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Ionic Conductivity of Nanocrystalline Metal Fluorides

M. Fichtner, Anji Munnangi Orcid Logo

Photonic and Electronic Properties of Fluoride Materials, Pages: 449 - 463

Swansea University Author: Anji Munnangi Orcid Logo

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DOI (Published version): 10.1016/B978-0-12-801639-8.00020-9

Abstract

Fluoride, a small and monovalent anion with high charge density, is highly mobile in certain metal fluorides and this unique property of fluoride ion makes it attractive for applications like fluoride ion–selective electrodes and batteries based on fluoride ion transport. Most of the fluoride conduc...

Full description

Published in: Photonic and Electronic Properties of Fluoride Materials
ISBN: 9780128016398
Published: Elsevier 2016
URI: https://cronfa.swan.ac.uk/Record/cronfa51588
first_indexed 2022-11-16T13:28:34Z
last_indexed 2023-01-11T14:28:24Z
id cronfa51588
recordtype SURis
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spelling 2022-11-16T13:28:35.8021014 v2 51588 2019-08-27 Ionic Conductivity of Nanocrystalline Metal Fluorides 3ed0b4f2ff4fb9e87c7a73e7a3c39da7 0000-0001-9101-0252 Anji Munnangi Anji Munnangi true false 2019-08-27 EAAS Fluoride, a small and monovalent anion with high charge density, is highly mobile in certain metal fluorides and this unique property of fluoride ion makes it attractive for applications like fluoride ion–selective electrodes and batteries based on fluoride ion transport. Most of the fluoride conductivity studies were made on single crystals. Recently it was found that the ionic conductivity of nanocrystalline CaF2 increases significantly compared to single crystals. This generated fundamental interest on the ionic conductivity and ionic conduction mechanism of nanocrystalline metal fluorides. Further the use of nanocrystalline fluoride ion conductors was demonstrated in fluoride ion batteries. The following chapter is focused on the ionic conductivity of nanocrystalline metal fluorides, metal fluoride composites, and the effect of synthesis method on the ionic conductivity. Book chapter Photonic and Electronic Properties of Fluoride Materials 449 463 Elsevier 9780128016398 Fluoride ion, Fluoride ion batteries, Fluoride ion selective electrode, FluoriteIonic conductivity, Metal fluoride composites, Tysonite 25 3 2016 2016-03-25 10.1016/B978-0-12-801639-8.00020-9 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University 2022-11-16T13:28:35.8021014 2019-08-27T12:31:47.1382221 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry M. Fichtner 1 Anji Munnangi 0000-0001-9101-0252 2
title Ionic Conductivity of Nanocrystalline Metal Fluorides
spellingShingle Ionic Conductivity of Nanocrystalline Metal Fluorides
Anji Munnangi
title_short Ionic Conductivity of Nanocrystalline Metal Fluorides
title_full Ionic Conductivity of Nanocrystalline Metal Fluorides
title_fullStr Ionic Conductivity of Nanocrystalline Metal Fluorides
title_full_unstemmed Ionic Conductivity of Nanocrystalline Metal Fluorides
title_sort Ionic Conductivity of Nanocrystalline Metal Fluorides
author_id_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7
author_id_fullname_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7_***_Anji Munnangi
author Anji Munnangi
author2 M. Fichtner
Anji Munnangi
format Book chapter
container_title Photonic and Electronic Properties of Fluoride Materials
container_start_page 449
publishDate 2016
institution Swansea University
isbn 9780128016398
doi_str_mv 10.1016/B978-0-12-801639-8.00020-9
publisher Elsevier
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry
document_store_str 0
active_str 0
description Fluoride, a small and monovalent anion with high charge density, is highly mobile in certain metal fluorides and this unique property of fluoride ion makes it attractive for applications like fluoride ion–selective electrodes and batteries based on fluoride ion transport. Most of the fluoride conductivity studies were made on single crystals. Recently it was found that the ionic conductivity of nanocrystalline CaF2 increases significantly compared to single crystals. This generated fundamental interest on the ionic conductivity and ionic conduction mechanism of nanocrystalline metal fluorides. Further the use of nanocrystalline fluoride ion conductors was demonstrated in fluoride ion batteries. The following chapter is focused on the ionic conductivity of nanocrystalline metal fluorides, metal fluoride composites, and the effect of synthesis method on the ionic conductivity.
published_date 2016-03-25T04:33:54Z
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score 11.099424

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