CO2 Separation by Imide/Imine Organic Cages

Cognata, Sonia La; Mobili, Riccardo; Milanese, Chiara; Boiocchi, Massimo; Gaboardi, Mattia; Armentano, Donatella; Jansen, Johannes C.; Monteleone, Marcello; Antonangelo, Ariana; Carta, Mariolino; Amendola, Valeria

doi:10.1002/chem.202201631

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CO2 Separation by Imide/Imine Organic Cages

Sonia La Cognata, Riccardo Mobili

, Chiara Milanese, Massimo Boiocchi

, Mattia Gaboardi

, Donatella Armentano

, Johannes C. Jansen

, Marcello Monteleone

, Ariana Antonangelo, Mariolino Carta, Valeria Amendola

Chemistry – A European Journal, Volume: 28, Issue: 49

Swansea University Authors: Ariana Antonangelo, Mariolino Carta

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DOI (Published version): 10.1002/chem.202201631

Abstract

Two novel imide/imine-based organic cages were prepared and studied as materials for the selective separation of CO 2 from N 2 and CH 4 in Vacuum Swing Adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO 2 over N 2 and CH 4 . The cages were also tested as fillers in...

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Published in:	Chemistry – A European Journal
ISSN:	0947-6539 1521-3765
Published:	Wiley 2022
Online Access:	Check full text
URI:	https://cronfa.swan.ac.uk/Record/cronfa60398

first_indexed	2022-07-07T15:00:39Z
last_indexed	2024-11-14T12:17:16Z
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spelling	2024-07-17T11:28:47.1081554 v2 60398 2022-07-07 CO2 Separation by Imide/Imine Organic Cages 4565af0854d884b5f995af8f5dc652fc Ariana Antonangelo Ariana Antonangelo true false 56aebf2bba457f395149bbecbfa6d3eb Mariolino Carta Mariolino Carta true false 2022-07-07 EAAS Two novel imide/imine-based organic cages were prepared and studied as materials for the selective separation of CO 2 from N 2 and CH 4 in Vacuum Swing Adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO 2 over N 2 and CH 4 . The cages were also tested as fillers in mixed-matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid ® or PEEK-WC polymers. Improved gas transport properties and selectivity for CO 2 were achieved compared to the neat polymer membranes. Journal Article Chemistry – A European Journal 28 49 Wiley 0947-6539 1521-3765 organic cages; carbon capture; gas separation; porous materials; mixed-matrix membranes 22 8 2022 2022-08-22 10.1002/chem.202201631 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University We gratefully acknowledge the Cariplo Foundation (Circular Economy for a sustainable future - 2019: MOCA project, grant 2019-2090) for financial support; CM acknowledges C.S.G.I.-Centrefor Colloid and Surface Sciencefor the financial support. 2024-07-17T11:28:47.1081554 2022-07-07T15:50:13.9143783 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry Sonia La Cognata 1 Riccardo Mobili 0000-0003-4451-4364 2 Chiara Milanese 3 Massimo Boiocchi 0000-0002-4991-145x 4 Mattia Gaboardi 0000-0003-3340-4469 5 Donatella Armentano 0000-0002-8502-8074 6 Johannes C. Jansen 0000-0003-4538-6851 7 Marcello Monteleone 0000-0001-8339-062x 8 Ariana Antonangelo 9 Mariolino Carta 10 Valeria Amendola 0000-0001-5219-6074 11 60398__24830__e72066109d4b40edbf0d7973aaf0437b.pdf 60398_VoR.pdf 2022-08-03T15:29:22.9997492 Output 1153699 application/pdf Version of Record true © 2022 The Authors. This is an open access article under the terms of the Creative Commons Attribution CC-BY Licence. true eng http://creativecommons.org/licenses/by/4.0/
title	CO2 Separation by Imide/Imine Organic Cages
spellingShingle	CO2 Separation by Imide/Imine Organic Cages Ariana Antonangelo Mariolino Carta
title_short	CO2 Separation by Imide/Imine Organic Cages
title_full	CO2 Separation by Imide/Imine Organic Cages
title_fullStr	CO2 Separation by Imide/Imine Organic Cages
title_full_unstemmed	CO2 Separation by Imide/Imine Organic Cages
title_sort	CO2 Separation by Imide/Imine Organic Cages
author_id_str_mv	4565af0854d884b5f995af8f5dc652fc 56aebf2bba457f395149bbecbfa6d3eb
author_id_fullname_str_mv	4565af0854d884b5f995af8f5dc652fc_*_Ariana Antonangelo 56aebf2bba457f395149bbecbfa6d3eb_*_Mariolino Carta
author	Ariana Antonangelo Mariolino Carta
author2	Sonia La Cognata Riccardo Mobili Chiara Milanese Massimo Boiocchi Mattia Gaboardi Donatella Armentano Johannes C. Jansen Marcello Monteleone Ariana Antonangelo Mariolino Carta Valeria Amendola
format	Journal article
container_title	Chemistry – A European Journal
container_volume	28
container_issue	49
publishDate	2022
institution	Swansea University
issn	0947-6539 1521-3765
doi_str_mv	10.1002/chem.202201631
publisher	Wiley
college_str	Faculty of Science and Engineering
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department_str	School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry
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description	Two novel imide/imine-based organic cages were prepared and studied as materials for the selective separation of CO 2 from N 2 and CH 4 in Vacuum Swing Adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO 2 over N 2 and CH 4 . The cages were also tested as fillers in mixed-matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid ® or PEEK-WC polymers. Improved gas transport properties and selectivity for CO 2 were achieved compared to the neat polymer membranes.
published_date	2022-08-22T04:59:41Z
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CO2 Separation by Imide/Imine Organic Cages

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