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When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks

Marco Taddei Orcid Logo

Coordination Chemistry Reviews

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1016/j.ccr.2017.04.010

Abstract

Zirconium-based metal-organic frameworks (Zr-MOFs) are one of the most attractive classes of MOF materials, due to their superior thermal, chemical and mechanical stability. Recently, Zr-MOFs have been shown to feature an unusually high concentration of defects without suffering from severe loss of...

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Published in: Coordination Chemistry Reviews
ISSN: 0010-8545
Published: 2017
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URI: https://cronfa.swan.ac.uk/Record/cronfa33169
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first_indexed 2017-05-03T13:11:41Z
last_indexed 2018-02-09T05:21:52Z
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spelling 2017-06-20T12:02:32.3810598 v2 33169 2017-05-03 When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2017-05-03 EEN Zirconium-based metal-organic frameworks (Zr-MOFs) are one of the most attractive classes of MOF materials, due to their superior thermal, chemical and mechanical stability. Recently, Zr-MOFs have been shown to feature an unusually high concentration of defects without suffering from severe loss of stability. This feature makes Zr-MOFs unique among MOF materials and is generating additional interest around them. Defects have a significant impact on porosity, thermal properties, mechanical properties, Lewis and Brønsted acidity. Researchers have quickly recognized that defects can be engineered to tune the physical-chemical properties of Zr-MOFs, opening up new avenues for their practical application. The scope of the present review article is to provide a comprehensive account of the progress made in this field since the discovery of defects in Zr-MOFs in 2011 and to point out some relevant controversies and open issues of fundamental nature that need to be addressed to improve the understanding of the very nature of defects. Journal Article Coordination Chemistry Reviews 0010-8545 Metal-organic frameworks; Zirconium; Defects; Porous materials 31 12 2017 2017-12-31 10.1016/j.ccr.2017.04.010 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2017-06-20T12:02:32.3810598 2017-05-03T10:48:53.4946839 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Marco Taddei 0000-0003-2805-6375 1 0033169-03052017105100.pdf taddei2017.pdf 2017-05-03T10:51:00.0270000 Output 5350449 application/pdf Accepted Manuscript true 2018-04-29T00:00:00.0000000 true eng
title When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
spellingShingle When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
Marco Taddei
title_short When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
title_full When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
title_fullStr When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
title_full_unstemmed When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
title_sort When defects turn into virtues: the curious case of zirconium-based metal-organic frameworks
author_id_str_mv 5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv 5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Marco Taddei
author2 Marco Taddei
format Journal article
container_title Coordination Chemistry Reviews
publishDate 2017
institution Swansea University
issn 0010-8545
doi_str_mv 10.1016/j.ccr.2017.04.010
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
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description Zirconium-based metal-organic frameworks (Zr-MOFs) are one of the most attractive classes of MOF materials, due to their superior thermal, chemical and mechanical stability. Recently, Zr-MOFs have been shown to feature an unusually high concentration of defects without suffering from severe loss of stability. This feature makes Zr-MOFs unique among MOF materials and is generating additional interest around them. Defects have a significant impact on porosity, thermal properties, mechanical properties, Lewis and Brønsted acidity. Researchers have quickly recognized that defects can be engineered to tune the physical-chemical properties of Zr-MOFs, opening up new avenues for their practical application. The scope of the present review article is to provide a comprehensive account of the progress made in this field since the discovery of defects in Zr-MOFs in 2011 and to point out some relevant controversies and open issues of fundamental nature that need to be addressed to improve the understanding of the very nature of defects.
published_date 2017-12-31T03:40:49Z
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score 11.016235

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