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Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution)
ACS Applied Materials & Interfaces, Volume: 12, Issue: 22, Pages: 24877 - 24882
Swansea University Authors: Rongsheng Cai , Chedly Tizaoui , Richard Palmer , Jerome Vernieres
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DOI (Published version): 10.1021/acsami.0c05955
Abstract
The deposition of precisely controlled clusters from the beam onto suitable supports represents a novel method to prepare advanced cluster-based catalysts. In principle, cluster size, composition, and morphology can be tuned or selected prior to deposition. The newly invented matrix assembly cluster...
Published in: | ACS Applied Materials & Interfaces |
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ISSN: | 1944-8244 1944-8252 |
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American Chemical Society (ACS)
2020
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URI: | https://cronfa.swan.ac.uk/Record/cronfa54290 |
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In principle, cluster size, composition, and morphology can be tuned or selected prior to deposition. The newly invented matrix assembly cluster source (MACS) offers one solution to the long-standing problem of low cluster deposition rate. Demonstrations of the cluster activities under realistic reaction conditions are now needed. We deposited elemental silver (Ag) and gold (Au) clusters onto gram-scale powders of commercial titanium dioxide (TiO2) to investigate the catalytic oxidation of nitrophenol (a representative pollutant in water) by ozone in aqueous solution, as relevant to the removal of waste drugs from the water supply. A range of techniques, including scanning transmission electron microscopy (STEM), Brunauer–Emmett–Teller (BET) surface area test, and X-ray photoelectron spectroscopy (XPS), were employed to reveal the catalyst size, morphology, surface area, and oxidation state. Both the Ag and Au cluster catalysts proved active for the nitrophenol ozonation. The cluster catalysts showed activities at least comparable to those of catalysts made by traditional chemical methods in the literature, demonstrating the potential applications of the cluster beam deposition method for practical heterogeneous catalysis in solution.</abstract><type>Journal Article</type><journal>ACS Applied Materials & Interfaces</journal><volume>12</volume><journalNumber>22</journalNumber><paginationStart>24877</paginationStart><paginationEnd>24882</paginationEnd><publisher>American Chemical Society (ACS)</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>1944-8244</issnPrint><issnElectronic>1944-8252</issnElectronic><keywords>heterogeneous catalysis; cluster beam deposition; nitrophenol ozonation; water treatment; metal clusters; scale-up; matrix assembly cluster source (MACS); titanium dioxide powder</keywords><publishedDay>3</publishedDay><publishedMonth>6</publishedMonth><publishedYear>2020</publishedYear><publishedDate>2020-06-03</publishedDate><doi>10.1021/acsami.0c05955</doi><url>http://dx.doi.org/10.1021/acsami.0c05955</url><notes/><college>COLLEGE NANME</college><department>Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>EEN</DepartmentCode><institution>Swansea University</institution><apcterm/><funders>UKRI, EP/K006061/2</funders><lastEdited>2021-08-29T16:50:23.9795468</lastEdited><Created>2020-05-20T13:13:11.2088140</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Chemical Engineering</level></path><authors><author><firstname>Rongsheng</firstname><surname>Cai</surname><orcid>0000-0002-2148-0563</orcid><order>1</order></author><author><firstname>Francesca</firstname><surname>Martelli</surname><order>2</order></author><author><firstname>Jerome</firstname><surname>Vernieres</surname><order>3</order></author><author><firstname>Stefania</firstname><surname>Albonetti</surname><order>4</order></author><author><firstname>Nikolaos</firstname><surname>Dimitratos</surname><order>5</order></author><author><firstname>Chedly</firstname><surname>Tizaoui</surname><orcid>0000-0003-2159-7881</orcid><order>6</order></author><author><firstname>Richard</firstname><surname>Palmer</surname><orcid>0000-0001-8728-8083</orcid><order>7</order></author><author><firstname>Jerome</firstname><surname>Vernieres</surname><order>8</order></author></authors><documents><document><filename>54290__17543__65389cb0261f4c7282e1186e879bc38c.pdf</filename><originalFilename>54290VOR.pdf</originalFilename><uploaded>2020-06-18T18:31:39.2249493</uploaded><type>Output</type><contentLength>3397204</contentLength><contentType>application/pdf</contentType><version>Version of Record</version><cronfaStatus>true</cronfaStatus><documentNotes>Released under the terms of a Creative Commons Attribution License (CC-BY).</documentNotes><copyrightCorrect>true</copyrightCorrect><language>English</language><licence>http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html</licence></document></documents><OutputDurs/></rfc1807> |
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2021-08-29T16:50:23.9795468 v2 54290 2020-05-20 Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) c2d38332a07bde5ce1ce66d8750f652e 0000-0002-2148-0563 Rongsheng Cai Rongsheng Cai true false 4b34a0286d3c0b0b081518fa6987031d 0000-0003-2159-7881 Chedly Tizaoui Chedly Tizaoui true false 6ae369618efc7424d9774377536ea519 0000-0001-8728-8083 Richard Palmer Richard Palmer true false 53706ee4229ff15c98713442422ecd4b Jerome Vernieres Jerome Vernieres true false 2020-05-20 EEN The deposition of precisely controlled clusters from the beam onto suitable supports represents a novel method to prepare advanced cluster-based catalysts. In principle, cluster size, composition, and morphology can be tuned or selected prior to deposition. The newly invented matrix assembly cluster source (MACS) offers one solution to the long-standing problem of low cluster deposition rate. Demonstrations of the cluster activities under realistic reaction conditions are now needed. We deposited elemental silver (Ag) and gold (Au) clusters onto gram-scale powders of commercial titanium dioxide (TiO2) to investigate the catalytic oxidation of nitrophenol (a representative pollutant in water) by ozone in aqueous solution, as relevant to the removal of waste drugs from the water supply. A range of techniques, including scanning transmission electron microscopy (STEM), Brunauer–Emmett–Teller (BET) surface area test, and X-ray photoelectron spectroscopy (XPS), were employed to reveal the catalyst size, morphology, surface area, and oxidation state. Both the Ag and Au cluster catalysts proved active for the nitrophenol ozonation. The cluster catalysts showed activities at least comparable to those of catalysts made by traditional chemical methods in the literature, demonstrating the potential applications of the cluster beam deposition method for practical heterogeneous catalysis in solution. Journal Article ACS Applied Materials & Interfaces 12 22 24877 24882 American Chemical Society (ACS) 1944-8244 1944-8252 heterogeneous catalysis; cluster beam deposition; nitrophenol ozonation; water treatment; metal clusters; scale-up; matrix assembly cluster source (MACS); titanium dioxide powder 3 6 2020 2020-06-03 10.1021/acsami.0c05955 http://dx.doi.org/10.1021/acsami.0c05955 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University UKRI, EP/K006061/2 2021-08-29T16:50:23.9795468 2020-05-20T13:13:11.2088140 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Rongsheng Cai 0000-0002-2148-0563 1 Francesca Martelli 2 Jerome Vernieres 3 Stefania Albonetti 4 Nikolaos Dimitratos 5 Chedly Tizaoui 0000-0003-2159-7881 6 Richard Palmer 0000-0001-8728-8083 7 Jerome Vernieres 8 54290__17543__65389cb0261f4c7282e1186e879bc38c.pdf 54290VOR.pdf 2020-06-18T18:31:39.2249493 Output 3397204 application/pdf Version of Record true Released under the terms of a Creative Commons Attribution License (CC-BY). true English http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html |
title |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) |
spellingShingle |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) Rongsheng Cai Chedly Tizaoui Richard Palmer Jerome Vernieres |
title_short |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) |
title_full |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) |
title_fullStr |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) |
title_full_unstemmed |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) |
title_sort |
Scale-Up of Cluster Beam Deposition to the Gram Scale with the Matrix Assembly Cluster Source for Heterogeneous Catalysis (Catalytic Ozonation of Nitrophenol in Aqueous Solution) |
author_id_str_mv |
c2d38332a07bde5ce1ce66d8750f652e 4b34a0286d3c0b0b081518fa6987031d 6ae369618efc7424d9774377536ea519 53706ee4229ff15c98713442422ecd4b |
author_id_fullname_str_mv |
c2d38332a07bde5ce1ce66d8750f652e_***_Rongsheng Cai 4b34a0286d3c0b0b081518fa6987031d_***_Chedly Tizaoui 6ae369618efc7424d9774377536ea519_***_Richard Palmer 53706ee4229ff15c98713442422ecd4b_***_Jerome Vernieres |
author |
Rongsheng Cai Chedly Tizaoui Richard Palmer Jerome Vernieres |
author2 |
Rongsheng Cai Francesca Martelli Jerome Vernieres Stefania Albonetti Nikolaos Dimitratos Chedly Tizaoui Richard Palmer Jerome Vernieres |
format |
Journal article |
container_title |
ACS Applied Materials & Interfaces |
container_volume |
12 |
container_issue |
22 |
container_start_page |
24877 |
publishDate |
2020 |
institution |
Swansea University |
issn |
1944-8244 1944-8252 |
doi_str_mv |
10.1021/acsami.0c05955 |
publisher |
American Chemical Society (ACS) |
college_str |
Faculty of Science and Engineering |
hierarchytype |
|
hierarchy_top_id |
facultyofscienceandengineering |
hierarchy_top_title |
Faculty of Science and Engineering |
hierarchy_parent_id |
facultyofscienceandengineering |
hierarchy_parent_title |
Faculty of Science and Engineering |
department_str |
School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering |
url |
http://dx.doi.org/10.1021/acsami.0c05955 |
document_store_str |
1 |
active_str |
0 |
description |
The deposition of precisely controlled clusters from the beam onto suitable supports represents a novel method to prepare advanced cluster-based catalysts. In principle, cluster size, composition, and morphology can be tuned or selected prior to deposition. The newly invented matrix assembly cluster source (MACS) offers one solution to the long-standing problem of low cluster deposition rate. Demonstrations of the cluster activities under realistic reaction conditions are now needed. We deposited elemental silver (Ag) and gold (Au) clusters onto gram-scale powders of commercial titanium dioxide (TiO2) to investigate the catalytic oxidation of nitrophenol (a representative pollutant in water) by ozone in aqueous solution, as relevant to the removal of waste drugs from the water supply. A range of techniques, including scanning transmission electron microscopy (STEM), Brunauer–Emmett–Teller (BET) surface area test, and X-ray photoelectron spectroscopy (XPS), were employed to reveal the catalyst size, morphology, surface area, and oxidation state. Both the Ag and Au cluster catalysts proved active for the nitrophenol ozonation. The cluster catalysts showed activities at least comparable to those of catalysts made by traditional chemical methods in the literature, demonstrating the potential applications of the cluster beam deposition method for practical heterogeneous catalysis in solution. |
published_date |
2020-06-03T04:07:44Z |
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1763753553483005952 |
score |
10.998116 |