No Cover Image

Journal article 348 views

Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications

C. S. Santos, R. D. de Oliveira, Sudhagar Pitchaimuthu Orcid Logo, L. F. Marchesi, C. A. Pessôa

Chemical Papers, Volume: 74, Pages: 887 - 894

Swansea University Author: Sudhagar Pitchaimuthu Orcid Logo

Full text not available from this repository: check for access using links below.

Check full text

DOI (Published version): 10.1007/s11696-019-00920-9

Abstract

This work describes the electrochemical characterization toward supercapacitive properties of a modified electrode based on MnO2 electrodeposited onto carbon felt electrode (CFE/MnO2). Raman analysis confirmed the electrode modification and FEG-SEM images showed a 3D network structure with a homogen...

Full description

Published in: Chemical Papers
ISSN: 2585-7290 1336-9075
Published: Springer Science and Business Media LLC 2020
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa52661
Tags: Add Tag
No Tags, Be the first to tag this record!
first_indexed 2019-11-07T13:14:17Z
last_indexed 2023-01-11T14:29:54Z
id cronfa52661
recordtype SURis
fullrecord <?xml version="1.0"?><rfc1807><datestamp>2022-11-16T13:43:32.4728345</datestamp><bib-version>v2</bib-version><id>52661</id><entry>2019-11-07</entry><title>Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications</title><swanseaauthors><author><sid>2fdbee02f4bfc5a1b174c8bd04afbd2b</sid><ORCID>0000-0001-9098-8806</ORCID><firstname>Sudhagar</firstname><surname>Pitchaimuthu</surname><name>Sudhagar Pitchaimuthu</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2019-11-07</date><deptcode>EEN</deptcode><abstract>This work describes the electrochemical characterization toward supercapacitive properties of a modified electrode based on MnO2 electrodeposited onto carbon felt electrode (CFE/MnO2). Raman analysis confirmed the electrode modification and FEG-SEM images showed a 3D network structure with a homogeneous deposit of the MnO2 film. The morphology of the electrodeposited film showed to be dependent on the electrodeposition applied potential and time. Cyclic voltammetry and galvanostatic charge/discharge curve results showed that the charge storage process is reversible and a combination of EDLC and pseudocapacitive behavior. Under optimized conditions (1.2 V and 600 s), the modified electrode presented a specific capacitance of 541 F g&#x2212;1 in an applied current density of 0.2 A g&#x2212;1, which was attributed to a favored accessibility of the electrolyte on the film porous due to morphological issues. Besides, the modified electrode revealed a good capacitance retention of 80% in an applied current density of 1.0 A g&#x2212;1 after 1000 cycles.</abstract><type>Journal Article</type><journal>Chemical Papers</journal><volume>74</volume><journalNumber/><paginationStart>887</paginationStart><paginationEnd>894</paginationEnd><publisher>Springer Science and Business Media LLC</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>2585-7290</issnPrint><issnElectronic>1336-9075</issnElectronic><keywords>Carbon felt, MnO2, Electrodeposition, Supercapacitive properties</keywords><publishedDay>1</publishedDay><publishedMonth>3</publishedMonth><publishedYear>2020</publishedYear><publishedDate>2020-03-01</publishedDate><doi>10.1007/s11696-019-00920-9</doi><url>http://dx.doi.org/10.1007/s11696-019-00920-9</url><notes/><college>COLLEGE NANME</college><department>Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>EEN</DepartmentCode><institution>Swansea University</institution><apcterm/><funders/><projectreference/><lastEdited>2022-11-16T13:43:32.4728345</lastEdited><Created>2019-11-07T10:24:50.2893883</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Chemistry</level></path><authors><author><firstname>C. S.</firstname><surname>Santos</surname><order>1</order></author><author><firstname>R. D. de</firstname><surname>Oliveira</surname><order>2</order></author><author><firstname>Sudhagar</firstname><surname>Pitchaimuthu</surname><orcid>0000-0001-9098-8806</orcid><order>3</order></author><author><firstname>L. F.</firstname><surname>Marchesi</surname><order>4</order></author><author><firstname>C. A.</firstname><surname>Pess&#xF4;a</surname><order>5</order></author></authors><documents/><OutputDurs/></rfc1807>
spelling 2022-11-16T13:43:32.4728345 v2 52661 2019-11-07 Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications 2fdbee02f4bfc5a1b174c8bd04afbd2b 0000-0001-9098-8806 Sudhagar Pitchaimuthu Sudhagar Pitchaimuthu true false 2019-11-07 EEN This work describes the electrochemical characterization toward supercapacitive properties of a modified electrode based on MnO2 electrodeposited onto carbon felt electrode (CFE/MnO2). Raman analysis confirmed the electrode modification and FEG-SEM images showed a 3D network structure with a homogeneous deposit of the MnO2 film. The morphology of the electrodeposited film showed to be dependent on the electrodeposition applied potential and time. Cyclic voltammetry and galvanostatic charge/discharge curve results showed that the charge storage process is reversible and a combination of EDLC and pseudocapacitive behavior. Under optimized conditions (1.2 V and 600 s), the modified electrode presented a specific capacitance of 541 F g−1 in an applied current density of 0.2 A g−1, which was attributed to a favored accessibility of the electrolyte on the film porous due to morphological issues. Besides, the modified electrode revealed a good capacitance retention of 80% in an applied current density of 1.0 A g−1 after 1000 cycles. Journal Article Chemical Papers 74 887 894 Springer Science and Business Media LLC 2585-7290 1336-9075 Carbon felt, MnO2, Electrodeposition, Supercapacitive properties 1 3 2020 2020-03-01 10.1007/s11696-019-00920-9 http://dx.doi.org/10.1007/s11696-019-00920-9 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2022-11-16T13:43:32.4728345 2019-11-07T10:24:50.2893883 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry C. S. Santos 1 R. D. de Oliveira 2 Sudhagar Pitchaimuthu 0000-0001-9098-8806 3 L. F. Marchesi 4 C. A. Pessôa 5
title Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
spellingShingle Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
Sudhagar Pitchaimuthu
title_short Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
title_full Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
title_fullStr Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
title_full_unstemmed Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
title_sort Modified electrodes based on MnO2 electrodeposited onto carbon felt: an evaluation toward supercapacitive applications
author_id_str_mv 2fdbee02f4bfc5a1b174c8bd04afbd2b
author_id_fullname_str_mv 2fdbee02f4bfc5a1b174c8bd04afbd2b_***_Sudhagar Pitchaimuthu
author Sudhagar Pitchaimuthu
author2 C. S. Santos
R. D. de Oliveira
Sudhagar Pitchaimuthu
L. F. Marchesi
C. A. Pessôa
format Journal article
container_title Chemical Papers
container_volume 74
container_start_page 887
publishDate 2020
institution Swansea University
issn 2585-7290
1336-9075
doi_str_mv 10.1007/s11696-019-00920-9
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry
url http://dx.doi.org/10.1007/s11696-019-00920-9
document_store_str 0
active_str 0
description This work describes the electrochemical characterization toward supercapacitive properties of a modified electrode based on MnO2 electrodeposited onto carbon felt electrode (CFE/MnO2). Raman analysis confirmed the electrode modification and FEG-SEM images showed a 3D network structure with a homogeneous deposit of the MnO2 film. The morphology of the electrodeposited film showed to be dependent on the electrodeposition applied potential and time. Cyclic voltammetry and galvanostatic charge/discharge curve results showed that the charge storage process is reversible and a combination of EDLC and pseudocapacitive behavior. Under optimized conditions (1.2 V and 600 s), the modified electrode presented a specific capacitance of 541 F g−1 in an applied current density of 0.2 A g−1, which was attributed to a favored accessibility of the electrolyte on the film porous due to morphological issues. Besides, the modified electrode revealed a good capacitance retention of 80% in an applied current density of 1.0 A g−1 after 1000 cycles.
published_date 2020-03-01T04:05:09Z
_version_ 1763753391185461248
score 10.998116

Similar Items