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Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands

Marco Taddei Orcid Logo, Ferdinando Costantino, Riccardo Vivani

European Journal of Inorganic Chemistry, Volume: 2016, Issue: 27, Pages: 4300 - 4309

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1002/ejic.201600207

Abstract

Microporous metal-organic frameworks (MOFs) based on phosphonic ligands are still a very small family of materials if compared to carboxylate-based MOFs, due to some inherent features that make them challenging to synthesize and to characterize. Nonetheless, metal phosphonates display remarkable che...

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Published in: European Journal of Inorganic Chemistry
ISSN: 1434-1948
Published: Wiley 2016
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa32742
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first_indexed 2017-03-29T13:47:15Z
last_indexed 2018-02-09T05:20:59Z
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spelling 2017-07-06T12:35:14.6471368 v2 32742 2017-03-29 Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2017-03-29 EEN Microporous metal-organic frameworks (MOFs) based on phosphonic ligands are still a very small family of materials if compared to carboxylate-based MOFs, due to some inherent features that make them challenging to synthesize and to characterize. Nonetheless, metal phosphonates display remarkable chemical and thermal robustness that could represent an asset in terms of their employment for practical applications. This feature makes them attractive as alternative materials to classical carboxylate-based MOFs, which often suffer from limited stability. In recent years a number of tritopic phosphonoaromatic ligands have been used as building blocks with the aim of generating open-framework structures. The approach has often proved to be successful and several microporous compounds have been discovered. Journal Article European Journal of Inorganic Chemistry 2016 27 4300 4309 Wiley 1434-1948 Metal-organic frameworks; Microporous materials; Absorption; Metal phosphonates; P ligands; Solid-state structures 1 9 2016 2016-09-01 10.1002/ejic.201600207 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2017-07-06T12:35:14.6471368 2017-03-29T09:52:35.8468953 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Marco Taddei 0000-0003-2805-6375 1 Ferdinando Costantino 2 Riccardo Vivani 3
title Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
spellingShingle Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
Marco Taddei
title_short Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
title_full Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
title_fullStr Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
title_full_unstemmed Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
title_sort Robust Metal-Organic Frameworks Based on Tritopic Phosphonoaromatic Ligands
author_id_str_mv 5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv 5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Marco Taddei
author2 Marco Taddei
Ferdinando Costantino
Riccardo Vivani
format Journal article
container_title European Journal of Inorganic Chemistry
container_volume 2016
container_issue 27
container_start_page 4300
publishDate 2016
institution Swansea University
issn 1434-1948
doi_str_mv 10.1002/ejic.201600207
publisher Wiley
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description Microporous metal-organic frameworks (MOFs) based on phosphonic ligands are still a very small family of materials if compared to carboxylate-based MOFs, due to some inherent features that make them challenging to synthesize and to characterize. Nonetheless, metal phosphonates display remarkable chemical and thermal robustness that could represent an asset in terms of their employment for practical applications. This feature makes them attractive as alternative materials to classical carboxylate-based MOFs, which often suffer from limited stability. In recent years a number of tritopic phosphonoaromatic ligands have been used as building blocks with the aim of generating open-framework structures. The approach has often proved to be successful and several microporous compounds have been discovered.
published_date 2016-09-01T03:40:13Z
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score 11.016235

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