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Recent developments and future perspectives of anionic batteries

Guruprakash Karkera, Anji Munnangi Orcid Logo, Maximilian Fichtner

Journal of Power Sources, Volume: 481, Start page: 228877

Swansea University Author: Anji Munnangi Orcid Logo

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DOI (Published version): 10.1016/j.jpowsour.2020.228877

Abstract

This paper contains a review of developments in anionic batteries. Among the several battery chemistries, Li-ion batteries (LIBs) have excelled in the past two decades. However, new cation based rechargeable battery chemistries of Na+, K+, Mg2+, Ca2+ shuttle have gained interest. Apart from cations,...

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Published in: Journal of Power Sources
ISSN: 0378-7753
Published: Elsevier BV 2021
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URI: https://cronfa.swan.ac.uk/Record/cronfa55199
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first_indexed 2020-09-17T15:23:40Z
last_indexed 2021-01-01T04:18:35Z
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spelling 2020-12-31T15:50:28.3035161 v2 55199 2020-09-17 Recent developments and future perspectives of anionic batteries 3ed0b4f2ff4fb9e87c7a73e7a3c39da7 0000-0001-9101-0252 Anji Munnangi Anji Munnangi true false 2020-09-17 MTLS This paper contains a review of developments in anionic batteries. Among the several battery chemistries, Li-ion batteries (LIBs) have excelled in the past two decades. However, new cation based rechargeable battery chemistries of Na+, K+, Mg2+, Ca2+ shuttle have gained interest. Apart from cations, anionic shuttle dependent batteries offer great potential, too. While nickel metal hydride (Ni-MH) and nickel cadmium (Ni-Cd) batteries rely on OH− ion shuttle and are well-studied, commercial anionic batteries, the new members to this family are fluoride-ion batteries (FIBs) and chloride-ion batteries (CIBs). These batteries utilize metal and metal fluoride or metal chloride containing electrodes as source and target of the shuttle ion. The new generation of fluoride-ion, chloride-ion batteries can theoretically offer higher energy densities than LIBs. Herein, we discuss the origin, developments of CIBs, FIBs, and the advancements achieved so far on various electrolytes, cathodes, and anode materials. We will also briefly discuss the status of related aluminium chloride-based, Ni-MH, and Ni-Cd batteries. Overall, this review investigates the progression, state of the art, trends in outcomes, and provides future perspectives, with an anticipating trajectory towards its practical applications. Journal Article Journal of Power Sources 481 228877 Elsevier BV 0378-7753 Anionic batteries, Chloride-ion batteries, Fluoride-ion batteries, Solid electrolytes, High energy density, Dissolution, Ionic conductivity 1 1 2021 2021-01-01 10.1016/j.jpowsour.2020.228877 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2020-12-31T15:50:28.3035161 2020-09-17T16:22:16.3015063 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Guruprakash Karkera 1 Anji Munnangi 0000-0001-9101-0252 2 Maximilian Fichtner 3
title Recent developments and future perspectives of anionic batteries
spellingShingle Recent developments and future perspectives of anionic batteries
Anji Munnangi
title_short Recent developments and future perspectives of anionic batteries
title_full Recent developments and future perspectives of anionic batteries
title_fullStr Recent developments and future perspectives of anionic batteries
title_full_unstemmed Recent developments and future perspectives of anionic batteries
title_sort Recent developments and future perspectives of anionic batteries
author_id_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7
author_id_fullname_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7_***_Anji Munnangi
author Anji Munnangi
author2 Guruprakash Karkera
Anji Munnangi
Maximilian Fichtner
format Journal article
container_title Journal of Power Sources
container_volume 481
container_start_page 228877
publishDate 2021
institution Swansea University
issn 0378-7753
doi_str_mv 10.1016/j.jpowsour.2020.228877
publisher Elsevier BV
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
active_str 0
description This paper contains a review of developments in anionic batteries. Among the several battery chemistries, Li-ion batteries (LIBs) have excelled in the past two decades. However, new cation based rechargeable battery chemistries of Na+, K+, Mg2+, Ca2+ shuttle have gained interest. Apart from cations, anionic shuttle dependent batteries offer great potential, too. While nickel metal hydride (Ni-MH) and nickel cadmium (Ni-Cd) batteries rely on OH− ion shuttle and are well-studied, commercial anionic batteries, the new members to this family are fluoride-ion batteries (FIBs) and chloride-ion batteries (CIBs). These batteries utilize metal and metal fluoride or metal chloride containing electrodes as source and target of the shuttle ion. The new generation of fluoride-ion, chloride-ion batteries can theoretically offer higher energy densities than LIBs. Herein, we discuss the origin, developments of CIBs, FIBs, and the advancements achieved so far on various electrolytes, cathodes, and anode materials. We will also briefly discuss the status of related aluminium chloride-based, Ni-MH, and Ni-Cd batteries. Overall, this review investigates the progression, state of the art, trends in outcomes, and provides future perspectives, with an anticipating trajectory towards its practical applications.
published_date 2021-01-01T04:09:14Z
_version_ 1763753648343482368
score 11.037603

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