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A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability

Eurig W. Jones, Peter Holliman Orcid Logo, Arthur Connell, Matthew Davies Orcid Logo, Jenny Baker Orcid Logo, Robert J. Hobbs, Sanjay Ghosh, Leo Furnell, Rosie Anthony, Cameron Pleydell-Pearce

Chemical Communications, Volume: 52, Issue: 23, Pages: 4301 - 4304

Swansea University Authors: Peter Holliman Orcid Logo, Matthew Davies Orcid Logo, Jenny Baker Orcid Logo, Cameron Pleydell-Pearce

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DOI (Published version): 10.1039/C5CC09859A

Abstract

We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks. We have bar cast these inks to produce photoactive perovskite thin films w...

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Published in: Chemical Communications
ISSN: 1359-7345 1364-548X
Published: 2016
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URI: https://cronfa.swan.ac.uk/Record/cronfa37040
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spelling 2020-12-08T10:30:33.2199152 v2 37040 2017-11-24 A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability c8f52394d776279c9c690dc26066ddf9 0000-0002-9911-8513 Peter Holliman Peter Holliman true false 4ad478e342120ca3434657eb13527636 0000-0003-2595-5121 Matthew Davies Matthew Davies true false 6913b56f36f0c8cd34d8c9040d2df460 0000-0003-3530-1957 Jenny Baker Jenny Baker true false 564c480cb2abe761533a139c7dbaaca1 Cameron Pleydell-Pearce Cameron Pleydell-Pearce true false 2017-11-24 MTLS We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks. We have bar cast these inks to produce photoactive perovskite thin films which are significantly more stable to humidity than solution-processed films. This new method also avoids the use of toxic DMF solvent. Journal Article Chemical Communications 52 23 4301 4304 1359-7345 1364-548X 21 3 2016 2016-03-21 10.1039/C5CC09859A COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2020-12-08T10:30:33.2199152 2017-11-24T11:37:48.6173011 Professional Services ISS - Uncategorised Eurig W. Jones 1 Peter Holliman 0000-0002-9911-8513 2 Arthur Connell 3 Matthew Davies 0000-0003-2595-5121 4 Jenny Baker 0000-0003-3530-1957 5 Robert J. Hobbs 6 Sanjay Ghosh 7 Leo Furnell 8 Rosie Anthony 9 Cameron Pleydell-Pearce 10 0037040-24112017114958.pdf jones2017(3).pdf 2017-11-24T11:49:58.0700000 Output 1254456 application/pdf Version of Record true 2017-11-24T00:00:00.0000000 This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. true eng
title A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
spellingShingle A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
Peter Holliman
Matthew Davies
Jenny Baker
Cameron Pleydell-Pearce
title_short A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
title_full A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
title_fullStr A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
title_full_unstemmed A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
title_sort A novel dimethylformamide (DMF) free bar-cast method to deposit organolead perovskite thin films with improved stability
author_id_str_mv c8f52394d776279c9c690dc26066ddf9
4ad478e342120ca3434657eb13527636
6913b56f36f0c8cd34d8c9040d2df460
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author_id_fullname_str_mv c8f52394d776279c9c690dc26066ddf9_***_Peter Holliman
4ad478e342120ca3434657eb13527636_***_Matthew Davies
6913b56f36f0c8cd34d8c9040d2df460_***_Jenny Baker
564c480cb2abe761533a139c7dbaaca1_***_Cameron Pleydell-Pearce
author Peter Holliman
Matthew Davies
Jenny Baker
Cameron Pleydell-Pearce
author2 Eurig W. Jones
Peter Holliman
Arthur Connell
Matthew Davies
Jenny Baker
Robert J. Hobbs
Sanjay Ghosh
Leo Furnell
Rosie Anthony
Cameron Pleydell-Pearce
format Journal article
container_title Chemical Communications
container_volume 52
container_issue 23
container_start_page 4301
publishDate 2016
institution Swansea University
issn 1359-7345
1364-548X
doi_str_mv 10.1039/C5CC09859A
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description We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks. We have bar cast these inks to produce photoactive perovskite thin films which are significantly more stable to humidity than solution-processed films. This new method also avoids the use of toxic DMF solvent.
published_date 2016-03-21T03:42:00Z
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score 10.92735