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Schottky barrier heights of defect-free metal/ZnO, CdO, MgO, and SrO interfaces

Jiaqi Chen, Zhaofu Zhang, Yuzheng Guo Orcid Logo, John Robertson

Journal of Applied Physics, Volume: 129, Issue: 17, Start page: 175304

Swansea University Author: Yuzheng Guo Orcid Logo

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DOI (Published version): 10.1063/5.0047447

Abstract

The Schottky barrier heights (SBHs) of defect-free interfaces of ZnO, CdO, MgO, and SrO with various metals and different terminations are investigated by density functional supercell calculations. The oxide bands are corrected for their density functional bandgap error by applying a U-type term to...

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Published in: Journal of Applied Physics
ISSN: 0021-8979 1089-7550
Published: AIP Publishing 2021
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URI: https://cronfa.swan.ac.uk/Record/cronfa56935
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Abstract: The Schottky barrier heights (SBHs) of defect-free interfaces of ZnO, CdO, MgO, and SrO with various metals and different terminations are investigated by density functional supercell calculations. The oxide bands are corrected for their density functional bandgap error by applying a U-type term to their metal-d and O-p states where necessary. The p-type SBHs are found to decrease linearly with increasing metal work function. The pinning factor S of the non-polar and polar interfaces is similar for each oxide. S is found to be 0.26, 0.56, 0.74, and 0.96 for CdO, ZnO, MgO, and SrO, respectively, with S increasing with increasing oxide ionicity. The calculated pinning factors are generally consistent with the metal-induced gap state model in terms of variation in ionicity and dielectric constant. A significant shift of SBHs from the non-polar to the polar interfaces of 0.4, 1, and 0.5‚ÄČeV for ZnO, MgO, and SrO, respectively, is found, which can be explained by an interfacial dipole. Our results are also useful to describe Co,Fe|MgO interfaces in magnetic tunnel junctions.
College: Faculty of Science and Engineering
Issue: 17
Start Page: 175304