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Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application

Prerna Mahajan, Anoop Singh, Ram Datt Orcid Logo, Wing Chung Tsoi Orcid Logo, Vinay Gupta, Sandeep Arya Orcid Logo

The European Physical Journal Plus, Volume: 139, Issue: 2

Swansea University Authors: Ram Datt Orcid Logo, Wing Chung Tsoi Orcid Logo

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Abstract

Here, a transparent luminescent down-conversion material (DCM) of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles has been used for OSCs application. The core@shell nanoparticles were prepared via a chemical sol–gel process. In OSCs, the prepared DCM is coated at backside of indium-doped tin oxide gl...

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Published in: The European Physical Journal Plus
ISSN: 2190-5444
Published: Springer Science and Business Media LLC 2024
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URI: https://cronfa.swan.ac.uk/Record/cronfa66414
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spelling v2 66414 2024-05-14 Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application 350d1f64ddd9787a6eda98611dcbb8d2 0000-0003-3109-1278 Ram Datt Ram Datt true false 7e5f541df6635a9a8e1a579ff2de5d56 0000-0003-3836-5139 Wing Chung Tsoi Wing Chung Tsoi true false 2024-05-14 EAAS Here, a transparent luminescent down-conversion material (DCM) of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles has been used for OSCs application. The core@shell nanoparticles were prepared via a chemical sol–gel process. In OSCs, the prepared DCM is coated at backside of indium-doped tin oxide glass substrate, and the final device is called optimized device; whereas, the uncoated device is defined as control device. The power conversion efficiency of optimized device improved from 7.95 to 8.45%, as a result of the DCM re-emitting ultraviolet light in the visible range. Most importantly, the control device had inadequate stability under UV-B light, and within 90 min, efficiency has decreased by 38%. However, optimized device shows significantly superior performance by maintaining 84% of its initial PCE even after 90 min. It has been suggested that the NaYF4:Pr3+@NaYF4:Eu3+ DCM minimizes the ultraviolet deterioration while also improving the PCE of OSCs. Journal Article The European Physical Journal Plus 139 2 Springer Science and Business Media LLC 2190-5444 23 2 2024 2024-02-23 10.1140/epjp/s13360-024-04982-x COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University This work was supported by the Science and Engineering Research Board (SERB), India (File no. EEQ/2021/000172). 2024-06-12T16:59:27.1693068 2024-05-14T11:47:53.2413721 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Prerna Mahajan 1 Anoop Singh 2 Ram Datt 0000-0003-3109-1278 3 Wing Chung Tsoi 0000-0003-3836-5139 4 Vinay Gupta 5 Sandeep Arya 0000-0001-5059-0609 6 66414__30356__a8a9123ccb3e4d45898152b2c8e1ee72.pdf 66414.pdf 2024-05-14T12:40:30.1087646 Output 1765900 application/pdf Accepted Manuscript true Author accepted manuscript document released under the terms of a Creative Commons CC-BY licence using the Swansea University Research Publications Policy (rights retention). true eng https://creativecommons.org/licenses/by/4.0/deed.en
title Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
spellingShingle Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
Ram Datt
Wing Chung Tsoi
title_short Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
title_full Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
title_fullStr Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
title_full_unstemmed Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
title_sort Synthesis and characterization of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles as down-conversion material for organic solar cells application
author_id_str_mv 350d1f64ddd9787a6eda98611dcbb8d2
7e5f541df6635a9a8e1a579ff2de5d56
author_id_fullname_str_mv 350d1f64ddd9787a6eda98611dcbb8d2_***_Ram Datt
7e5f541df6635a9a8e1a579ff2de5d56_***_Wing Chung Tsoi
author Ram Datt
Wing Chung Tsoi
author2 Prerna Mahajan
Anoop Singh
Ram Datt
Wing Chung Tsoi
Vinay Gupta
Sandeep Arya
format Journal article
container_title The European Physical Journal Plus
container_volume 139
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publishDate 2024
institution Swansea University
issn 2190-5444
doi_str_mv 10.1140/epjp/s13360-024-04982-x
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
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hierarchy_parent_id facultyofscienceandengineering
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department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
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description Here, a transparent luminescent down-conversion material (DCM) of NaYF4:Pr3+@NaYF4:Eu3+ core@shell nanoparticles has been used for OSCs application. The core@shell nanoparticles were prepared via a chemical sol–gel process. In OSCs, the prepared DCM is coated at backside of indium-doped tin oxide glass substrate, and the final device is called optimized device; whereas, the uncoated device is defined as control device. The power conversion efficiency of optimized device improved from 7.95 to 8.45%, as a result of the DCM re-emitting ultraviolet light in the visible range. Most importantly, the control device had inadequate stability under UV-B light, and within 90 min, efficiency has decreased by 38%. However, optimized device shows significantly superior performance by maintaining 84% of its initial PCE even after 90 min. It has been suggested that the NaYF4:Pr3+@NaYF4:Eu3+ DCM minimizes the ultraviolet deterioration while also improving the PCE of OSCs.
published_date 2024-02-23T16:59:25Z
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