No Cover Image

Journal article 292 views 65 downloads

Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS

S. J. Richardson, M. R. Burton, X. Luo, P. A. Staniec, I. S. Nandhakumar, N. J. Terrill, J. M. Elliott, A. M. Squires, Matthew Burton Orcid Logo

Nanoscale, Volume: 9, Issue: 29, Pages: 10227 - 10232

Swansea University Author: Matthew Burton Orcid Logo

  • richardson2017.pdf

    PDF | Version of Record

    Distributed under the terms of a Creative Commons Attribution Non-Commercial (CC-BY-3.0)

    Download (2.78MB)

Check full text

DOI (Published version): 10.1039/c7nr03321d

Abstract

In this paper, we monitor the real-time growth of mesoporous platinum during electrodeposition using small-angle X-ray scattering (SAXS). Previously, we have demonstrated that platinum films featuring the ‘single diamond’ (Fd3m) morphology can be produced from ‘double diamond’ (Pn3m) lipid cubic pha...

Full description

Published in: Nanoscale
ISSN: 2040-3364 2040-3372
Published: 2017
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa50240
Tags: Add Tag
No Tags, Be the first to tag this record!
first_indexed 2019-05-09T20:01:17Z
last_indexed 2019-07-18T21:34:51Z
id cronfa50240
recordtype SURis
fullrecord <?xml version="1.0"?><rfc1807><datestamp>2019-07-18T14:46:40.0447038</datestamp><bib-version>v2</bib-version><id>50240</id><entry>2019-05-07</entry><title>Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS</title><swanseaauthors><author><sid>2deade2806e39b1f749e9cf67ac640b2</sid><ORCID>0000-0002-0376-6322</ORCID><firstname>Matthew</firstname><surname>Burton</surname><name>Matthew Burton</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2019-05-07</date><deptcode>MTLS</deptcode><abstract>In this paper, we monitor the real-time growth of mesoporous platinum during electrodeposition using small-angle X-ray scattering (SAXS). Previously, we have demonstrated that platinum films featuring the &#x2018;single diamond&#x2019; (Fd3m) morphology can be produced from &#x2018;double diamond&#x2019; (Pn3m) lipid cubic phase templates; the difference in symmetry provides additional scattering signals unique to the metal. Taking advantage of this, we present simultaneous in situ SAXS/electrochemical measurement as the platinum nanostructures grow within the lipid template. This measurement allows us to correlate the nanostructure appearance with the deposition current density and to monitor the evolution of the orientational and lateral ordering of the lipid and platinum during deposition and after template removal. In other periodic metal nanomaterials deposited within any of the normal topology liquid crystal, mesoporous silica or block copolymer templates previously published, the template and emerging metal have the same symmetry, so such a study has not been possible previously.</abstract><type>Journal Article</type><journal>Nanoscale</journal><volume>9</volume><journalNumber>29</journalNumber><paginationStart>10227</paginationStart><paginationEnd>10232</paginationEnd><publisher/><issnPrint>2040-3364</issnPrint><issnElectronic>2040-3372</issnElectronic><keywords/><publishedDay>31</publishedDay><publishedMonth>12</publishedMonth><publishedYear>2017</publishedYear><publishedDate>2017-12-31</publishedDate><doi>10.1039/c7nr03321d</doi><url/><notes/><college>COLLEGE NANME</college><department>Materials Science and Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>MTLS</DepartmentCode><institution>Swansea University</institution><apcterm/><lastEdited>2019-07-18T14:46:40.0447038</lastEdited><Created>2019-05-07T09:57:02.8909088</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Materials Science and Engineering</level></path><authors><author><firstname>S. J.</firstname><surname>Richardson</surname><order>1</order></author><author><firstname>M. R.</firstname><surname>Burton</surname><order>2</order></author><author><firstname>X.</firstname><surname>Luo</surname><order>3</order></author><author><firstname>P. A.</firstname><surname>Staniec</surname><order>4</order></author><author><firstname>I. S.</firstname><surname>Nandhakumar</surname><order>5</order></author><author><firstname>N. J.</firstname><surname>Terrill</surname><order>6</order></author><author><firstname>J. M.</firstname><surname>Elliott</surname><order>7</order></author><author><firstname>A. M.</firstname><surname>Squires</surname><order>8</order></author><author><firstname>Matthew</firstname><surname>Burton</surname><orcid>0000-0002-0376-6322</orcid><order>9</order></author></authors><documents><document><filename>0050240-13052019104519.pdf</filename><originalFilename>richardson2017.pdf</originalFilename><uploaded>2019-05-13T10:45:19.7770000</uploaded><type>Output</type><contentLength>2977438</contentLength><contentType>application/pdf</contentType><version>Version of Record</version><cronfaStatus>true</cronfaStatus><embargoDate>2019-05-13T00:00:00.0000000</embargoDate><documentNotes>Distributed under the terms of a Creative Commons Attribution Non-Commercial (CC-BY-3.0)</documentNotes><copyrightCorrect>true</copyrightCorrect><language>eng</language></document></documents><OutputDurs/></rfc1807>
spelling 2019-07-18T14:46:40.0447038 v2 50240 2019-05-07 Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS 2deade2806e39b1f749e9cf67ac640b2 0000-0002-0376-6322 Matthew Burton Matthew Burton true false 2019-05-07 MTLS In this paper, we monitor the real-time growth of mesoporous platinum during electrodeposition using small-angle X-ray scattering (SAXS). Previously, we have demonstrated that platinum films featuring the ‘single diamond’ (Fd3m) morphology can be produced from ‘double diamond’ (Pn3m) lipid cubic phase templates; the difference in symmetry provides additional scattering signals unique to the metal. Taking advantage of this, we present simultaneous in situ SAXS/electrochemical measurement as the platinum nanostructures grow within the lipid template. This measurement allows us to correlate the nanostructure appearance with the deposition current density and to monitor the evolution of the orientational and lateral ordering of the lipid and platinum during deposition and after template removal. In other periodic metal nanomaterials deposited within any of the normal topology liquid crystal, mesoporous silica or block copolymer templates previously published, the template and emerging metal have the same symmetry, so such a study has not been possible previously. Journal Article Nanoscale 9 29 10227 10232 2040-3364 2040-3372 31 12 2017 2017-12-31 10.1039/c7nr03321d COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2019-07-18T14:46:40.0447038 2019-05-07T09:57:02.8909088 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering S. J. Richardson 1 M. R. Burton 2 X. Luo 3 P. A. Staniec 4 I. S. Nandhakumar 5 N. J. Terrill 6 J. M. Elliott 7 A. M. Squires 8 Matthew Burton 0000-0002-0376-6322 9 0050240-13052019104519.pdf richardson2017.pdf 2019-05-13T10:45:19.7770000 Output 2977438 application/pdf Version of Record true 2019-05-13T00:00:00.0000000 Distributed under the terms of a Creative Commons Attribution Non-Commercial (CC-BY-3.0) true eng
title Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
spellingShingle Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
Matthew Burton
title_short Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
title_full Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
title_fullStr Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
title_full_unstemmed Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
title_sort Watching mesoporous metal films grow during templated electrodeposition with in situ SAXS
author_id_str_mv 2deade2806e39b1f749e9cf67ac640b2
author_id_fullname_str_mv 2deade2806e39b1f749e9cf67ac640b2_***_Matthew Burton
author Matthew Burton
author2 S. J. Richardson
M. R. Burton
X. Luo
P. A. Staniec
I. S. Nandhakumar
N. J. Terrill
J. M. Elliott
A. M. Squires
Matthew Burton
format Journal article
container_title Nanoscale
container_volume 9
container_issue 29
container_start_page 10227
publishDate 2017
institution Swansea University
issn 2040-3364
2040-3372
doi_str_mv 10.1039/c7nr03321d
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
active_str 0
description In this paper, we monitor the real-time growth of mesoporous platinum during electrodeposition using small-angle X-ray scattering (SAXS). Previously, we have demonstrated that platinum films featuring the ‘single diamond’ (Fd3m) morphology can be produced from ‘double diamond’ (Pn3m) lipid cubic phase templates; the difference in symmetry provides additional scattering signals unique to the metal. Taking advantage of this, we present simultaneous in situ SAXS/electrochemical measurement as the platinum nanostructures grow within the lipid template. This measurement allows us to correlate the nanostructure appearance with the deposition current density and to monitor the evolution of the orientational and lateral ordering of the lipid and platinum during deposition and after template removal. In other periodic metal nanomaterials deposited within any of the normal topology liquid crystal, mesoporous silica or block copolymer templates previously published, the template and emerging metal have the same symmetry, so such a study has not been possible previously.
published_date 2017-12-31T03:55:42Z
_version_ 1756237023112331264
score 10.926594