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Cu based Metal Organic Framework (Cu-MOF) for electrocatalytic hydrogen evolution reaction

Ravi Nivetha, Aparna Sajeev, Aleena Mary Paul, Kannan Gothandapani, Subashini Gnanasekar, Preetam Bhardwaj, George Jacob, Raja Sellappan, Vimala Raghavan, Krishna Chandar N, Sudhagar Pitchaimuthu Orcid Logo, Soon Kwan Jeong, Andrews Nirmala Grace

Materials Research Express, Volume: 7, Issue: 11, Start page: 114001

Swansea University Author: Sudhagar Pitchaimuthu Orcid Logo

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Abstract

Hydrogen production using novel catalysts is regarded as one of the most needed technology for the future economic needs and water splitting to give H2 gas, which is a challenging task for large-scale production. This work reports the synthesis of Meso-Cu-BTC metal organic framework and further used...

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Published in: Materials Research Express
ISSN: 2053-1591
Published: IOP Publishing 2020
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa55866
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Abstract: Hydrogen production using novel catalysts is regarded as one of the most needed technology for the future economic needs and water splitting to give H2 gas, which is a challenging task for large-scale production. This work reports the synthesis of Meso-Cu-BTC metal organic framework and further used for understanding its role in electrochemical hydrogen evolution reaction (HER) in 1 M NaOH solution. Meso-Cu-BTC electrocatalyst showed a less overpotential of 89.32 mV and an onset potential of 25 mV with an appreciable current density. Results show a low Tafel slope of 33.41 mVdec−1 and long-term durability. Thus, the overall results show that Meso-Cu-BTC acted as a good candidate for electrocatalysis towards hydrogen evolution.
Keywords: hydrogen evolution reaction, copper, 1, 3, 5 benzene tricarboxylic acid, hydrogen evolutio metal organic frameworks(MOFs)
College: Faculty of Science and Engineering
Issue: 11
Start Page: 114001