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A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability

Eurig W. Jones, Peter Holliman Orcid Logo, Arthur Connell, Matthew Davies Orcid Logo, Jenny Baker Orcid Logo, Robert J. Hobbs, Sanjay Ghosh, Leo Furnell, Rosie Anthony, Cameron Pleydell-Pearce

Chemical Communications, Volume: 52, Issue: 23, Pages: 4301 - 4304

Swansea University Authors: Peter Holliman Orcid Logo, Matthew Davies Orcid Logo, Jenny Baker Orcid Logo, Cameron Pleydell-Pearce

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DOI (Published version): 10.1039/c5cc09859a

Abstract

We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks. We have bar cast these inks to produce photoactive perovskite thin films w...

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Published in: Chemical Communications
ISSN: 1359-7345 1364-548X
Published: Royal Society of Chemistry (RSC) 2016
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa37040
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Abstract: We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks. We have bar cast these inks to produce photoactive perovskite thin films which are significantly more stable to humidity than solution-processed films. This new method also avoids the use of toxic DMF solvent.
College: Faculty of Science and Engineering
Issue: 23
Start Page: 4301
End Page: 4304