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“Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks

Roberto D’Amato Orcid Logo, Roberto Bondi, Intissar Moghdad, Fabio Marmottini Orcid Logo, Matthew McPherson Orcid Logo, Houcine Naïli Orcid Logo, Marco Taddei Orcid Logo, Ferdinando Costantino Orcid Logo

Inorganic Chemistry, Volume: 60, Issue: 18, Pages: 14294 - 14301

Swansea University Authors: Matthew McPherson Orcid Logo, Marco Taddei Orcid Logo

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DOI (Published version): 10.1021/acs.inorgchem.1c01839

Abstract

We report a novel synthetic procedure for the high-yield synthesis of metal-organic frameworks (MOFs) with topology with a UiO-66-like structure starting from a range of commercial Zr precursors and various substituted dicarboxylic linkers. The syntheses are carried out by grinding in a ball mill th...

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Published in: Inorganic Chemistry
ISSN: 0020-1669 1520-510X
Published: American Chemical Society (ACS) 2021
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URI: https://cronfa.swan.ac.uk/Record/cronfa57926
first_indexed 2021-09-28T15:51:51Z
last_indexed 2023-01-11T14:38:09Z
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spelling 2022-08-17T12:29:32.4349638 v2 57926 2021-09-16 “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks 69886ed1df27345672e1a52ddee565fe 0000-0002-7529-5355 Matthew McPherson Matthew McPherson true false 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2021-09-16 We report a novel synthetic procedure for the high-yield synthesis of metal-organic frameworks (MOFs) with topology with a UiO-66-like structure starting from a range of commercial Zr precursors and various substituted dicarboxylic linkers. The syntheses are carried out by grinding in a ball mill the starting reagents, namely, Zr salts and the dicarboxylic linkers, in the presence of a small amount of acetic acid and water (1 mL total volume for 1 mmol of each reagent), followed by incubation at either room temperature or 120 °C. Such a simple "shake 'n bake" procedure, inspired by the solid-state reaction of inorganic materials, such as oxides, avoids the use of large amounts of solvents generally used for the syntheses of Zr-MOF. Acidity of the linkers and the amount of water are found to be crucial factors in affording materials of quality comparable to that of products obtained under solvo- or hydrothermal conditions. Journal Article Inorganic Chemistry 60 18 14294 14301 American Chemical Society (ACS) 0020-1669 1520-510X 20 9 2021 2021-09-20 10.1021/acs.inorgchem.1c01839 COLLEGE NANME COLLEGE CODE Swansea University The authors acknowledge the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement no. 663830 (M.T.), the Engineering and Physical Sciences Research Council (EPSRC) for funding through the First Grant scheme EP/R01910X/1 (M.T. and M.J.M.), the Fondo Ricerca di Base (FRB2017), and the Project AMIS, University of Perugia (F.C. and F.M.). 2022-08-17T12:29:32.4349638 2021-09-16T16:11:57.3554907 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Roberto D’Amato 0000-0001-8519-0568 1 Roberto Bondi 2 Intissar Moghdad 3 Fabio Marmottini 0000-0002-8835-553x 4 Matthew McPherson 0000-0002-7529-5355 5 Houcine Naïli 0000-0002-9224-5851 6 Marco Taddei 0000-0003-2805-6375 7 Ferdinando Costantino 0000-0002-2120-1456 8 57926__21156__4d46230f736b4cdabeb6b98628aa4261.pdf 57926.pdf 2021-10-12T20:23:16.4599290 Output 1725093 application/pdf Version of Record true © 2021 The Authors. Released under the terms of a CC-BY license true eng https://creativecommons.org/licenses/by/4.0/
title “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
spellingShingle “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
Matthew McPherson
Marco Taddei
title_short “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
title_full “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
title_fullStr “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
title_full_unstemmed “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
title_sort “Shake ‘n Bake” Route to Functionalized Zr-UiO-66 Metal–Organic Frameworks
author_id_str_mv 69886ed1df27345672e1a52ddee565fe
5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv 69886ed1df27345672e1a52ddee565fe_***_Matthew McPherson
5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Matthew McPherson
Marco Taddei
author2 Roberto D’Amato
Roberto Bondi
Intissar Moghdad
Fabio Marmottini
Matthew McPherson
Houcine Naïli
Marco Taddei
Ferdinando Costantino
format Journal article
container_title Inorganic Chemistry
container_volume 60
container_issue 18
container_start_page 14294
publishDate 2021
institution Swansea University
issn 0020-1669
1520-510X
doi_str_mv 10.1021/acs.inorgchem.1c01839
publisher American Chemical Society (ACS)
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
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description We report a novel synthetic procedure for the high-yield synthesis of metal-organic frameworks (MOFs) with topology with a UiO-66-like structure starting from a range of commercial Zr precursors and various substituted dicarboxylic linkers. The syntheses are carried out by grinding in a ball mill the starting reagents, namely, Zr salts and the dicarboxylic linkers, in the presence of a small amount of acetic acid and water (1 mL total volume for 1 mmol of each reagent), followed by incubation at either room temperature or 120 °C. Such a simple "shake 'n bake" procedure, inspired by the solid-state reaction of inorganic materials, such as oxides, avoids the use of large amounts of solvents generally used for the syntheses of Zr-MOF. Acidity of the linkers and the amount of water are found to be crucial factors in affording materials of quality comparable to that of products obtained under solvo- or hydrothermal conditions.
published_date 2021-09-20T20:05:08Z
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score 11.04748

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