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Probing Charge Generation Efficiency in Thin-Film Solar Cells by Integral-Mode Transient Charge Extraction

Stefan Zeiske, Oskar Sandberg Orcid Logo, Jona Kurpiers, Safa Shoaee Orcid Logo, Paul Meredith Orcid Logo, Ardalan Armin Orcid Logo

ACS Photonics, Volume: 9, Issue: 4, Pages: 1188 - 1195

Swansea University Authors: Stefan Zeiske, Oskar Sandberg Orcid Logo, Paul Meredith Orcid Logo, Ardalan Armin Orcid Logo

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Abstract

The photogeneration of free charges in light-harvesting devices is a multistep process, which can be challenging to probe due to the complexity of contributing energetic states and the competitive character of different driving mechanisms. In this contribution, we advance a technique, integral-mode...

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Published in: ACS Photonics
ISSN: 2330-4022 2330-4022
Published: American Chemical Society (ACS) 2022
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa59906
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Abstract: The photogeneration of free charges in light-harvesting devices is a multistep process, which can be challenging to probe due to the complexity of contributing energetic states and the competitive character of different driving mechanisms. In this contribution, we advance a technique, integral-mode transient charge extraction (ITCE), to probe these processes in thin-film solar cells. ITCE combines capacitance measurements with the integral-mode time-of-flight method in the low intensity regime of sandwich-type thin-film devices and allows for the sensitive determination of photogenerated charge-carrier densities. We verify the theoretical framework of our method by drift-diffusion simulations and demonstrate the applicability of ITCE to organic and perovskite semiconductor-based thin-film solar cells. Furthermore, we examine the field dependence of charge generation efficiency and find our ITCE results to be in excellent agreement with those obtained via time-delayed collection field measurements conducted on the same devices.
Keywords: charge generation, thin-film solar cells, organic semiconductors, perovskite semiconductors, external generation efficiency
College: College of Science
Funders: Swansea University Alexander von Humboldt-Stiftung UK Research and Innovation - EP/T028511/1; Engineering Research Network Wales European Regional Development Fund
Issue: 4
Start Page: 1188
End Page: 1195