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Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries

Mochun Zhang, Rui Tan Orcid Logo, Mengran Wang, Zhian Zhang, CheeTong John Low, Yanqing Lai

Battery Energy, Volume: 3, Issue: 2

Swansea University Author: Rui Tan Orcid Logo

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DOI (Published version): 10.1002/bte2.20230050

Abstract

Rechargeable lithium-metal batteries (LMBs) hold great promise for providing high-energy density. However, their widespread commercial adoption has been inhibited by critical challenges, for example, the capacity fading from irreversible processes at electrolyte/electrode interfaces and safety conce...

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Published in: Battery Energy
ISSN: 2768-1688 2768-1696
Published: Wiley 2024
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URI: https://cronfa.swan.ac.uk/Record/cronfa67792
first_indexed 2024-10-18T11:43:54Z
last_indexed 2024-11-25T14:20:51Z
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spelling 2024-10-18T12:46:17.4173528 v2 67792 2024-09-25 Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries 774c33a0a76a9152ca86a156b5ae26ff 0009-0001-9278-7327 Rui Tan Rui Tan true false 2024-09-25 EAAS Rechargeable lithium-metal batteries (LMBs) hold great promise for providing high-energy density. However, their widespread commercial adoption has been inhibited by critical challenges, for example, the capacity fading from irreversible processes at electrolyte/electrode interfaces and safety concerns originating from the inhomogeneous lithium deposition. Polymer electrolytes benefiting from enhanced electrolyte/electrode contact and low interfacial impedance provide a variable solution to address these challenges and enable a high-energy and flexible battery system. Although promising, inefficient bulky ionic conductivity and poor mechanical stability confront the stable operation of polymer electrolytes in tangible batteries, which highly requires the development of innovative polymer electrolyte chemistries. Among various polymer materials, microporous polymers stand out due to their abundant porosity and customizable micropore structure, positioning them as promising candidates for next-generation electrolyte membranes. This review, therefore, summarizes recent advances in electrolyte membranes based on two new chemistries, hypercrosslinked polymers (HCPs) and porous coordination polymers (PCPs). Other microporous polymers, such as covalent organic polymers, porous organic cages, and polymers of intrinsic microporosity, are also discussed with an emphasis on their applications in LMBs. Most importantly, by reviewing the design strategies, synthesis protocols, and performance in LMBs, we gain insights into the design principles of high-performance electrolyte membranes based on HCPs and PCPs and highlight potential future research directions. Journal Article Battery Energy 3 2 Wiley 2768-1688 2768-1696 electrolyte membranes; hypercrosslinked polymers; lithium-metal batteries; polymer electrolytes; porous coordination polymers 24 3 2024 2024-03-24 10.1002/bte2.20230050 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University Another institution paid the OA fee The Science and Technology Innovation Program of Hunan Province. Grant Number: 2023RC3054 Changsha Municipal Natural Science Foundation. Grant Number: kq2202085 RSC Researcher Collaborations. Grant Number: C23-8220221815 2024-10-18T12:46:17.4173528 2024-09-25T21:18:12.3251482 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Mochun Zhang 1 Rui Tan 0009-0001-9278-7327 2 Mengran Wang 3 Zhian Zhang 4 CheeTong John Low 5 Yanqing Lai 6 67792__32640__90e4c19d242a4c1daedd1ac55bab8156.pdf 67792.VOR.pdf 2024-10-18T12:44:24.1309472 Output 4830554 application/pdf Version of Record true © 2024 The Authors. This is an open access article under the terms of the Creative Commons Attribution License. true eng http://creativecommons.org/licenses/by/4.0/
title Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
spellingShingle Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
Rui Tan
title_short Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
title_full Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
title_fullStr Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
title_full_unstemmed Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
title_sort Hypercrosslinked porous and coordination polymer materials for electrolyte membranes in lithium‐metal batteries
author_id_str_mv 774c33a0a76a9152ca86a156b5ae26ff
author_id_fullname_str_mv 774c33a0a76a9152ca86a156b5ae26ff_***_Rui Tan
author Rui Tan
author2 Mochun Zhang
Rui Tan
Mengran Wang
Zhian Zhang
CheeTong John Low
Yanqing Lai
format Journal article
container_title Battery Energy
container_volume 3
container_issue 2
publishDate 2024
institution Swansea University
issn 2768-1688
2768-1696
doi_str_mv 10.1002/bte2.20230050
publisher Wiley
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
document_store_str 0
active_str 0
description Rechargeable lithium-metal batteries (LMBs) hold great promise for providing high-energy density. However, their widespread commercial adoption has been inhibited by critical challenges, for example, the capacity fading from irreversible processes at electrolyte/electrode interfaces and safety concerns originating from the inhomogeneous lithium deposition. Polymer electrolytes benefiting from enhanced electrolyte/electrode contact and low interfacial impedance provide a variable solution to address these challenges and enable a high-energy and flexible battery system. Although promising, inefficient bulky ionic conductivity and poor mechanical stability confront the stable operation of polymer electrolytes in tangible batteries, which highly requires the development of innovative polymer electrolyte chemistries. Among various polymer materials, microporous polymers stand out due to their abundant porosity and customizable micropore structure, positioning them as promising candidates for next-generation electrolyte membranes. This review, therefore, summarizes recent advances in electrolyte membranes based on two new chemistries, hypercrosslinked polymers (HCPs) and porous coordination polymers (PCPs). Other microporous polymers, such as covalent organic polymers, porous organic cages, and polymers of intrinsic microporosity, are also discussed with an emphasis on their applications in LMBs. Most importantly, by reviewing the design strategies, synthesis protocols, and performance in LMBs, we gain insights into the design principles of high-performance electrolyte membranes based on HCPs and PCPs and highlight potential future research directions.
published_date 2024-03-24T05:32:31Z
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