Journal article 26 views 9 downloads
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide
Angewandte Chemie International Edition, Volume: 60, Issue: 24, Pages: 13484 - 13492
Swansea University Author:
Roland Gillen
-
PDF | Version of Record
Copyright 2021: The Authors. This is an open access article under the terms of the Creative Commons Attribution Non-CommercialNoDerivs License.
Download (1.94MB)
DOI (Published version): 10.1002/anie.202103353
Abstract
Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activate...
Published in: | Angewandte Chemie International Edition |
---|---|
ISSN: | 1433-7851 1521-3773 |
Published: |
Wiley
2021
|
Online Access: |
Check full text
|
URI: | https://cronfa.swan.ac.uk/Record/cronfa66652 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
first_indexed |
2024-08-13T11:33:34Z |
---|---|
last_indexed |
2024-08-13T11:33:34Z |
id |
cronfa66652 |
recordtype |
SURis |
fullrecord |
<?xml version="1.0" encoding="utf-8"?><rfc1807 xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:xsd="http://www.w3.org/2001/XMLSchema"><bib-version>v2</bib-version><id>66652</id><entry>2024-06-11</entry><title>Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide</title><swanseaauthors><author><sid>8fd99815709ad1e4ae52e27f63257604</sid><ORCID>0000-0002-7913-0953</ORCID><firstname>Roland</firstname><surname>Gillen</surname><name>Roland Gillen</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2024-06-11</date><deptcode>ACEM</deptcode><abstract>Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activated MoS2 with alkyl iodide and aryl diazonium salts. This approach can be utilized to modify both colloidal and substrate supported MoS2 nanosheets. We have discovered that compared to the adducts formed through the reactions of MoS2 with diazonium salts, those formed through the reactions of MoS2 with alkyl iodides display higher reactivity towards further reactions with electrophiles. We are convinced that our systematic study on the formation and reactivity of covalently functionalized MoS2 hybrids will provide some practical guidance on multi-angle tailoring of the properties of 2D MoS2 for various potential applications.</abstract><type>Journal Article</type><journal>Angewandte Chemie International Edition</journal><volume>60</volume><journalNumber>24</journalNumber><paginationStart>13484</paginationStart><paginationEnd>13492</paginationEnd><publisher>Wiley</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>1433-7851</issnPrint><issnElectronic>1521-3773</issnElectronic><keywords/><publishedDay>7</publishedDay><publishedMonth>6</publishedMonth><publishedYear>2021</publishedYear><publishedDate>2021-06-07</publishedDate><doi>10.1002/anie.202103353</doi><url/><notes/><college>COLLEGE NANME</college><department>Aerospace, Civil, Electrical, and Mechanical Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>ACEM</DepartmentCode><institution>Swansea University</institution><apcterm>Another institution paid the OA fee</apcterm><funders>European Union's Horizon 2020 research and innovation programme Graphene Flagship. Grant Number: No 881603.
EU Horizon 2020. Grant Number: No. 829035 (QUE-FORMAL)
Deutsche Forschungsgemeinschaft (DFG) through the SFB 953 "Synthetic Carbon Allotropes"- B13.. Grant Number: Project number 182849149</funders><projectreference/><lastEdited>2024-08-13T16:01:54.7048034</lastEdited><Created>2024-06-11T12:42:39.2603603</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering</level></path><authors><author><firstname>Xin</firstname><surname>Chen</surname><order>1</order></author><author><firstname>Cian</firstname><surname>Bartlam</surname><order>2</order></author><author><firstname>Vicent</firstname><surname>Lloret</surname><order>3</order></author><author><firstname>Narine Moses</firstname><surname>Badlyan</surname><order>4</order></author><author><firstname>Stefan</firstname><surname>Wolff</surname><order>5</order></author><author><firstname>Roland</firstname><surname>Gillen</surname><orcid>0000-0002-7913-0953</orcid><order>6</order></author><author><firstname>Tanja</firstname><surname>Stimpel‐Lindner</surname><order>7</order></author><author><firstname>Janina</firstname><surname>Maultzsch</surname><order>8</order></author><author><firstname>Georg S.</firstname><surname>Duesberg</surname><order>9</order></author><author><firstname>Kathrin C.</firstname><surname>Knirsch</surname><order>10</order></author><author><firstname>Andreas</firstname><surname>Hirsch</surname><orcid>0000-0003-1458-8872</orcid><order>11</order></author></authors><documents><document><filename>66652__31098__38bcb8477b084038bbf1651bf1fd912f.pdf</filename><originalFilename>66652.VoR.pdf</originalFilename><uploaded>2024-08-13T12:43:56.8874911</uploaded><type>Output</type><contentLength>2031955</contentLength><contentType>application/pdf</contentType><version>Version of Record</version><cronfaStatus>true</cronfaStatus><documentNotes>Copyright 2021: The Authors. This is an open access article under the terms of the Creative Commons Attribution Non-CommercialNoDerivs License.</documentNotes><copyrightCorrect>true</copyrightCorrect><language>eng</language><licence>http://creativecommons.org/licenses/by-nc-nd/4.0/</licence></document></documents><OutputDurs/></rfc1807> |
spelling |
v2 66652 2024-06-11 Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide 8fd99815709ad1e4ae52e27f63257604 0000-0002-7913-0953 Roland Gillen Roland Gillen true false 2024-06-11 ACEM Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activated MoS2 with alkyl iodide and aryl diazonium salts. This approach can be utilized to modify both colloidal and substrate supported MoS2 nanosheets. We have discovered that compared to the adducts formed through the reactions of MoS2 with diazonium salts, those formed through the reactions of MoS2 with alkyl iodides display higher reactivity towards further reactions with electrophiles. We are convinced that our systematic study on the formation and reactivity of covalently functionalized MoS2 hybrids will provide some practical guidance on multi-angle tailoring of the properties of 2D MoS2 for various potential applications. Journal Article Angewandte Chemie International Edition 60 24 13484 13492 Wiley 1433-7851 1521-3773 7 6 2021 2021-06-07 10.1002/anie.202103353 COLLEGE NANME Aerospace, Civil, Electrical, and Mechanical Engineering COLLEGE CODE ACEM Swansea University Another institution paid the OA fee European Union's Horizon 2020 research and innovation programme Graphene Flagship. Grant Number: No 881603. EU Horizon 2020. Grant Number: No. 829035 (QUE-FORMAL) Deutsche Forschungsgemeinschaft (DFG) through the SFB 953 "Synthetic Carbon Allotropes"- B13.. Grant Number: Project number 182849149 2024-08-13T16:01:54.7048034 2024-06-11T12:42:39.2603603 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering Xin Chen 1 Cian Bartlam 2 Vicent Lloret 3 Narine Moses Badlyan 4 Stefan Wolff 5 Roland Gillen 0000-0002-7913-0953 6 Tanja Stimpel‐Lindner 7 Janina Maultzsch 8 Georg S. Duesberg 9 Kathrin C. Knirsch 10 Andreas Hirsch 0000-0003-1458-8872 11 66652__31098__38bcb8477b084038bbf1651bf1fd912f.pdf 66652.VoR.pdf 2024-08-13T12:43:56.8874911 Output 2031955 application/pdf Version of Record true Copyright 2021: The Authors. This is an open access article under the terms of the Creative Commons Attribution Non-CommercialNoDerivs License. true eng http://creativecommons.org/licenses/by-nc-nd/4.0/ |
title |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide |
spellingShingle |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide Roland Gillen |
title_short |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide |
title_full |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide |
title_fullStr |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide |
title_full_unstemmed |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide |
title_sort |
Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide |
author_id_str_mv |
8fd99815709ad1e4ae52e27f63257604 |
author_id_fullname_str_mv |
8fd99815709ad1e4ae52e27f63257604_***_Roland Gillen |
author |
Roland Gillen |
author2 |
Xin Chen Cian Bartlam Vicent Lloret Narine Moses Badlyan Stefan Wolff Roland Gillen Tanja Stimpel‐Lindner Janina Maultzsch Georg S. Duesberg Kathrin C. Knirsch Andreas Hirsch |
format |
Journal article |
container_title |
Angewandte Chemie International Edition |
container_volume |
60 |
container_issue |
24 |
container_start_page |
13484 |
publishDate |
2021 |
institution |
Swansea University |
issn |
1433-7851 1521-3773 |
doi_str_mv |
10.1002/anie.202103353 |
publisher |
Wiley |
college_str |
Faculty of Science and Engineering |
hierarchytype |
|
hierarchy_top_id |
facultyofscienceandengineering |
hierarchy_top_title |
Faculty of Science and Engineering |
hierarchy_parent_id |
facultyofscienceandengineering |
hierarchy_parent_title |
Faculty of Science and Engineering |
department_str |
School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering |
document_store_str |
1 |
active_str |
0 |
description |
Covalent functionalization of two-dimensional molybdenum disulfide (2D MoS2) holds great promise in developing robust organic-MoS2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS2 hybrid structure through successively reacting activated MoS2 with alkyl iodide and aryl diazonium salts. This approach can be utilized to modify both colloidal and substrate supported MoS2 nanosheets. We have discovered that compared to the adducts formed through the reactions of MoS2 with diazonium salts, those formed through the reactions of MoS2 with alkyl iodides display higher reactivity towards further reactions with electrophiles. We are convinced that our systematic study on the formation and reactivity of covalently functionalized MoS2 hybrids will provide some practical guidance on multi-angle tailoring of the properties of 2D MoS2 for various potential applications. |
published_date |
2021-06-07T16:01:56Z |
_version_ |
1807285030661128192 |
score |
11.02167 |