Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide

Chen, Xin; Bartlam, Cian; Lloret, Vicent; Badlyan, Narine Moses; Wolff, Stefan; Gillen, Roland; Stimpel‐Lindner, Tanja; Maultzsch, Janina; Duesberg, Georg S.; Knirsch, Kathrin C.; Hirsch, Andreas

doi:10.1002/anie.202103353

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Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide

Xin Chen, Cian Bartlam, Vicent Lloret, Narine Moses Badlyan, Stefan Wolff, Roland Gillen

, Tanja Stimpel‐Lindner, Janina Maultzsch, Georg S. Duesberg, Kathrin C. Knirsch, Andreas Hirsch

Angewandte Chemie International Edition, Volume: 60, Issue: 24, Pages: 13484 - 13492

Swansea University Author: Roland Gillen

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DOI (Published version): 10.1002/anie.202103353

Abstract

Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activate...

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Published in:	Angewandte Chemie International Edition
ISSN:	1433-7851 1521-3773
Published:	Wiley 2021
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URI:	https://cronfa.swan.ac.uk/Record/cronfa66652
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spelling	v2 66652 2024-06-11 Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide 8fd99815709ad1e4ae52e27f63257604 0000-0002-7913-0953 Roland Gillen Roland Gillen true false 2024-06-11 ACEM Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activated MoS2 with alkyl iodide and aryl diazonium salts. This approach can be utilized to modify both colloidal and substrate supported MoS2 nanosheets. We have discovered that compared to the adducts formed through the reactions of MoS2 with diazonium salts, those formed through the reactions of MoS2 with alkyl iodides display higher reactivity towards further reactions with electrophiles. We are convinced that our systematic study on the formation and reactivity of covalently functionalized MoS2 hybrids will provide some practical guidance on multi-angle tailoring of the properties of 2D MoS2 for various potential applications. Journal Article Angewandte Chemie International Edition 60 24 13484 13492 Wiley 1433-7851 1521-3773 7 6 2021 2021-06-07 10.1002/anie.202103353 COLLEGE NANME Aerospace, Civil, Electrical, and Mechanical Engineering COLLEGE CODE ACEM Swansea University Another institution paid the OA fee European Union's Horizon 2020 research and innovation programme Graphene Flagship. Grant Number: No 881603. EU Horizon 2020. Grant Number: No. 829035 (QUE-FORMAL) Deutsche Forschungsgemeinschaft (DFG) through the SFB 953 "Synthetic Carbon Allotropes"- B13.. Grant Number: Project number 182849149 2024-08-13T16:01:54.7048034 2024-06-11T12:42:39.2603603 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering Xin Chen 1 Cian Bartlam 2 Vicent Lloret 3 Narine Moses Badlyan 4 Stefan Wolff 5 Roland Gillen 0000-0002-7913-0953 6 Tanja Stimpel‐Lindner 7 Janina Maultzsch 8 Georg S. Duesberg 9 Kathrin C. Knirsch 10 Andreas Hirsch 0000-0003-1458-8872 11 66652__31098__38bcb8477b084038bbf1651bf1fd912f.pdf 66652.VoR.pdf 2024-08-13T12:43:56.8874911 Output 2031955 application/pdf Version of Record true Copyright 2021: The Authors. This is an open access article under the terms of the Creative Commons Attribution Non-CommercialNoDerivs License. true eng http://creativecommons.org/licenses/by-nc-nd/4.0/
title	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
spellingShingle	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide Roland Gillen
title_short	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
title_full	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
title_fullStr	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
title_full_unstemmed	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
title_sort	Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
author_id_str_mv	8fd99815709ad1e4ae52e27f63257604
author_id_fullname_str_mv	8fd99815709ad1e4ae52e27f63257604_***_Roland Gillen
author	Roland Gillen
author2	Xin Chen Cian Bartlam Vicent Lloret Narine Moses Badlyan Stefan Wolff Roland Gillen Tanja Stimpel‐Lindner Janina Maultzsch Georg S. Duesberg Kathrin C. Knirsch Andreas Hirsch
format	Journal article
container_title	Angewandte Chemie International Edition
container_volume	60
container_issue	24
container_start_page	13484
publishDate	2021
institution	Swansea University
issn	1433-7851 1521-3773
doi_str_mv	10.1002/anie.202103353
publisher	Wiley
college_str	Faculty of Science and Engineering
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description	Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activated MoS2 with alkyl iodide and aryl diazonium salts. This approach can be utilized to modify both colloidal and substrate supported MoS2 nanosheets. We have discovered that compared to the adducts formed through the reactions of MoS2 with diazonium salts, those formed through the reactions of MoS2 with alkyl iodides display higher reactivity towards further reactions with electrophiles. We are convinced that our systematic study on the formation and reactivity of covalently functionalized MoS2 hybrids will provide some practical guidance on multi-angle tailoring of the properties of 2D MoS2 for various potential applications.
published_date	2021-06-07T16:01:56Z
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Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide

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