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Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Mark V. Khenkin, Eugene A. Katz, Antonio Abate, Giorgio Bardizza, Joseph J. Berry, Christoph Brabec, Francesca Brunetti, Vladimir Bulović, Quinn Burlingame, Aldo Di Carlo, Rongrong Cheacharoen, Yi-Bing Cheng, Alexander Colsmann, Stephane Cros, Konrad Domanski, Michał Dusza, Christopher J. Fell, Stephen R. Forrest, Yulia Galagan, Diego Di Girolamo, Michael Grätzel, Anders Hagfeldt, Elizabeth von Hauff, Harald Hoppe, Jeff Kettle, Hans Köbler, Marina S. Leite, Shengzhong Liu, Yueh-Lin Loo, Joseph M. Luther, Chang-Qi Ma, Morten Madsen, Matthieu Manceau, Muriel Matheron, Michael McGehee, Rico Meitzner, Mohammad Khaja Nazeeruddin, Ana Flavia Nogueira, Çağla Odabaşı, Anna Osherov, Nam-Gyu Park, Matthew O. Reese, Francesca De Rossi Orcid Logo, Michael Saliba, Ulrich S. Schubert, Henry J. Snaith, Samuel D. Stranks, Wolfgang Tress, Pavel A. Troshin, Vida Turkovic, Sjoerd Veenstra, Iris Visoly-Fisher, Aron Walsh, Trystan Watson Orcid Logo, Haibing Xie, Ramazan Yıldırım, Shaik Mohammed Zakeeruddin, Kai Zhu, Monica Lira-Cantu

Nature Energy, Volume: 5, Issue: 1, Pages: 35 - 49

Swansea University Authors: Francesca De Rossi Orcid Logo, Trystan Watson Orcid Logo

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DOI (Published version): 10.1038/s41560-019-0529-5

Abstract

Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduc...

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Published in: Nature Energy
ISSN: 2058-7546
Published: Springer Science and Business Media LLC 2020
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spelling 2020-10-26T16:26:11.5221150 v2 53413 2020-02-03 Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures 04b56f7760ea2de5fd65985ff510d625 0000-0002-6591-5928 Francesca De Rossi Francesca De Rossi true false a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false 2020-02-03 EEN Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis. Journal Article Nature Energy 5 1 35 49 Springer Science and Business Media LLC 2058-7546 22 1 2020 2020-01-22 10.1038/s41560-019-0529-5 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2020-10-26T16:26:11.5221150 2020-02-03T15:08:39.5864066 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Mark V. Khenkin 1 Eugene A. Katz 2 Antonio Abate 3 Giorgio Bardizza 4 Joseph J. Berry 5 Christoph Brabec 6 Francesca Brunetti 7 Vladimir Bulović 8 Quinn Burlingame 9 Aldo Di Carlo 10 Rongrong Cheacharoen 11 Yi-Bing Cheng 12 Alexander Colsmann 13 Stephane Cros 14 Konrad Domanski 15 Michał Dusza 16 Christopher J. Fell 17 Stephen R. Forrest 18 Yulia Galagan 19 Diego Di Girolamo 20 Michael Grätzel 21 Anders Hagfeldt 22 Elizabeth von Hauff 23 Harald Hoppe 24 Jeff Kettle 25 Hans Köbler 26 Marina S. Leite 27 Shengzhong Liu 28 Yueh-Lin Loo 29 Joseph M. Luther 30 Chang-Qi Ma 31 Morten Madsen 32 Matthieu Manceau 33 Muriel Matheron 34 Michael McGehee 35 Rico Meitzner 36 Mohammad Khaja Nazeeruddin 37 Ana Flavia Nogueira 38 Çağla Odabaşı 39 Anna Osherov 40 Nam-Gyu Park 41 Matthew O. Reese 42 Francesca De Rossi 0000-0002-6591-5928 43 Michael Saliba 44 Ulrich S. Schubert 45 Henry J. Snaith 46 Samuel D. Stranks 47 Wolfgang Tress 48 Pavel A. Troshin 49 Vida Turkovic 50 Sjoerd Veenstra 51 Iris Visoly-Fisher 52 Aron Walsh 53 Trystan Watson 0000-0002-8015-1436 54 Haibing Xie 55 Ramazan Yıldırım 56 Shaik Mohammed Zakeeruddin 57 Kai Zhu 58 Monica Lira-Cantu 59 53413__16513__b4b0a551143c432894d7fdd1865d4ec9.pdf khenkin2020.pdf 2020-02-03T15:11:04.5100469 Output 2235967 application/pdf Version of Record true Released under the terms of a Creative Commons Attribution 4.0 International License (CC-BY). true eng http://creativecommons.org/licenses/by/4.0/
title Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
spellingShingle Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
Francesca De Rossi
Trystan Watson
title_short Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
title_full Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
title_fullStr Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
title_full_unstemmed Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
title_sort Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures
author_id_str_mv 04b56f7760ea2de5fd65985ff510d625
a210327b52472cfe8df9b8108d661457
author_id_fullname_str_mv 04b56f7760ea2de5fd65985ff510d625_***_Francesca De Rossi
a210327b52472cfe8df9b8108d661457_***_Trystan Watson
author Francesca De Rossi
Trystan Watson
author2 Mark V. Khenkin
Eugene A. Katz
Antonio Abate
Giorgio Bardizza
Joseph J. Berry
Christoph Brabec
Francesca Brunetti
Vladimir Bulović
Quinn Burlingame
Aldo Di Carlo
Rongrong Cheacharoen
Yi-Bing Cheng
Alexander Colsmann
Stephane Cros
Konrad Domanski
Michał Dusza
Christopher J. Fell
Stephen R. Forrest
Yulia Galagan
Diego Di Girolamo
Michael Grätzel
Anders Hagfeldt
Elizabeth von Hauff
Harald Hoppe
Jeff Kettle
Hans Köbler
Marina S. Leite
Shengzhong Liu
Yueh-Lin Loo
Joseph M. Luther
Chang-Qi Ma
Morten Madsen
Matthieu Manceau
Muriel Matheron
Michael McGehee
Rico Meitzner
Mohammad Khaja Nazeeruddin
Ana Flavia Nogueira
Çağla Odabaşı
Anna Osherov
Nam-Gyu Park
Matthew O. Reese
Francesca De Rossi
Michael Saliba
Ulrich S. Schubert
Henry J. Snaith
Samuel D. Stranks
Wolfgang Tress
Pavel A. Troshin
Vida Turkovic
Sjoerd Veenstra
Iris Visoly-Fisher
Aron Walsh
Trystan Watson
Haibing Xie
Ramazan Yıldırım
Shaik Mohammed Zakeeruddin
Kai Zhu
Monica Lira-Cantu
format Journal article
container_title Nature Energy
container_volume 5
container_issue 1
container_start_page 35
publishDate 2020
institution Swansea University
issn 2058-7546
doi_str_mv 10.1038/s41560-019-0529-5
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
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description Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.
published_date 2020-01-22T04:06:21Z
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score 11.028798

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