Journal article 1032 views
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries
Flexible and Printed Electronics, Volume: 4, Issue: 3, Start page: 035003
Swansea University Author: Timothy Claypole
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DOI (Published version): 10.1088/2058-8585/ab38e2
Abstract
Primary zinc–carbon batteries with a coplanar battery architecture were prepared by screen printing. Prior to battery activation by printing of an acidic zinc chloride electrolyte, printed zinc and manganese dioxide electrodes were compacted by calendering. Material densification of the electodes re...
Published in: | Flexible and Printed Electronics |
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ISSN: | 2058-8585 |
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2019
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URI: | https://cronfa.swan.ac.uk/Record/cronfa51736 |
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2019-09-09T11:52:01.2869790 v2 51736 2019-09-09 The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries 7735385522f1e68a8775b4f709e91d55 Timothy Claypole Timothy Claypole true false 2019-09-09 Primary zinc–carbon batteries with a coplanar battery architecture were prepared by screen printing. Prior to battery activation by printing of an acidic zinc chloride electrolyte, printed zinc and manganese dioxide electrodes were compacted by calendering. Material densification of the electodes resulted in electrode layer thickness reduction on both sides, modified micropore surface area and volume on the cathode side. Galvanostatic impedance measurements and chronopotentiometry were used to characterise fabricated batteries with the individually prepared electrode configurations. While calendering of both electrodes of the batteries showed adverse effects by an increase of internal resistances and a reduction of discharge capacities, exclusive calendering of the zinc anode increased the active material utilisation by electrochemical cell reaction and thus the discharge efficiency of the battery. Journal Article Flexible and Printed Electronics 4 3 035003 2058-8585 21 7 2019 2019-07-21 10.1088/2058-8585/ab38e2 COLLEGE NANME COLLEGE CODE Swansea University 2019-09-09T11:52:01.2869790 2019-09-09T11:50:48.1443041 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering Patrick Rassek 1 Erich Steiner 2 Michael Herrenbauer 3 Timothy Claypole 4 |
title |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries |
spellingShingle |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries Timothy Claypole |
title_short |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries |
title_full |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries |
title_fullStr |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries |
title_full_unstemmed |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries |
title_sort |
The effect of electrode calendering on the performance of fully printed Zn∣MnO2 batteries |
author_id_str_mv |
7735385522f1e68a8775b4f709e91d55 |
author_id_fullname_str_mv |
7735385522f1e68a8775b4f709e91d55_***_Timothy Claypole |
author |
Timothy Claypole |
author2 |
Patrick Rassek Erich Steiner Michael Herrenbauer Timothy Claypole |
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Journal article |
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Flexible and Printed Electronics |
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4 |
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3 |
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035003 |
publishDate |
2019 |
institution |
Swansea University |
issn |
2058-8585 |
doi_str_mv |
10.1088/2058-8585/ab38e2 |
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Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering |
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description |
Primary zinc–carbon batteries with a coplanar battery architecture were prepared by screen printing. Prior to battery activation by printing of an acidic zinc chloride electrolyte, printed zinc and manganese dioxide electrodes were compacted by calendering. Material densification of the electodes resulted in electrode layer thickness reduction on both sides, modified micropore surface area and volume on the cathode side. Galvanostatic impedance measurements and chronopotentiometry were used to characterise fabricated batteries with the individually prepared electrode configurations. While calendering of both electrodes of the batteries showed adverse effects by an increase of internal resistances and a reduction of discharge capacities, exclusive calendering of the zinc anode increased the active material utilisation by electrochemical cell reaction and thus the discharge efficiency of the battery. |
published_date |
2019-07-21T07:48:30Z |
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1822025067580620800 |
score |
11.048042 |