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Systematic in situ hydration neutron reflectometry study on Nafion thin films

Hamish Cavaye Orcid Logo, Rebecca J. L. Welbourn Orcid Logo, Jan G. Gluschke Orcid Logo, Paul Hughes, Ky V. Nguyen, Adam P. Micolich, Paul Meredith Orcid Logo, Bernard Mostert Orcid Logo

Physical Chemistry Chemical Physics, Volume: 24, Issue: 46, Pages: 28554 - 28563

Swansea University Authors: Paul Hughes, Paul Meredith Orcid Logo, Bernard Mostert Orcid Logo

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DOI (Published version): 10.1039/d2cp03067e

Abstract

Reported herein is a neutron reflectometry (NR) study on hydrated Nafion thin films (∼30 nm) on a silicon substrate with native oxide. The Nafion morphology is investigated systematically across the whole relative humidity range using both H2O and D2O vapours to enable a comparative study. By utilis...

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Published in: Physical Chemistry Chemical Physics
ISSN: 1463-9076 1463-9084
Published: Royal Society of Chemistry (RSC) 2022
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa62079
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Abstract: Reported herein is a neutron reflectometry (NR) study on hydrated Nafion thin films (∼30 nm) on a silicon substrate with native oxide. The Nafion morphology is investigated systematically across the whole relative humidity range using both H2O and D2O vapours to enable a comparative study. By utilising this systematic approach two key results have been obtained. The first is that by leveraging the strong positive scattering signal from the D2O vapour, a complete and systematic water adsorption isotherm (Type II) for a Nafion thin film is produced. Utilising the slight negative scattering signal of the H2O enabled the quantification of the hydration dependent evolution of the formation of Nafion/water lamellae near the substrate surface. The number of lamellae layers increases continuously with hydration, and does not form abruptly. We also report the effects of swelling on the thin films across the relative humidity ranges. The work reported should prove useful in quantifying other hydration dependent properties of Nafion thin films such as conductivity and understanding Nafion/semiconductor based devices, as well as showcasing a NR methodology for other hydrophilic polymers.
College: Faculty of Science and Engineering
Funders: Australian Research Council (ARC) under DP170104024 and DP170102552 Welsh European Funding Office (European Regional Development Fund) through the Sêr Cymru II Program. European Regional Development Fund Welsh Government through the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No 663830. Swansea University Strategic Initiative in Sustainable Advanced Materials. NSW node of the Australian National Fabrication Facility (ANFF).
Issue: 46
Start Page: 28554
End Page: 28563