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Cu based Metal Organic Framework (Cu-MOF) for electrocatalytic hydrogen evolution reaction
Materials Research Express, Volume: 7, Issue: 11, Start page: 114001
Swansea University Author: Sudhagar Pitchaimuthu
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DOI (Published version): 10.1088/2053-1591/abb056
Abstract
Hydrogen production using novel catalysts is regarded as one of the most needed technology for the future economic needs and water splitting to give H2 gas, which is a challenging task for large-scale production. This work reports the synthesis of Meso-Cu-BTC metal organic framework and further used...
Published in: | Materials Research Express |
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ISSN: | 2053-1591 |
Published: |
IOP Publishing
2020
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Online Access: |
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URI: | https://cronfa.swan.ac.uk/Record/cronfa55866 |
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Abstract: |
Hydrogen production using novel catalysts is regarded as one of the most needed technology for the future economic needs and water splitting to give H2 gas, which is a challenging task for large-scale production. This work reports the synthesis of Meso-Cu-BTC metal organic framework and further used for understanding its role in electrochemical hydrogen evolution reaction (HER) in 1 M NaOH solution. Meso-Cu-BTC electrocatalyst showed a less overpotential of 89.32 mV and an onset potential of 25 mV with an appreciable current density. Results show a low Tafel slope of 33.41 mVdec−1 and long-term durability. Thus, the overall results show that Meso-Cu-BTC acted as a good candidate for electrocatalysis towards hydrogen evolution. |
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Keywords: |
hydrogen evolution reaction, copper, 1, 3, 5 benzene tricarboxylic acid, hydrogen evolutio metal organic frameworks(MOFs) |
College: |
Faculty of Science and Engineering |
Issue: |
11 |
Start Page: |
114001 |