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The use of anion exchange pigments to inhibit the filiform corrosion of zinc-aluminium-magnesium coated steel

Natalie Wint, D. Eaves, Geraint Williams Orcid Logo, Hamilton McMurray

Corrosion Science, Volume: 193, Start page: 109886

Swansea University Authors: Natalie Wint, Geraint Williams Orcid Logo, Hamilton McMurray

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Abstract

In-coating natural (carbonate exchanged) hydrotalcite is shown to significantly reduce the extent of filiform corrosion (FFC) on Zinc-Aluminium-Magnesium (ZAM) coated steels. The hydrotalcite pigment is dispersed within the model poly vinyl butyral (PVB) coating, which is then applied to ZAM. Acetic...

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Published in: Corrosion Science
ISSN: 0010-938X
Published: Elsevier BV 2021
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa58367
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Abstract: In-coating natural (carbonate exchanged) hydrotalcite is shown to significantly reduce the extent of filiform corrosion (FFC) on Zinc-Aluminium-Magnesium (ZAM) coated steels. The hydrotalcite pigment is dispersed within the model poly vinyl butyral (PVB) coating, which is then applied to ZAM. Acetic acid is applied to an artificial scribe penetrative PVB coating defect to initiate corrosion. Filiform corroded area and filament length are shown to decrease with increase in pigment volume fraction (ϕ). Tapering of filaments is also observed. Findings are consistent with hydrotalcite acting to sequester anions or neutralise the filiform head electrolyte.
Keywords: A Steel, A Magnesium, A Metal Coatings, A Organic Coatings, C Atmospheric Corrosion, C Polymer Coatings
College: Faculty of Science and Engineering
Start Page: 109886