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Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes

Ershad Parvazian, David Beynon Orcid Logo, Olivia Jenkins, Rahul Patidar, James McGettrick Orcid Logo, SAMUAL NGOMBE, Bhushan Patil, Rodrigo Garcia Rodriguez, Karen Valadez Villalobos, Pete Davies, Matthew Davies Orcid Logo, Trystan Watson Orcid Logo

Communications Materials, Volume: 5, Issue: 1

Swansea University Authors: Ershad Parvazian, David Beynon Orcid Logo, Rahul Patidar, James McGettrick Orcid Logo, SAMUAL NGOMBE, Bhushan Patil, Rodrigo Garcia Rodriguez, Karen Valadez Villalobos, Pete Davies, Matthew Davies Orcid Logo, Trystan Watson Orcid Logo

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Abstract

Perovskite solar cells hold promise for cost-effective, high-efficiency renewable energy generation; yet their commercialization is hindered by progress towards scalable fabrication methods. Roll-to-roll processing is a promising solution for large-scale production, and the incorporation of Roll-to-...

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Published in: Communications Materials
ISSN: 2662-4443
Published: Springer Science and Business Media LLC 2024
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa66508
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Abstract: Perovskite solar cells hold promise for cost-effective, high-efficiency renewable energy generation; yet their commercialization is hindered by progress towards scalable fabrication methods. Roll-to-roll processing is a promising solution for large-scale production, and the incorporation of Roll-to-roll coated carbon electrodes offers several additional advantages, including low-cost manufacturing and high-stability. Introducing a compatible hole transporting layer between perovskite and carbon significantly improves performance. Here we present a study comparing four interlayers (Spiro-MeOTAD, PTAA, PEDOT, and P3HT) in printed devices, assessing efficiency, stability, and scalability. Our results reveal that spiro-MeOTAD and PTAA was not compatible with the carbon electrode however PEDOT and P3HT showed promising results. Beyond photovoltaic performance, comparison of P3HT and PEDOT in terms of stability, toxicity, and cost reveals that P3HT can be a superior choice for scaling up manufacturing. These findings offer valuable insights for optimizing perovskite solar cells performance in scalable production via roll-to-roll printing.
Keywords: Solar Cells
College: Faculty of Science and Engineering
Funders: This work was made possible by the funding supplied to the SPECIFIC Innovation and Knowledge Centre by the Engineering and Physical Science Research Council Program Grant ATIP (Application Targeted and Integrated Photovoltaics) (EP/T028513/1). Additional support was received from the EPSRC Prosperity Partnership [EP EP/X025217/1]. Also, the Advanced Imaging of Materials (AIM) facility at Swansea University. RGR would like to acknowledge the IMPACT operation, which has been partly funded by the European Regional Development Fund through the Welsh Government and Swansea University.
Issue: 1