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Renewable energy from solar, biomass and biofuels resources / SAHAM IBARHIAM

Swansea University Author: SAHAM IBARHIAM

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DOI (Published version): 10.23889/SUthesis.58763

Abstract

In the current study, the waste stones and rachis obtained from Barhee and Medjool dates palm trees were characterized on a laboratory scale and their potential as biomass feedstock were investigated. The proximate, ultimate, structure/composition and thermo-gravimetric analysis experiments were con...

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Published: Swansea 2021
Institution: Swansea University
Degree level: Doctoral
Degree name: Ph.D
Supervisor: Titiolye, James O.
URI: https://cronfa.swan.ac.uk/Record/cronfa58763
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first_indexed 2021-11-24T11:21:18Z
last_indexed 2021-11-25T04:18:06Z
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spelling 2021-11-24T12:16:14.3383115 v2 58763 2021-11-24 Renewable energy from solar, biomass and biofuels resources 2b428d50411b8dc4b0652e618c5af42e SAHAM IBARHIAM SAHAM IBARHIAM true false 2021-11-24 In the current study, the waste stones and rachis obtained from Barhee and Medjool dates palm trees were characterized on a laboratory scale and their potential as biomass feedstock were investigated. The proximate, ultimate, structure/composition and thermo-gravimetric analysis experiments were conducted to characterize the selected biomass materials. The results showed that the Medjool and Barhee stones are a promising biomass feedstock as they have high volatile and fixed carbon contents with low ash content. Moreover, they have high carbon and nitrogen contents with a very high cellulose contents reaching up to 66% in the case of Barhee stones. The thermo-gravimetric analysis showed that the decomposition of Barhee and Medjool stones can be completed below 420 °C; while it can be completed below 360 °C for Barhee and Medjool rachis under thermo-gravimetric pyrolysis analysis. Based on the TGA results obtained, slow pyrolysis experiments for the stones and rachis feedstock materials were conducted. Among the four slow pyrolysis trials, maximum yield for bio-oil of 21.54% was achieved when Barhee rachis was used, while Medjool rachis produced the least value. Characterization and analysis of the bio-oil extracted from the pyrolysis experiments showed the superiority of the bio-oil from Barhee stone as it has the highest heating value. The gas chromatography mass spectrometry analysis showed that phenol, furfural and benzoic acid are the main components of the bio-oil obtained from the date palm rachis samples while d-allose, furfural, 5-methyl 2-furancarboxaldehyde, and dodecanoic acid are the main components of the bio-oil extracted from the date palm stones. The opportunities of exploitation of renewable energy with solar, biomass and biofuels resources in the Middle East, are also reviewed in detail in this work. The techno-economic analysis for the concentrating solar power plants installed in the Middle East showed promising potential from the economic and technical point of view. E-Thesis Swansea 24 11 2021 2021-11-24 10.23889/SUthesis.58763 A selection of third party content is redacted or is partially redacted from this thesis due to copyright restrictions. COLLEGE NANME COLLEGE CODE Swansea University Titiolye, James O. Doctoral Ph.D 2021-11-24T12:16:14.3383115 2021-11-24T11:19:02.9634247 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised SAHAM IBARHIAM 1 58763__21658__c31a234d43234646b60a1622ebe82c56.pdf Ibarhiam_Saham_F_PhD_Thesis_Final_Redacted.pdf 2021-11-24T11:31:53.4506539 Output 7682789 application/pdf Redacted version - open access true Copyright: The author, Saham F. Ibarhiam, 2021. true eng
title Renewable energy from solar, biomass and biofuels resources
spellingShingle Renewable energy from solar, biomass and biofuels resources
SAHAM IBARHIAM
title_short Renewable energy from solar, biomass and biofuels resources
title_full Renewable energy from solar, biomass and biofuels resources
title_fullStr Renewable energy from solar, biomass and biofuels resources
title_full_unstemmed Renewable energy from solar, biomass and biofuels resources
title_sort Renewable energy from solar, biomass and biofuels resources
author_id_str_mv 2b428d50411b8dc4b0652e618c5af42e
author_id_fullname_str_mv 2b428d50411b8dc4b0652e618c5af42e_***_SAHAM IBARHIAM
author SAHAM IBARHIAM
author2 SAHAM IBARHIAM
format E-Thesis
publishDate 2021
institution Swansea University
doi_str_mv 10.23889/SUthesis.58763
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
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description In the current study, the waste stones and rachis obtained from Barhee and Medjool dates palm trees were characterized on a laboratory scale and their potential as biomass feedstock were investigated. The proximate, ultimate, structure/composition and thermo-gravimetric analysis experiments were conducted to characterize the selected biomass materials. The results showed that the Medjool and Barhee stones are a promising biomass feedstock as they have high volatile and fixed carbon contents with low ash content. Moreover, they have high carbon and nitrogen contents with a very high cellulose contents reaching up to 66% in the case of Barhee stones. The thermo-gravimetric analysis showed that the decomposition of Barhee and Medjool stones can be completed below 420 °C; while it can be completed below 360 °C for Barhee and Medjool rachis under thermo-gravimetric pyrolysis analysis. Based on the TGA results obtained, slow pyrolysis experiments for the stones and rachis feedstock materials were conducted. Among the four slow pyrolysis trials, maximum yield for bio-oil of 21.54% was achieved when Barhee rachis was used, while Medjool rachis produced the least value. Characterization and analysis of the bio-oil extracted from the pyrolysis experiments showed the superiority of the bio-oil from Barhee stone as it has the highest heating value. The gas chromatography mass spectrometry analysis showed that phenol, furfural and benzoic acid are the main components of the bio-oil obtained from the date palm rachis samples while d-allose, furfural, 5-methyl 2-furancarboxaldehyde, and dodecanoic acid are the main components of the bio-oil extracted from the date palm stones. The opportunities of exploitation of renewable energy with solar, biomass and biofuels resources in the Middle East, are also reviewed in detail in this work. The techno-economic analysis for the concentrating solar power plants installed in the Middle East showed promising potential from the economic and technical point of view.
published_date 2021-11-24T04:15:33Z
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