCl with a space group of Pmmn was synthesized via a solid-gas reaction. During electrochemical charge and discharge a combination of intercal...

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Published in: Journal of The Electrochemical Society
ISSN: 0013-4651 1945-7111
Published: The Electrochemical Society 2016
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URI: https://cronfa.swan.ac.uk/Record/cronfa51581
first_indexed 2019-08-27T15:30:59Z
last_indexed 2019-09-04T14:49:35Z
id cronfa51581
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spelling 2019-09-04T11:55:34.3715041 v2 51581 2019-08-27 Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries 3ed0b4f2ff4fb9e87c7a73e7a3c39da7 0000-0001-9101-0252 Anji Munnangi Anji Munnangi true false 2019-08-27 EAAS Here, we report on the electrochemical behavior of layered VOCl material as potential electrode material in rechargeable lithium-ion batteries. Orthorhombic VOCl with a space group of Pmmn was synthesized via a solid-gas reaction. During electrochemical charge and discharge a combination of intercalation and conversion reactions are proposed to take place based on the data collected from a variety of analytical methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge spectroscopy (XANES), infrared spectroscopy (IR), Raman spectroscopy and electrochemical methods. The pseudocapacitive contribution to the Li+ storage was identified using a cyclic voltammetry (CV) technique. Charge and discharge tests showed that the VOCl electrode can deliver first discharge and recharge capacities of 1228 mAh g−1 and 759 mAh g−1 at a current density of 100 mA g−1, respectively. Even after 120 cycles at 260 mA g−1 a reversible capacity of 351 mAh g−1 can be obtained with a high coulombic efficiency (>98%). Journal Article Journal of The Electrochemical Society 163 10 A2326 A2332 The Electrochemical Society 0013-4651 1945-7111 anode, conversion reaction, Lithium ion battery, Vanadium oxychloride, VOCl 26 8 2016 2016-08-26 10.1149/2.0851610jes COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University 2019-09-04T11:55:34.3715041 2019-08-27T12:26:26.1824525 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Ping Gao 1 Xiu-Mei Lin 2 Anji Munnangi 0000-0001-9101-0252 3 Le Zhang 4 Thomas Diemant 5 R. Jürgen Behm 6 Maximilian Fichtner 7
title Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
spellingShingle Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
Anji Munnangi
title_short Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
title_full Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
title_fullStr Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
title_full_unstemmed Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
title_sort Electrochemical Behavior of Layered Vanadium Oxychloride in Rechargeable Lithium Ion Batteries
author_id_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7
author_id_fullname_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7_***_Anji Munnangi
author Anji Munnangi
author2 Ping Gao
Xiu-Mei Lin
Anji Munnangi
Le Zhang
Thomas Diemant
R. Jürgen Behm
Maximilian Fichtner
format Journal article
container_title Journal of The Electrochemical Society
container_volume 163
container_issue 10
container_start_page A2326
publishDate 2016
institution Swansea University
issn 0013-4651
1945-7111
doi_str_mv 10.1149/2.0851610jes
publisher The Electrochemical Society
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
active_str 0
description Here, we report on the electrochemical behavior of layered VOCl material as potential electrode material in rechargeable lithium-ion batteries. Orthorhombic VOCl with a space group of Pmmn was synthesized via a solid-gas reaction. During electrochemical charge and discharge a combination of intercalation and conversion reactions are proposed to take place based on the data collected from a variety of analytical methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge spectroscopy (XANES), infrared spectroscopy (IR), Raman spectroscopy and electrochemical methods. The pseudocapacitive contribution to the Li+ storage was identified using a cyclic voltammetry (CV) technique. Charge and discharge tests showed that the VOCl electrode can deliver first discharge and recharge capacities of 1228 mAh g−1 and 759 mAh g−1 at a current density of 100 mA g−1, respectively. Even after 120 cycles at 260 mA g−1 a reversible capacity of 351 mAh g−1 can be obtained with a high coulombic efficiency (>98%).
published_date 2016-08-26T04:40:34Z
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score 11.089572

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