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Metal organic framework composites for reduction of CO2
,
Ali Morsali,
Amarajothi Dhakshinamoorthy,
Hermenegildo Garcia
Coordination Chemistry Reviews, Volume: 493, Start page: 215257
Swansea University Author:
Mary Larimi
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DOI (Published version): 10.1016/j.ccr.2023.215257
Abstract
Global warming due to greenhouse gases is a major current environmental threat. In today’s world those applicable technologies which convert CO2 into valuable and environmentally friendly fuels and chemicals are of great importance. Thanks to functional sites or guests embedded in the structure, met...
| Published in: | Coordination Chemistry Reviews |
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| ISSN: | 0010-8545 |
| Published: |
Elsevier BV
2023
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| Online Access: |
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa67226 |
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| Abstract: |
Global warming due to greenhouse gases is a major current environmental threat. In today’s world those applicable technologies which convert CO2 into valuable and environmentally friendly fuels and chemicals are of great importance. Thanks to functional sites or guests embedded in the structure, metal organic frameworks (MOFs) show a superb potential for such a conversion that is even further enhanced in MOF composites. The present review discusses the use of MOF composites, with an emphasis on their constituent components, as catalysts for CO2 reduction, converting it into various value-added and environmentally friendly chemicals such as saturated and unsaturated hydrocarbons, carboxylic acids and carboxylates, and carbon monoxide. The present review covers four major approaches for CO2 reduction, including electroreduction, photoreduction, photoelectroreduction, and hydrogenation. All reports on the design and development of appropriate MOF composites to be used in the above-mentioned CO2 reductions have been considered. Finally, the future outlook on the use of MOF composites in CO2 reduction is provided, giving some ideas for further design highly efficient MOF composites capable of converting CO2 to value-added products. |
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| Keywords: |
Heterogeneous catalysis; CO2 utilization, metal-organic framework composites; Electrocatalysis; Photocatalysis; CO2 hydrogenation |
| College: |
Faculty of Science and Engineering |
| Funders: |
The authors gratefully acknowledge from Tarbiat Modares University and the support received from the Niroo Research Institute (NRI) under the contract number 99/50420/152. This work was supported by the National Natural Science Foundation of China (Grant No. 92161106), the Natural Science Foundation of Ningxia (Grant No. 2022AAC05017), and the Foundation of State Key Laboratory of Physical Chemistry of Solid Surfaces (Grant No. 202013). Financial support by the Spanish Ministry of Science and Innovation (PDI-2021-0126071-OB-CO21) and Generalitat Valenciana (Prometeo 2021-038) is gratefully acknowledged. This study forms part of the Advanced Materials programme and was supported by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat Valenciana (Graphica MFA/2022/023. The Institute is a Center of Excellence Severo Ochoa (CEX-2021-001230-S). A.D. is beneficiary of a grant María Zambrano in Universitat Politècnica de València within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU). |
| Start Page: |
215257 |