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CO2 Separation by Imide/Imine Organic Cages
Chemistry – A European Journal, Volume: 28, Issue: 49
Swansea University Authors: Ariana Antonangelo, Mariolino Carta
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DOI (Published version): 10.1002/chem.202201631
Abstract
Two novel imide/imine-based organic cages were prepared and studied as materials for the selective separation of CO 2 from N 2 and CH 4 in Vacuum Swing Adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO 2 over N 2 and CH 4 . The cages were also tested as fillers in...
Published in: | Chemistry – A European Journal |
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ISSN: | 0947-6539 1521-3765 |
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Wiley
2022
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URI: | https://cronfa.swan.ac.uk/Record/cronfa60398 |
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v2 60398 2022-07-07 CO2 Separation by Imide/Imine Organic Cages 4565af0854d884b5f995af8f5dc652fc Ariana Antonangelo Ariana Antonangelo true false 56aebf2bba457f395149bbecbfa6d3eb 0000-0003-0718-6971 Mariolino Carta Mariolino Carta true false 2022-07-07 EAAS Two novel imide/imine-based organic cages were prepared and studied as materials for the selective separation of CO 2 from N 2 and CH 4 in Vacuum Swing Adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO 2 over N 2 and CH 4 . The cages were also tested as fillers in mixed-matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid ® or PEEK-WC polymers. Improved gas transport properties and selectivity for CO 2 were achieved compared to the neat polymer membranes. Journal Article Chemistry – A European Journal 28 49 Wiley 0947-6539 1521-3765 organic cages; carbon capture; gas separation; porous materials; mixed-matrix membranes 22 8 2022 2022-08-22 10.1002/chem.202201631 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University We gratefully acknowledge the Cariplo Foundation (Circular Economy for a sustainable future - 2019: MOCA project, grant 2019-2090) for financial support; CM acknowledges C.S.G.I.-Centrefor Colloid and Surface Sciencefor the financial support. 2024-07-17T11:28:47.1081554 2022-07-07T15:50:13.9143783 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry Sonia La Cognata 1 Riccardo Mobili 0000-0003-4451-4364 2 Chiara Milanese 3 Massimo Boiocchi 0000-0002-4991-145x 4 Mattia Gaboardi 0000-0003-3340-4469 5 Donatella Armentano 0000-0002-8502-8074 6 Johannes C. Jansen 0000-0003-4538-6851 7 Marcello Monteleone 0000-0001-8339-062x 8 Ariana Antonangelo 9 Mariolino Carta 0000-0003-0718-6971 10 Valeria Amendola 0000-0001-5219-6074 11 60398__24830__e72066109d4b40edbf0d7973aaf0437b.pdf 60398_VoR.pdf 2022-08-03T15:29:22.9997492 Output 1153699 application/pdf Version of Record true © 2022 The Authors. This is an open access article under the terms of the Creative Commons Attribution CC-BY Licence. true eng http://creativecommons.org/licenses/by/4.0/ |
title |
CO2 Separation by Imide/Imine Organic Cages |
spellingShingle |
CO2 Separation by Imide/Imine Organic Cages Ariana Antonangelo Mariolino Carta |
title_short |
CO2 Separation by Imide/Imine Organic Cages |
title_full |
CO2 Separation by Imide/Imine Organic Cages |
title_fullStr |
CO2 Separation by Imide/Imine Organic Cages |
title_full_unstemmed |
CO2 Separation by Imide/Imine Organic Cages |
title_sort |
CO2 Separation by Imide/Imine Organic Cages |
author_id_str_mv |
4565af0854d884b5f995af8f5dc652fc 56aebf2bba457f395149bbecbfa6d3eb |
author_id_fullname_str_mv |
4565af0854d884b5f995af8f5dc652fc_***_Ariana Antonangelo 56aebf2bba457f395149bbecbfa6d3eb_***_Mariolino Carta |
author |
Ariana Antonangelo Mariolino Carta |
author2 |
Sonia La Cognata Riccardo Mobili Chiara Milanese Massimo Boiocchi Mattia Gaboardi Donatella Armentano Johannes C. Jansen Marcello Monteleone Ariana Antonangelo Mariolino Carta Valeria Amendola |
format |
Journal article |
container_title |
Chemistry – A European Journal |
container_volume |
28 |
container_issue |
49 |
publishDate |
2022 |
institution |
Swansea University |
issn |
0947-6539 1521-3765 |
doi_str_mv |
10.1002/chem.202201631 |
publisher |
Wiley |
college_str |
Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry |
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description |
Two novel imide/imine-based organic cages were prepared and studied as materials for the selective separation of CO 2 from N 2 and CH 4 in Vacuum Swing Adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO 2 over N 2 and CH 4 . The cages were also tested as fillers in mixed-matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid ® or PEEK-WC polymers. Improved gas transport properties and selectivity for CO 2 were achieved compared to the neat polymer membranes. |
published_date |
2022-08-22T11:28:46Z |
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1804821726842847232 |
score |
11.028886 |