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Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process

S. Antony Savarimuthu, D.G. Leo Prakash, S. Augustine Thomas, Leo Prakash Orcid Logo

Tetrahedron Letters

Swansea University Author: Leo Prakash Orcid Logo

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DOI (Published version): 10.1016/j.tetlet.2014.02.086

Abstract

It is aimed to provide a cost effective p-NBSA catalyzed nucleophilic substitution of propargyl alcohols with alcohols, amines and heterocycles, without employing corrosive and costly metal catalysts, toxic solvents and column chromatography for purification. A systematic study of C-C, C-N and C-O b...

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Published in: Tetrahedron Letters
Published: 2014
URI: https://cronfa.swan.ac.uk/Record/cronfa17634
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first_indexed 2014-04-02T01:30:03Z
last_indexed 2018-09-13T18:08:20Z
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spelling 2018-09-13T14:32:45.4120964 v2 17634 2014-04-01 Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process bd72868c48af6c0b04bf9f6bb48ce324 0000-0002-8812-8927 Leo Prakash Leo Prakash true false 2014-04-01 MTLS It is aimed to provide a cost effective p-NBSA catalyzed nucleophilic substitution of propargyl alcohols with alcohols, amines and heterocycles, without employing corrosive and costly metal catalysts, toxic solvents and column chromatography for purification. A systematic study of C-C, C-N and C-O bond formation and efficacy of the scalability have also been confirmed. Journal Article Tetrahedron Letters Propargyl alcohol; Propargyl ether; Propargyl amine; Heterocycles; Sulfonic acids 21 5 2014 2014-05-21 10.1016/j.tetlet.2014.02.086 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2018-09-13T14:32:45.4120964 2014-04-01T10:03:49.1835072 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering S. Antony Savarimuthu 1 D.G. Leo Prakash 2 S. Augustine Thomas 3 Leo Prakash 0000-0002-8812-8927 4
title Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
spellingShingle Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
Leo Prakash
title_short Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
title_full Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
title_fullStr Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
title_full_unstemmed Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
title_sort Nucleophilic substitution of propargyl alcohols with aliphatic alcohols, aliphatic amines and heterocycles catalyzed by 4-nitrobenzenesulfonic acid: A scalable and metal-free process
author_id_str_mv bd72868c48af6c0b04bf9f6bb48ce324
author_id_fullname_str_mv bd72868c48af6c0b04bf9f6bb48ce324_***_Leo Prakash
author Leo Prakash
author2 S. Antony Savarimuthu
D.G. Leo Prakash
S. Augustine Thomas
Leo Prakash
format Journal article
container_title Tetrahedron Letters
publishDate 2014
institution Swansea University
doi_str_mv 10.1016/j.tetlet.2014.02.086
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
active_str 0
description It is aimed to provide a cost effective p-NBSA catalyzed nucleophilic substitution of propargyl alcohols with alcohols, amines and heterocycles, without employing corrosive and costly metal catalysts, toxic solvents and column chromatography for purification. A systematic study of C-C, C-N and C-O bond formation and efficacy of the scalability have also been confirmed.
published_date 2014-05-21T03:20:24Z
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score 11.016235

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