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Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands

Marco Taddei Orcid Logo, Ferdinando Costantino, Riccardo Vivani

European Journal of Inorganic Chemistry, Volume: 2016, Issue: 27, Pages: 4300 - 4309

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1002/ejic.201600207

Abstract

Microporous metal-organic frameworks (MOFs) based on phosphonic ligands are still a very small family of materials if compared to carboxylate-based MOFs, due to some inherent features that make them challenging to synthesize and to characterize. Nonetheless, metal phosphonates display remarkable che...

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Published in: European Journal of Inorganic Chemistry
ISSN: 1434-1948
Published: Wiley 2016
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa32742
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Abstract: Microporous metal-organic frameworks (MOFs) based on phosphonic ligands are still a very small family of materials if compared to carboxylate-based MOFs, due to some inherent features that make them challenging to synthesize and to characterize. Nonetheless, metal phosphonates display remarkable chemical and thermal robustness that could represent an asset in terms of their employment for practical applications. This feature makes them attractive as alternative materials to classical carboxylate-based MOFs, which often suffer from limited stability. In recent years a number of tritopic phosphonoaromatic ligands have been used as building blocks with the aim of generating open-framework structures. The approach has often proved to be successful and several microporous compounds have been discovered.
Keywords: Metal-organic frameworks; Microporous materials; Absorption; Metal phosphonates; P ligands; Solid-state structures
College: Faculty of Science and Engineering
Issue: 27
Start Page: 4300
End Page: 4309