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Comparative study of cadmium telluride solar cell performance on different TCO‐coated substrates under concentrated light intensities

Rose Davis, Ochai Oklobia, Stuart Irvine, Dan Lamb Orcid Logo

Progress in Photovoltaics: Research and Applications

Swansea University Authors: Rose Davis, Ochai Oklobia, Stuart Irvine, Dan Lamb Orcid Logo

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DOI (Published version): 10.1002/pip.3836

Abstract

Concentrating photovoltaics is an attractive route for achieving high power output with thin film solar cells, using low-cost optics. In this work, the performance of CdTe:As thin film solar cells on two different transparent conducting oxide (TCO)-coated substrates is investigated and compared unde...

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Published in: Progress in Photovoltaics: Research and Applications
ISSN: 1062-7995 1099-159X
Published: Wiley 2024
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa68054
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Abstract: Concentrating photovoltaics is an attractive route for achieving high power output with thin film solar cells, using low-cost optics. In this work, the performance of CdTe:As thin film solar cells on two different transparent conducting oxide (TCO)-coated substrates is investigated and compared under varying concentrated light intensities (1–6.3 Suns). Samples tested had CdZnS/CdTe:As devices deposited atop of either a soda-lime glass with a fluorine-doped tin oxide TCO or an ultra-thin glass (UTG) with an aluminium zinc oxide TCO and ZnO high-resistive transparent (HRT) layer. Device current density was found to increase linearly with increased light intensities, for both sample configurations. Power conversion efficiencies of both device samples decreased with increased light intensity, due to a decrease in fill factor. The fill factor, for both sample configurations, was affected by reducing shunt resistance with increasing illumination intensity. The two device types performed differently at the high illumination intensities due to their series resistance. Light-soaking devices under 6.3 Suns illumination intensity for 90 min showed no significant performance degradation, indicative of relatively stable devices under the highest illumination intensity tested. Efficiency limiting factors are assessed, evaluated and discussed.
Keywords: CdTe:As, concentrated light intensity, concentrated photovoltaic, solar cells, thin films, ZnO HRT layer
College: Faculty of Science and Engineering
Funders: The authors would like to acknowledge the European Regional Development Fund (ERDF) and the Welsh European Funding Office (WEFO) for funding the 2nd Solar Photovoltaic Academic Research Consortium (SPARC II). The authors would also like to acknowledge funding by the Engineering and Physical Sciences Research Council (EPSRC), United Kingdom via the grant EP/W000555/1.