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Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel

JORDAN WHITESIDE, Arnoud C.A. de Vooys, Elizabeth Sackett Orcid Logo, Hamilton McMurray

Corrosion Science, Volume: 190, Start page: 109662

Swansea University Authors: JORDAN WHITESIDE, Elizabeth Sackett Orcid Logo, Hamilton McMurray

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Abstract

Chromium-based coatings on steel, cathodically electroplated from Cr(VI) and Cr(III) electrolytes, were studied to compare their corrosion resistance following application of uniaxial strain. An organic overcoat (PVB) was applied to strained samples and an in-situ scanning Kelvin probe technique was...

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Published in: Corrosion Science
ISSN: 0010-938X
Published: Elsevier BV 2021
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URI: https://cronfa.swan.ac.uk/Record/cronfa57282
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spelling v2 57282 2021-07-08 Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel 1a86fe7741e101bc7050460df358eb6e JORDAN WHITESIDE JORDAN WHITESIDE true false 55d1695a53656de6b0bdfa4c08d8bcd4 0000-0002-5975-6967 Elizabeth Sackett Elizabeth Sackett true false 56fc1b17ffc3bdf6039dc05c6eba7f2a Hamilton McMurray Hamilton McMurray true false 2021-07-08 Chromium-based coatings on steel, cathodically electroplated from Cr(VI) and Cr(III) electrolytes, were studied to compare their corrosion resistance following application of uniaxial strain. An organic overcoat (PVB) was applied to strained samples and an in-situ scanning Kelvin probe technique was used to determine rates of PVB cathodic disbondment. The Cr(VI) derived coatings were fully resistant to cathodic disbondment post-deformation. The Cr(III) derived coatings exhibited increased rates of cathodic disbondment with increasing uniaxial strain. The Kinetics of cathodic disbondment are explained on the basis of coating morphology produced by deformation, and the exposure of underlying iron. The electrochemical availability of iron is estimated by measuring hydrogen evolution kinetics on cathodically polarised samples. Journal Article Corrosion Science 190 109662 Elsevier BV 0010-938X steel, Chromium, Cathodic disbondment, Oxygen reduction, Packaging Steels, Uniaxial Deformation 1 9 2021 2021-09-01 10.1016/j.corsci.2021.109662 COLLEGE NANME COLLEGE CODE Swansea University The authors would like to thank TATA Steel, and the M2A & COATED2 CDT financial support from the European Social Fund via the Welsh Government (<GN3>c80816<GN3>) and the Engineering and Physical Sciences Research Council (Grant Ref: EP/L015099/1). The work was further supported by the Advanced Imaging of Materials (AIM) Facility at Swansea University. 2022-10-31T16:46:08.3236753 2021-07-08T09:23:31.8490530 College of Engineering Engineering JORDAN WHITESIDE 1 Arnoud C.A. de Vooys 2 Elizabeth Sackett 0000-0002-5975-6967 3 Hamilton McMurray 4 57282__20359__d8b50a7de684483398314b8529faea38.pdf 57282.pdf 2021-07-08T09:25:27.9626400 Output 5325956 application/pdf Accepted Manuscript true 2022-07-06T00:00:00.0000000 Released under the terms of a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) License true eng http://creativecommons.org/licenses/by-nc-nd/4.0/
title Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
spellingShingle Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
JORDAN WHITESIDE
Elizabeth Sackett
Hamilton McMurray
title_short Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
title_full Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
title_fullStr Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
title_full_unstemmed Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
title_sort Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel
author_id_str_mv 1a86fe7741e101bc7050460df358eb6e
55d1695a53656de6b0bdfa4c08d8bcd4
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author_id_fullname_str_mv 1a86fe7741e101bc7050460df358eb6e_***_JORDAN WHITESIDE
55d1695a53656de6b0bdfa4c08d8bcd4_***_Elizabeth Sackett
56fc1b17ffc3bdf6039dc05c6eba7f2a_***_Hamilton McMurray
author JORDAN WHITESIDE
Elizabeth Sackett
Hamilton McMurray
author2 JORDAN WHITESIDE
Arnoud C.A. de Vooys
Elizabeth Sackett
Hamilton McMurray
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container_title Corrosion Science
container_volume 190
container_start_page 109662
publishDate 2021
institution Swansea University
issn 0010-938X
doi_str_mv 10.1016/j.corsci.2021.109662
publisher Elsevier BV
college_str College of Engineering
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hierarchy_parent_title College of Engineering
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description Chromium-based coatings on steel, cathodically electroplated from Cr(VI) and Cr(III) electrolytes, were studied to compare their corrosion resistance following application of uniaxial strain. An organic overcoat (PVB) was applied to strained samples and an in-situ scanning Kelvin probe technique was used to determine rates of PVB cathodic disbondment. The Cr(VI) derived coatings were fully resistant to cathodic disbondment post-deformation. The Cr(III) derived coatings exhibited increased rates of cathodic disbondment with increasing uniaxial strain. The Kinetics of cathodic disbondment are explained on the basis of coating morphology produced by deformation, and the exposure of underlying iron. The electrochemical availability of iron is estimated by measuring hydrogen evolution kinetics on cathodically polarised samples.
published_date 2021-09-01T16:46:06Z
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score 10.915416