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Characterisation of fire-damaged batteries – implications for recycling

Wafaa Abdul Ameer Al-shatty Orcid Logo, Jenny Baker, Davide Deganello Orcid Logo, Rhys G. Charles Orcid Logo, Tom Dunlop Orcid Logo

Sustainability Science and Technology

Swansea University Authors: Davide Deganello Orcid Logo, Rhys G. Charles Orcid Logo, Tom Dunlop Orcid Logo

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Abstract

As lithium-ion battery demand grows, so do fire safety challenges. Despite this, research on fire-damaged batteries remains limited. This study explores the distribution of valuable metals (such as Ni, Mn, Co, Cu) in two types of waste derived from lithium-ion nickel-manganese-cobalt oxide batteries...

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Published in: Sustainability Science and Technology
ISSN: 2977-3504
Published: IOP Publishing 2026
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URI: https://cronfa.swan.ac.uk/Record/cronfa72121
first_indexed 2026-06-19T09:33:32Z
last_indexed 2026-06-20T05:03:12Z
id cronfa72121
recordtype SURis
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spelling 2026-06-19T10:33:30.5025442 v2 72121 2026-06-19 Characterisation of fire-damaged batteries – implications for recycling ea38a0040bdfd3875506189e3629b32a 0000-0001-8341-4177 Davide Deganello Davide Deganello true false 1ff66fa61714afa2dd8bdae1769a5d21 0000-0003-1886-378X Rhys G. Charles Rhys G. Charles true true 809395460ab1e6b53a906b136d919c41 0000-0002-5851-8713 Tom Dunlop Tom Dunlop true false 2026-06-19 ACEM As lithium-ion battery demand grows, so do fire safety challenges. Despite this, research on fire-damaged batteries remains limited. This study explores the distribution of valuable metals (such as Ni, Mn, Co, Cu) in two types of waste derived from lithium-ion nickel-manganese-cobalt oxide batteries (NMC811): black mass (BM) and fire-damaged waste (FD). It emphasizes that cobalt, manganese, and nickel-rich NMC particles are predominantly found in smaller particle size fractions (<125 µm), where they can account for up to 85% of total metal content. Fire-damaged (FD) batteries show a similar, though less pronounced, trend. Evidence of structural degradation suggests that fire temperatures exceeded 500 °C; however, the presence of residual organic binders indicates that heat was unevenly distributed during the fire. FD batteries become friable and easily fragment into fine particles, which can hinder the effective separation of copper and aluminium current collectors, increasing their presence in processed material. The inclusion of FD batteries in standard BM processing introduces variability in output composition, potentially lowering the concentration of high-value NMC811 materials present. To maintain product quality and recycling output values, it is recommended that FD batteries are processed separately. Alternatively, particle size separation may allow for tailored outputs aligned with specific customer requirements. Journal Article Sustainability Science and Technology 0 IOP Publishing 2977-3504 Fire-damaged batteries, thermal XRD, End-of-life batteries, NMC811, Li-ion batteries 10 6 2026 2026-06-10 10.1088/2977-3504/ae7b3b COLLEGE NANME Aerospace Civil Electrical and Mechanical Engineering COLLEGE CODE ACEM Swansea University Another institution paid the OA fee We gratefully acknowledge funding from the EPSRC ECR Fellowship NoRESt EP/S03711X/1 (W-AS, JB) and TReFCo EP/W019167/1 (W-AS, RC, DD, JB). The authors would like to thank the access to characterisation equipment to Swansea University Advanced Imaging of Materials (AIM) facility, which was funded in part by the EPSRC (EP/M028267/1) and the European Regional Development Fund through the Welsh Government (80708). 2026-06-19T10:33:30.5025442 2026-06-19T10:20:54.8630894 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Wafaa Abdul Ameer Al-shatty 0000-0002-3389-0199 1 Jenny Baker 2 Davide Deganello 0000-0001-8341-4177 3 Rhys G. Charles 0000-0003-1886-378X 4 Tom Dunlop 0000-0002-5851-8713 5
title Characterisation of fire-damaged batteries – implications for recycling
spellingShingle Characterisation of fire-damaged batteries – implications for recycling
Davide Deganello
Rhys G. Charles
Tom Dunlop
title_short Characterisation of fire-damaged batteries – implications for recycling
title_full Characterisation of fire-damaged batteries – implications for recycling
title_fullStr Characterisation of fire-damaged batteries – implications for recycling
title_full_unstemmed Characterisation of fire-damaged batteries – implications for recycling
title_sort Characterisation of fire-damaged batteries – implications for recycling
author_id_str_mv ea38a0040bdfd3875506189e3629b32a
1ff66fa61714afa2dd8bdae1769a5d21
809395460ab1e6b53a906b136d919c41
author_id_fullname_str_mv ea38a0040bdfd3875506189e3629b32a_***_Davide Deganello
1ff66fa61714afa2dd8bdae1769a5d21_***_Rhys G. Charles
809395460ab1e6b53a906b136d919c41_***_Tom Dunlop
author Davide Deganello
Rhys G. Charles
Tom Dunlop
author2 Wafaa Abdul Ameer Al-shatty
Jenny Baker
Davide Deganello
Rhys G. Charles
Tom Dunlop
format Journal article
container_title Sustainability Science and Technology
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publishDate 2026
institution Swansea University
issn 2977-3504
doi_str_mv 10.1088/2977-3504/ae7b3b
publisher IOP Publishing
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
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description As lithium-ion battery demand grows, so do fire safety challenges. Despite this, research on fire-damaged batteries remains limited. This study explores the distribution of valuable metals (such as Ni, Mn, Co, Cu) in two types of waste derived from lithium-ion nickel-manganese-cobalt oxide batteries (NMC811): black mass (BM) and fire-damaged waste (FD). It emphasizes that cobalt, manganese, and nickel-rich NMC particles are predominantly found in smaller particle size fractions (<125 µm), where they can account for up to 85% of total metal content. Fire-damaged (FD) batteries show a similar, though less pronounced, trend. Evidence of structural degradation suggests that fire temperatures exceeded 500 °C; however, the presence of residual organic binders indicates that heat was unevenly distributed during the fire. FD batteries become friable and easily fragment into fine particles, which can hinder the effective separation of copper and aluminium current collectors, increasing their presence in processed material. The inclusion of FD batteries in standard BM processing introduces variability in output composition, potentially lowering the concentration of high-value NMC811 materials present. To maintain product quality and recycling output values, it is recommended that FD batteries are processed separately. Alternatively, particle size separation may allow for tailored outputs aligned with specific customer requirements.
published_date 2026-06-10T06:03:12Z
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