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Adsorption of Lead Ions by a Green AC/HKUST-1 Nanocomposite
Nanomaterials, Volume: 10, Issue: 9, Start page: 1647
Swansea University Author:
Zari Tehrani
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DOI (Published version): 10.3390/nano10091647
Abstract
A new nanocomposite consisting of activated carbon (AC) from the Cortaderia selloana flower and copper-based metal-organic framework (HKUST-1) was synthesized through a single-step solvothermal method and applied for the removal of lead ions from aqueous solution through adsorption. The nanocomposit...
| Published in: | Nanomaterials |
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| ISSN: | 2079-4991 |
| Published: |
MDPI AG
2020
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| Online Access: |
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa55193 |
| Abstract: |
A new nanocomposite consisting of activated carbon (AC) from the Cortaderia selloana flower and copper-based metal-organic framework (HKUST-1) was synthesized through a single-step solvothermal method and applied for the removal of lead ions from aqueous solution through adsorption. The nanocomposite, AC/HKUST-1, was characterized by Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Fourier Transform Infrared (FTIR), and Energy-Dispersive X-ray Spectroscopy (EDX) methods. The SEM images of both HKUST-1 and AC/HKUST-1 contain octahedral crystals. Different factors affecting adsorption processes, such as solution pH, contact time, adsorbent dose, and initial metal pollution concentration, were studied. The adsorption isotherm was evaluated with Freundlich and Langmuir models, and the latter was fitted with the experimental data on adsorption of lead ion. The adsorption capacity was 249.4 mg g−1 for 15 min at pH 6.1, which is an excellent result rivalling previously reported lead adsorbents considering the conditions. These nanocomposites show considerable potential for use as a functional material in the ink formulation of lead sensors. |
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| Keywords: |
metal organic framework; active carbon; heavy metal; low-cost adsorbents; lead sensor; Cortaderia selloana |
| College: |
Faculty of Science and Engineering |
| Issue: |
9 |
| Start Page: |
1647 |