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Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes

Ershad Parvazian, David Beynon Orcid Logo, Olivia Jenkins, Rahul Patidar, James McGettrick Orcid Logo, SAMUAL NGOMBE, Bhushan Patil, Rodrigo Garcia Rodriguez, Karen Valadez Villalobos, Pete Davies, Matthew Davies Orcid Logo, Trystan Watson Orcid Logo

Communications Materials, Volume: 5, Issue: 1

Swansea University Authors: Ershad Parvazian, David Beynon Orcid Logo, Rahul Patidar, James McGettrick Orcid Logo, SAMUAL NGOMBE, Bhushan Patil, Rodrigo Garcia Rodriguez, Karen Valadez Villalobos, Pete Davies, Matthew Davies Orcid Logo, Trystan Watson Orcid Logo

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DOI (Published version): 10.1038/s43246-024-00516-1

Abstract

Perovskite solar cells hold promise for cost-effective, high-efficiency renewable energy generation; yet their commercialization is hindered by progress towards scalable fabrication methods. Roll-to-roll processing is a promising solution for large-scale production, and the incorporation of Roll-to-...

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Published in: Communications Materials
ISSN: 2662-4443
Published: Springer Science and Business Media LLC 2024
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URI: https://cronfa.swan.ac.uk/Record/cronfa66508
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Roll-to-roll processing is a promising solution for large-scale production, and the incorporation of Roll-to-roll coated carbon electrodes offers several additional advantages, including low-cost manufacturing and high-stability. Introducing a compatible hole transporting layer between perovskite and carbon significantly improves performance. Here we present a study comparing four interlayers (Spiro-MeOTAD, PTAA, PEDOT, and P3HT) in printed devices, assessing efficiency, stability, and scalability. Our results reveal that spiro-MeOTAD and PTAA was not compatible with the carbon electrode however PEDOT and P3HT showed promising results. Beyond photovoltaic performance, comparison of P3HT and PEDOT in terms of stability, toxicity, and cost reveals that P3HT can be a superior choice for scaling up manufacturing. These findings offer valuable insights for optimizing perovskite solar cells performance in scalable production via roll-to-roll printing.</abstract><type>Journal Article</type><journal>Communications Materials</journal><volume>5</volume><journalNumber>1</journalNumber><paginationStart/><paginationEnd/><publisher>Springer Science and Business Media LLC</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint/><issnElectronic>2662-4443</issnElectronic><keywords>Solar Cells</keywords><publishedDay>21</publishedDay><publishedMonth>5</publishedMonth><publishedYear>2024</publishedYear><publishedDate>2024-05-21</publishedDate><doi>10.1038/s43246-024-00516-1</doi><url/><notes/><college>COLLEGE NANME</college><department>Engineering and Applied Sciences School</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>EAAS</DepartmentCode><institution>Swansea University</institution><apcterm>External research funder(s) paid the OA fee (includes OA grants disbursed by the Library)</apcterm><funders>This work was made possible by the funding supplied to the SPECIFIC Innovation and Knowledge Centre by the Engineering and Physical Science Research Council Program Grant ATIP (Application Targeted and Integrated Photovoltaics) (EP/T028513/1). Additional support was received from the EPSRC Prosperity Partnership [EP EP/X025217/1]. Also, the Advanced Imaging of Materials (AIM) facility at Swansea University. 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spelling v2 66508 2024-05-24 Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes 59dc6f18dde94e2a5fb2edd858270ec3 Ershad Parvazian Ershad Parvazian true false f5cf40043658d0b8a747ef6224019939 0000-0002-8189-9489 David Beynon David Beynon true false aa7f3b2aa6daa1c80cad60a4dd59055b Rahul Patidar Rahul Patidar true false bdbacc591e2de05180e0fd3cc13fa480 0000-0002-7719-2958 James McGettrick James McGettrick true false a3ceba7417eefc481138bcba04988753 SAMUAL NGOMBE SAMUAL NGOMBE true false cd545a170cd612ce3e4f08a04d336417 Bhushan Patil Bhushan Patil true false fb0f6e1eeb02aedee895b457faa35445 Rodrigo Garcia Rodriguez Rodrigo Garcia Rodriguez true false ed1f364a450ba609956e44a75da05bc0 Karen Valadez Villalobos Karen Valadez Villalobos true false 38c85534a35a03aac99b687029078831 Pete Davies Pete Davies true false 4ad478e342120ca3434657eb13527636 0000-0003-2595-5121 Matthew Davies Matthew Davies true false a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false 2024-05-24 EAAS Perovskite solar cells hold promise for cost-effective, high-efficiency renewable energy generation; yet their commercialization is hindered by progress towards scalable fabrication methods. Roll-to-roll processing is a promising solution for large-scale production, and the incorporation of Roll-to-roll coated carbon electrodes offers several additional advantages, including low-cost manufacturing and high-stability. Introducing a compatible hole transporting layer between perovskite and carbon significantly improves performance. Here we present a study comparing four interlayers (Spiro-MeOTAD, PTAA, PEDOT, and P3HT) in printed devices, assessing efficiency, stability, and scalability. Our results reveal that spiro-MeOTAD and PTAA was not compatible with the carbon electrode however PEDOT and P3HT showed promising results. Beyond photovoltaic performance, comparison of P3HT and PEDOT in terms of stability, toxicity, and cost reveals that P3HT can be a superior choice for scaling up manufacturing. These findings offer valuable insights for optimizing perovskite solar cells performance in scalable production via roll-to-roll printing. Journal Article Communications Materials 5 1 Springer Science and Business Media LLC 2662-4443 Solar Cells 21 5 2024 2024-05-21 10.1038/s43246-024-00516-1 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University External research funder(s) paid the OA fee (includes OA grants disbursed by the Library) This work was made possible by the funding supplied to the SPECIFIC Innovation and Knowledge Centre by the Engineering and Physical Science Research Council Program Grant ATIP (Application Targeted and Integrated Photovoltaics) (EP/T028513/1). Additional support was received from the EPSRC Prosperity Partnership [EP EP/X025217/1]. Also, the Advanced Imaging of Materials (AIM) facility at Swansea University. RGR would like to acknowledge the IMPACT operation, which has been partly funded by the European Regional Development Fund through the Welsh Government and Swansea University. 2024-06-17T14:02:02.3083209 2024-05-24T12:10:21.8002511 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Ershad Parvazian 1 David Beynon 0000-0002-8189-9489 2 Olivia Jenkins 3 Rahul Patidar 4 James McGettrick 0000-0002-7719-2958 5 SAMUAL NGOMBE 6 Bhushan Patil 7 Rodrigo Garcia Rodriguez 8 Karen Valadez Villalobos 9 Pete Davies 10 Matthew Davies 0000-0003-2595-5121 11 Trystan Watson 0000-0002-8015-1436 12 66508__30455__f2b3047d3e584c2a9a5ae5f355808227.pdf 66508.VOR.pdf 2024-05-24T12:15:33.9815782 Output 6246713 application/pdf Version of Record true This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. true eng http://creativecommons.org/licenses/by/4.0/
title Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
spellingShingle Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
Ershad Parvazian
David Beynon
Rahul Patidar
James McGettrick
SAMUAL NGOMBE
Bhushan Patil
Rodrigo Garcia Rodriguez
Karen Valadez Villalobos
Pete Davies
Matthew Davies
Trystan Watson
title_short Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
title_full Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
title_fullStr Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
title_full_unstemmed Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
title_sort Selecting non-halogenated low-toxic hole transporting materials for Roll-to-Roll perovskite solar cells using carbon electrodes
author_id_str_mv 59dc6f18dde94e2a5fb2edd858270ec3
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bdbacc591e2de05180e0fd3cc13fa480
a3ceba7417eefc481138bcba04988753
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fb0f6e1eeb02aedee895b457faa35445
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author_id_fullname_str_mv 59dc6f18dde94e2a5fb2edd858270ec3_***_Ershad Parvazian
f5cf40043658d0b8a747ef6224019939_***_David Beynon
aa7f3b2aa6daa1c80cad60a4dd59055b_***_Rahul Patidar
bdbacc591e2de05180e0fd3cc13fa480_***_James McGettrick
a3ceba7417eefc481138bcba04988753_***_SAMUAL NGOMBE
cd545a170cd612ce3e4f08a04d336417_***_Bhushan Patil
fb0f6e1eeb02aedee895b457faa35445_***_Rodrigo Garcia Rodriguez
ed1f364a450ba609956e44a75da05bc0_***_Karen Valadez Villalobos
38c85534a35a03aac99b687029078831_***_Pete Davies
4ad478e342120ca3434657eb13527636_***_Matthew Davies
a210327b52472cfe8df9b8108d661457_***_Trystan Watson
author Ershad Parvazian
David Beynon
Rahul Patidar
James McGettrick
SAMUAL NGOMBE
Bhushan Patil
Rodrigo Garcia Rodriguez
Karen Valadez Villalobos
Pete Davies
Matthew Davies
Trystan Watson
author2 Ershad Parvazian
David Beynon
Olivia Jenkins
Rahul Patidar
James McGettrick
SAMUAL NGOMBE
Bhushan Patil
Rodrigo Garcia Rodriguez
Karen Valadez Villalobos
Pete Davies
Matthew Davies
Trystan Watson
format Journal article
container_title Communications Materials
container_volume 5
container_issue 1
publishDate 2024
institution Swansea University
issn 2662-4443
doi_str_mv 10.1038/s43246-024-00516-1
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
active_str 0
description Perovskite solar cells hold promise for cost-effective, high-efficiency renewable energy generation; yet their commercialization is hindered by progress towards scalable fabrication methods. Roll-to-roll processing is a promising solution for large-scale production, and the incorporation of Roll-to-roll coated carbon electrodes offers several additional advantages, including low-cost manufacturing and high-stability. Introducing a compatible hole transporting layer between perovskite and carbon significantly improves performance. Here we present a study comparing four interlayers (Spiro-MeOTAD, PTAA, PEDOT, and P3HT) in printed devices, assessing efficiency, stability, and scalability. Our results reveal that spiro-MeOTAD and PTAA was not compatible with the carbon electrode however PEDOT and P3HT showed promising results. Beyond photovoltaic performance, comparison of P3HT and PEDOT in terms of stability, toxicity, and cost reveals that P3HT can be a superior choice for scaling up manufacturing. These findings offer valuable insights for optimizing perovskite solar cells performance in scalable production via roll-to-roll printing.
published_date 2024-05-21T14:02:01Z
_version_ 1802113459519750144
score 11.012678

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