Journal article 674 views
Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
M. Taddei,
A. Ienco,
F. Costantino,
A. Guerri,
Marco Taddei 
RSC Advances, Volume: 3, Issue: 48, Start page: 26177
Swansea University Author:
Marco Taddei
Full text not available from this repository: check for access using links below.
DOI (Published version): 10.1039/c3ra44910f
Abstract
Tubular MOFs based on copper(II) phosphinates and bipyridine have been found to be highly stable in water. However, the possibility to form more dense and stable phases could affect their water stability, leading to slow and spontaneous transformations driven by the hydrolysis of the metal–ligands b...
| Published in: | RSC Advances |
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| ISSN: | 2046-2069 |
| Published: |
Royal Society of Chemistry (RSC)
2013
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| Online Access: |
Check full text
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa32755 |
| Abstract: |
Tubular MOFs based on copper(II) phosphinates and bipyridine have been found to be highly stable in water. However, the possibility to form more dense and stable phases could affect their water stability, leading to slow and spontaneous transformations driven by the hydrolysis of the metal–ligands bonds. As a matter of fact, two structurally related MOFs have a very different water stability that, for one of the two MOFs, can be attributed to the existence of more stable phases that induces a slow transformation in water. For the other MOF, the non-existence of a related more stable phase, probably due to an unfavorable predicted crystal packing, yields an outstanding stability in hot water. |
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| College: |
Faculty of Science and Engineering |
| Issue: |
48 |
| Start Page: |
26177 |