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Photovoltaic performance of CdS/CdTe junctions on ZnO nanorod arrays

Giray Kartopu, D. Turkay, C. Ozcan, W. Hadibrata, P. Aurang, S. Yerci, H.E. Unalan, V. Barrioz, Y. Qu, L. Bowen, A.K. Gürlek, P. Maiello, R. Turan, Stuart Irvine Orcid Logo

Solar Energy Materials and Solar Cells, Volume: 176, Pages: 100 - 108

Swansea University Authors: Giray Kartopu, Stuart Irvine Orcid Logo

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DOI (Published version): 10.1016/j.solmat.2017.11.036

Abstract

One-dimensional nanostructures, such as nanorod (NR) arrays, are expected to improve the photovoltaic (PV) response of solar cells with an ultrathin absorber due to an increased areal (junction) density and light trapping. We report on the deposition of CdS and CdTe:As semiconductor thin films on Zn...

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Published in: Solar Energy Materials and Solar Cells
ISSN: 0927-0248
Published: 2018
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URI: https://cronfa.swan.ac.uk/Record/cronfa37059
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Abstract: One-dimensional nanostructures, such as nanorod (NR) arrays, are expected to improve the photovoltaic (PV) response of solar cells with an ultrathin absorber due to an increased areal (junction) density and light trapping. We report on the deposition of CdS and CdTe:As semiconductor thin films on ZnO NR arrays by means of metalorganic chemical vapour deposition (MOCVD). The change in optical properties of the ZnO NRs upon the growth of CdS shell was monitored and compared to the simulated data, which confirmed the presence of strong light scattering effects in the visible and near infrared regions. The PV performance of nanostructured vs. planar CdS/CdTe solar cells (grown using the material from the same MOCVD run) showed similar conversion efficiencies (~ 4%), despite the current density being lower for the nanostructured cell due to its thicker CdS window. A clear improvement in the quantum efficiency was however observed in the near infrared region, resulting from the light trapping by the ZnO/CdS core-shell NR structure. We also showed that reduction of surface defects and use of high absorber carrier density would boost the efficiency beyond that of planar CdTe solar cells. The reported device performance and the direct observation of light trapping are promising towards optimisation of extremely-thin-absorber CdTe PV devices.
Item Description: Released under a Creative Commons Attribution Non-Commercial No Derivatives License (CC-BY-NC-ND).
Keywords: ZnO nanorods; CdS/CdTe thin film photovoltaics; MOCVD; Light trapping
College: Faculty of Science and Engineering
Start Page: 100
End Page: 108

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