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Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks

M. Taddei, A. Ienco, F. Costantino, A. Guerri, Marco Taddei Orcid Logo

RSC Advances, Volume: 3, Issue: 48, Start page: 26177

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1039/c3ra44910f

Abstract

Tubular MOFs based on copper(II) phosphinates and bipyridine have been found to be highly stable in water. However, the possibility to form more dense and stable phases could affect their water stability, leading to slow and spontaneous transformations driven by the hydrolysis of the metal–ligands b...

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Published in: RSC Advances
ISSN: 2046-2069
Published: Royal Society of Chemistry (RSC) 2013
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URI: https://cronfa.swan.ac.uk/Record/cronfa32755
first_indexed 2017-03-29T13:47:17Z
last_indexed 2018-02-09T05:21:01Z
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recordtype SURis
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spelling 2017-04-03T12:02:52.9286928 v2 32755 2017-03-29 Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2017-03-29 Tubular MOFs based on copper(II) phosphinates and bipyridine have been found to be highly stable in water. However, the possibility to form more dense and stable phases could affect their water stability, leading to slow and spontaneous transformations driven by the hydrolysis of the metal–ligands bonds. As a matter of fact, two structurally related MOFs have a very different water stability that, for one of the two MOFs, can be attributed to the existence of more stable phases that induces a slow transformation in water. For the other MOF, the non-existence of a related more stable phase, probably due to an unfavorable predicted crystal packing, yields an outstanding stability in hot water. Journal Article RSC Advances 3 48 26177 Royal Society of Chemistry (RSC) 2046-2069 31 12 2013 2013-12-31 10.1039/c3ra44910f COLLEGE NANME COLLEGE CODE Swansea University 2017-04-03T12:02:52.9286928 2017-03-29T09:52:48.7170310 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised M. Taddei 1 A. Ienco 2 F. Costantino 3 A. Guerri 4 Marco Taddei 0000-0003-2805-6375 5
title Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
spellingShingle Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
Marco Taddei
title_short Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
title_full Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
title_fullStr Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
title_full_unstemmed Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
title_sort Supramolecular interactions impacting on the water stability of tubular metal–organic frameworks
author_id_str_mv 5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv 5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Marco Taddei
author2 M. Taddei
A. Ienco
F. Costantino
A. Guerri
Marco Taddei
format Journal article
container_title RSC Advances
container_volume 3
container_issue 48
container_start_page 26177
publishDate 2013
institution Swansea University
issn 2046-2069
doi_str_mv 10.1039/c3ra44910f
publisher Royal Society of Chemistry (RSC)
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description Tubular MOFs based on copper(II) phosphinates and bipyridine have been found to be highly stable in water. However, the possibility to form more dense and stable phases could affect their water stability, leading to slow and spontaneous transformations driven by the hydrolysis of the metal–ligands bonds. As a matter of fact, two structurally related MOFs have a very different water stability that, for one of the two MOFs, can be attributed to the existence of more stable phases that induces a slow transformation in water. For the other MOF, the non-existence of a related more stable phase, probably due to an unfavorable predicted crystal packing, yields an outstanding stability in hot water.
published_date 2013-12-31T04:16:55Z
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score 11.103893

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